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Thermochemical Properties of n-Undecylammonium Bromide Monohydrate C11H28BrNO(s)

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Abstract

The crystal structure of n-undecylammonium bromide monohydrate was determined by X-ray crystallography. The crystal system of the compound is monoclinic, and the space group is P21/c. Molar enthalpies of dissolution of the compound at different concentrations m/(mol·kg−1) were measured with an isoperibol solution–reaction calorimeter at T = 298.15 K. According to the Pitzer’s electrolyte solution model, the molar enthalpy of dissolution of the compound at infinite dilution (\( \Updelta_{\text{sol}} H_{\text{m}}^{\infty } \)) and Pitzer parameters (\( \beta_{\text{MX}}^{(0)L} \) and \( \beta_{\text{MX}}^{(1)L} \)) were obtained. Values of the apparent relative molar enthalpies (\( {}^{\Upphi }L \)) of the title compound and relative partial molar enthalpies (\( \bar{L}_{2} \) and \( \bar{L}_{1} \)) of the solute and the solvent at different concentrations were derived from experimental values of the enthalpies of dissolution.

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References

  1. Alkan, C., Sari, A., Karaipekli, A.: Preparation, thermal properties and thermal reliability of microencapsulated n-eicosane as novel phase change material for thermal energy storage. Energy Convers. Manag. 52, 687–692 (2011)

    Article  CAS  Google Scholar 

  2. Fang, G.Y., Li, H., Yang, F., Liu, X., Wu, S.M.: Preparation and characterization of nano-encapsulated n-tetradecane as phase change material for thermal energy storage. Chem. Eng. J. 153, 217–221 (2009)

    Article  CAS  Google Scholar 

  3. Li, H., Liu, X., Fang, G.Y.: Preparation and characteristics of n-nonadecane/cement composites as thermal energy storage materials in buildings. Energy Build. 42, 1661–1665 (2010)

    Article  Google Scholar 

  4. Rademeyer, M., Kruger, G.J., Billing, D.G.: Crystal structures and phase transitions of long-chain n-alkylammonium bromide monohydrates. Cryst. Eng. Comm. 11, 1926–1933 (2009)

    Article  CAS  Google Scholar 

  5. Kruger, G.J., Rademeyera, M., Billingb, D.G.: n-Undecylammonium bromide monohydrate. Acta Cryst. E59, o480–o482 (2003)

    CAS  Google Scholar 

  6. Dan, W.Y., Di, Y.Y., Xin, C.L., Kong, Y.X., Tan, Z.C.: Low-temperature heat capacities and standard molar enthalpy of formation of ethylenediammonium tetrachlorocobaltate(II) chloride (H3NCH2CH2NH3)2[CoCl4]Cl2(s). J. Chem. Eng. Data 55, 3010–3016 (2010)

    Article  CAS  Google Scholar 

  7. Di, Y.Y., Yang, W.W., Kong, Y.X., Shi, Q., Tan, Z.C.: Low–temperature heat capacities and standard molar enthalpy of formation of L-3-(3,4-dihydroxyphenyl) alanine (C9H11NO4). J. Chem. Eng. Data 53, 900–904 (2008)

    Article  CAS  Google Scholar 

  8. Yin, H.D., Chen, S.W., Li, L.W., Wang, D.Q.: Synthesis, characterization and crystal structures of the organotin(IV) compounds with the Schiff base ligands of pyruvic acid thiophene-2-carboxylic hydrazone and salicylaldehyde thiophene-2-carboxylic hydrazone. Inorg. Chim. Acta 360, 2215–2223 (2007)

    Article  CAS  Google Scholar 

  9. Yang, W.W., Di, Y.Y., Li, J., Kong, Y.X.: Thermochemistry on ephedrine hydrochloride and N-methylephedrine hydrochloride. J. Chem. Thermodyn. 41, 945–950 (2009)

    Article  CAS  Google Scholar 

  10. Liu, Y.P., Di, Y.Y., He, D.H., Kong, Y.X., Yang, W.W., Dan, W.Y.: Lattice potential energy and thermochemical properties of ethylenediamine dihydrochloride (C2H10N2Cl2). J. Chem. Thermodyn. 42, 513–517 (2010)

    Article  CAS  Google Scholar 

  11. Rychly, R., Pekarek, V.: The use of potassium chloride and tris-(hydroxymethyl) aminomethane as standard substances for solution calorimetry. J. Chem. Thermodyn. 9, 391–396 (1977)

    Article  CAS  Google Scholar 

  12. Silvester, L.F., Pitzer, K.S.: Thermodynamics of electrolytes VIII. High-temperature properties, including enthalpy and heat capacity, with application to sodium chloride. J. Phys. Chem. 81, 1822–1828 (1977)

    Article  CAS  Google Scholar 

  13. Pitzer, K.S. (ed.): Activity coefficients in electrolyte solutions, 2nd edn. CRC, Boca Raton (1991)

    Google Scholar 

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Acknowledgments

This work was financially supported by the National Natural Science Foundations of China under the contracts NSFC No. 20673050 and 20973089.

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  1. Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, College of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng, 252059, Shandong, People’s Republic of China

    Li-Jun Zhang, You-Ying Di & Jian-Min Dou

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  1. Li-Jun Zhang
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  2. You-Ying Di
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Correspondence to You-Ying Di.

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Zhang, LJ., Di, YY. & Dou, JM. Thermochemical Properties of n-Undecylammonium Bromide Monohydrate C11H28BrNO(s). J Solution Chem 42, 52–59 (2013). https://doi.org/10.1007/s10953-013-9954-4

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  • DOI: https://doi.org/10.1007/s10953-013-9954-4

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