Skip to main content
SpringerLink
Log in

Thermal Conductivity and Thermoelectric Power of Potassium and Sodium-Substituted Bi-2212 Superconductor Prepared by PEI Technique

  • Original Paper
  • Published:
Journal of Superconductivity and Novel Magnetism Aims and scope Submit manuscript

Abstract

In the present study, thermal conductivity (κ − T), thermoelectric power (S − T), and figure of merit (ZT) measurements from room temperature down to 20 K of polycrystalline Bi2Sr2Ca1−x Na x Cu2O8+y and Bi2Sr2Ca1−x K x Cu2O8+y superconductors prepared by a polymer solution technique using polyethyleneimine, PEI, have been carried out. The thermoelectric power, S(T), of samples have both negative (at high T) and positive values (at low T), and are found to increase with decreasing temperature, reaching their maximum values (peaks) around their T c values and dropping rapidly to zero below T c. Na and K substitutions also have a considerable effect on the thermal conductivity, κ. Namely, with increasing Na concentration the magnitude of κ is decreased, but for the K substitution, the magnitude of κ is drastically increased for x = 0.75.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Maeda, H., Tanaka, Y., Fukutomi, M., Asano, T.: Jpn. J. Appl. Phys. 27, L 209 (1988)

    Article  ADS  Google Scholar 

  2. Özçelik, B., Gündoğmuş, H., Yazıcı, D.: J. Mater. Sci.: Mater. Electron. 25, 2456 (2014)

    Google Scholar 

  3. Özçelik, B., Kaya, C., Gündoğmuş, H., Sotelo, A., Madre, M.A.: J. Low Temp. Phys. 174, 136 (2014)

    Article  ADS  Google Scholar 

  4. Türk, N., Gündogmus, H., Akyol, M., Yakıncı, Z.D., Ekicibil, A., Özçelik, B.: J. Supercond. Nov. Magn. 27, 711 (2014)

    Article  Google Scholar 

  5. Özaslan, A., Özçelik, B., Özkurt, B., Sotelo, A., Madre, M.A.: J. Supercond. Nov. Magn. 27, 53 (2014)

    Article  Google Scholar 

  6. Gündoğmuş, H., Özçelik, B., Sotelo, A., Madre, M.A.: J. Mater. Sci.: Mater. Electron. 24, 2568 (2013)

    Google Scholar 

  7. Ozcelik, B., Gursul, M., Sotelo, A., Madre, M.A.: J. Mater. Sci.: Mater. Electron. 25, 4476 (2014)

    Google Scholar 

  8. Özçelik, B., Özkurt, B., Yakıncı, M.E., Sotelo, A., Madre, M.A.: J. Supercond. Nov. Magn. 26, 873 (2013)

    Article  Google Scholar 

  9. Yazıcı, D., Ozçelik, B., Yakıncı, M.E.: J. Low Temp. Phys. 163, 370 (2011)

    Article  ADS  Google Scholar 

  10. Sotelo, A., Mora, M., Madre, M.A., Diez, J.C., Angurel, L.A., de la Fuente, G.F.: J. Eur. Ceram. Soc. 25, 2947 (2005)

    Article  Google Scholar 

  11. Jiang, L., Sun, Y., Wan, X., Wang, K., Xu, G., Chen, X., Ruan, K.: J. Du: Physica C 300, 61 (1998)

    ADS  Google Scholar 

  12. Shoushtari, M.Z., Ghahfarokhi, S.E.M.: J. Supercond. Nov. Magn. 24, 1505 (2011)

    Article  Google Scholar 

  13. Abou-Aly, A.I., Gawad, M.M.H.A., Awad, R., G-Eldeen, I.: J. Supercond. Nov. Magn. 24, 2077 (2011)

    Article  Google Scholar 

  14. Mora, M., Sotelo, A., Amaveda, H., Madre, M.A., Diez, J.C., Angurel, L.A., de la Fuente, G.F.: Bol. Soc. Esp. Ceram. V. 44, 199 (2005)

    Article  Google Scholar 

  15. de la Fuente, G.F., Sotelo, A., Huang, Y., Ruiz, M.T., Badia, A., Angurel, L.A., Lera, F., Navarro, R., Rillo, C., Ibañez, R., Beltran, D., Sapiña, F., Beltran, A.: Physica C 185, 509 (1991)

    Article  ADS  Google Scholar 

  16. Özkurt, B., Madre, M.A., Sotelo, A., Yakıncı, M.E., Özçelik, B.: J. Supercond. Nov. Magn. 25, 799 (2012)

    Article  Google Scholar 

  17. Bal, S., Dogruer, M., Yıldırım, G., Varilci, A., Terzioglu, C., Zalaoglu, Y.: J. Supercond. Nov. Magn. 25, 847 (2012)

    Article  Google Scholar 

  18. Chattopadhyay, B., Bandyopadhyay, B., Poddar, A., Mandal, P., Das, A.N., Ghosh, B.: Physica C 331, 38 (2000)

    Article  ADS  Google Scholar 

  19. Ilonca, G., Toma, V., Yang, T.R., Pop, A.V., Balint, P., Bodea, M., Macocian, E.: Physica C 369, 460 (2007)

    Google Scholar 

  20. Wang, X.L., Horvat, J., Gu, G.D., Uprety, K.K., Liu, H.K., Dou, S.X.: Physica C 337, 221 (2000)

    Article  ADS  Google Scholar 

  21. Yamamoto, T., Kakeya, I., Kadowaki, K.: Physica C 460-462, 799 (2007)

    Article  ADS  Google Scholar 

  22. Ozcelik, B., Yalaz, E., Yakıncı, M.E., Sotelo, A., Madre, M.A.: J. Supercond. Nov. Magn. 28, 553 (2015)

    Article  Google Scholar 

  23. Ozcelik, B., Gursul, M., Sotelo, A., Madre, M.A.: J. Mater. Sci: Mater. Electron. 26, 441 (2015)

    Google Scholar 

  24. Ozcelik, B., Gursul, M., Sotelo, A., Madre, M.A.: J. Mater Sci: Mater. Electron (2015). doi:10.1007/s10854-015-2765-1

  25. Gursul, M., Ekicibil, A., Ozcelik, B., Sotelo, A., Madre, M.A.: J. Supercond. Nov. Magn. (2015). doi:10.1007/s10948-015-2977-x

  26. Blatter, G., Feigelman, M.V., Ceshkenbein, V.B., Larkin, A.I., Vinokur, V.M.: Rev. Mod. Phys. 6, 1125 (1994)

    Article  ADS  Google Scholar 

  27. Torrance, J.B., Tokura, Y., Nazzal, A.I., Bezinge, A., Huang, T.C., Parkin, S.S.P.: Phys. Rev. Lett. 61, 1127 (1988)

    Article  ADS  Google Scholar 

  28. Tokura, Y., Torrance, J.B., Huang, T.C., Nazzal, A.I.: Phys. Rev. B 38, 7156 (1988)

    Article  ADS  Google Scholar 

  29. Zeng, R., Guo, Y.C., Tanaka, Y., Horvat, J., Ionescu, M., Beales, T.P., Appley, M., Liu, H.K., Dou, S.X.: Physica C 307, 229 (1998)

    Article  ADS  Google Scholar 

  30. Kanisada, Y., Koizumi, T., Satou, M., Yamada, Y.: IEEE Trans. Magn. 30, 1675 (1994)

    Article  ADS  Google Scholar 

  31. Chatterjee, S., Banerjee, S., Mollah, S., Chaudhuri, B.K.: Phys. Rev. B 53, 5942 (1996)

    Article  ADS  Google Scholar 

  32. Chatterjee, S., Chaudhuri, B.K., Komatsu, T.: Solid State Commun. 104, 67 (1997)

    Article  ADS  Google Scholar 

  33. Bhattacharya, S., Chatterjee, S., Goswami, K., Chaudhuri, B.K.: J. Mater. Sci. Lett. 17, 1575 (1998)

    Article  Google Scholar 

  34. Chatterjee, S., Pal, P.K., Bhattacharya, S., Chaudhuri, B.K.: Phys. Rev. B 58, 12427 (1998)

    Article  ADS  Google Scholar 

  35. Barik, H.K., Bhattacharya, S., Chatterjee, S., Pal, P.K., Chaudhuri, B.K.: Phılos. Mag. B 79, 1161 (1999)

    Article  Google Scholar 

  36. Aksan, M.A., Yakıncı, M.E.: J. Alloy Comp. 385, 33 (2004)

    Article  Google Scholar 

  37. Ozkurt, B., Ozcelik, B., Kıymac, K., Aksan, M.A., Yakıncı, M.E.: Physica C 467, 112 (2007)

    Article  ADS  Google Scholar 

  38. Ozkurt, B., Ekicibil, A., Aksan, M.A., Ozcelik, B., Yakıncı, M.E., Kıymac, K.: Low Temp.Phys 147(1/2) (2007)

  39. Dorbolo, S., Ausloss, M., Bougrine, H., Robertz, B., Cloots, R., Mucha, J., Durczewski, K.: J. Supercond. 12, 623 (1999)

    Article  ADS  Google Scholar 

  40. Kishore, K.N., Satyavathi, S., Muralidhar, V, Pena, O., Babu, V.H.: Physica C 252, 49 (1995)

    Article  ADS  Google Scholar 

  41. Sotelo, A., Rasekh, Sh., Madre, M.A., Diez, J.C.: J. Supercond. Nov. Magn. 24, 19 (2011)

    Article  Google Scholar 

  42. Sotelo, A., Szillat, H., Majewski, P., Aldinger, F.: Supercond. Sci. Technol. 10, 717–720 (1997)

    Article  ADS  Google Scholar 

  43. Gündogmus, H., Özçelik, B., Özkurt, B., Sotelo, A., Madre, M.A.: J. Supercond. Nov. Magn. 26, 111 (2013)

    Article  Google Scholar 

  44. Kaya, C., Özçelik, B., Özkurt, B., Sotelo, A., Madre, M.A.: J. Mater. Sci.: Mater. Electron. 24, 1580 (2013)

    Google Scholar 

  45. Basak, S., Ghatak, S.K.: Int. J. Mod. Phys. B 13, 1633 (1999)

    Article  ADS  Google Scholar 

  46. Zhang, L., Liu, C., Yang, X., Han, Q.: Physica B 279, 230 (2000)

    Article  ADS  Google Scholar 

  47. Forro, L., Raki, M., Henry, J.Y., Ayache, C.: Solid State Commun. 69, 1097 (1989)

    Article  ADS  Google Scholar 

  48. Ikegawa, S., Wada, T., Yamashida, T., Ichinose, A., Matsuura, K., Kubo, K., Yamauchi, H., Tanaka, S.: Phys. Rev. B 43, 11508 (1991)

    Article  ADS  Google Scholar 

  49. Gassumyants, V.E., Kaidanov, V.I., Vladimirskaya, E.V.: Physica C 248, 255 (1995)

    Article  ADS  Google Scholar 

  50. Xin, Y., Wong, K.W., Fan, C.X., Sheng, Z.Z., Chan, F.T.: Phys. Rev. B 48, 557 (1993)

    Article  ADS  Google Scholar 

  51. Wang, R., Sekine, H., Jin, H.: Supercond. Sci. Technol. 9, 529 (1996)

    Article  ADS  Google Scholar 

  52. Uher, C., Wang, W.N.: Phys. Rev. B 40, 2694 (1989)

    Article  ADS  Google Scholar 

  53. Chanda, B., Dey, T.K.: Solid State Commun. 89, 353 (1994)

    Article  ADS  Google Scholar 

  54. Aksan, M.A., Yakıncı, M.E., Balci, Y., Ates, H.: J. Low Temp. Phys. 117, 957 (1999)

    Article  ADS  Google Scholar 

  55. Natividad, E., Castro, M., Burriel, R., Angurel, L.A., Diez, J.C., Navarro, R.: Supercond. Sci. Technol. 15, 1022 (2002)

    Article  ADS  Google Scholar 

  56. Knizek, K., Veverka, M., Hadova, E., Hejtmanek, J., Sedmidubsky, D., Pollert, E.: Physica C 302, 290 (1998)

    Article  ADS  Google Scholar 

  57. Peacor, S.D., Richardson, R.A., Nori, F., Uher, C.: Phys. Rev. B 44, 9508 (1991)

    Article  ADS  Google Scholar 

  58. Aubin, H., Behnia, K., Ribault, M., Taillefer, L., Gagnon, R.: Z. Phys. B 103, 149 (1997)

    Article  ADS  Google Scholar 

  59. Yu, R.C., Salamon, M.B., Lu, J.P., Lee, W.C.: Phys. Rev. Lett. 69, 1431 (1992)

    Article  ADS  Google Scholar 

  60. Krishana, K., Haris, J.M., Ong, N.P.: Phys. Rev. Lett. 75, 3529 (1995)

    Article  ADS  Google Scholar 

  61. Hirschfeld, P.J., Putikka, W.O.: Phys. Rev. Lett. 77, 3909 (1996)

    Article  ADS  Google Scholar 

  62. Cullity, B.D.: Element of X-ray diffraction. Addition-Wesley, Reading (1978)

    Google Scholar 

  63. Presland, M.R., Tallon, V., Buckley, R.G., Liv, V., Floer, N.E.: Physica C 176, 95 (1991)

    Article  ADS  Google Scholar 

  64. Torrance, J.B., Bezinge, A., Nazzal, A.I.: Phys. Rev. B 40, 8872 (1989)

    Article  ADS  Google Scholar 

  65. Sekhar, M.C., Suryanarayana, S.V.: Physica C 415, 209 (2004)

    Article  ADS  Google Scholar 

  66. Beni, G.: Phys. Rev. B 10, 2187 (1974)

    Article  ADS  Google Scholar 

  67. Chaikin, P.M., Beni, G.: Phys. Rev. B 46, 647 (1976)

    Article  ADS  Google Scholar 

  68. Cooper, J.R., Alavi, B., Zhow, L.W., Boyermann, W.P., Gruner, G.: Phys. Rev. B 35, 8794 (1987)

    Article  ADS  Google Scholar 

  69. Cohn, J.L., Skelton, E.F., Wolf, S.A., Liu, J.Z., Shelton, R.N.: Phys. Rev. B 45, 13144 (1992)

    Article  ADS  Google Scholar 

  70. Castellazi, S., Cimberle, M.R., Ferdeghini, V, Giannini, E., Grasso, V, Marre, V, Putti, M., Siri, A.S.: Physica C 273, 314 (1997)

    Article  ADS  Google Scholar 

Download references

Acknowledgments

This work is supported by the Research Fund of Çukurova University, Adana, Turkey, under Grant Contract Nos FBE.2013YL45 and FEF2013BAP22. A. Sotelo and M. A. Madre wish to thank the Gobierno de Aragón and the Fondo Social Europeo (Research Group T12) and MINECO-FEDER (Project MAT2013-46505-C3-1-R) for the financial support.

Author information

Authors and Affiliations

  1. Department of Physics, Faculty of Sciences and Letters, Çukurova University, 01330, Adana, Turkey

    B. Özçelik, A. Tangüner & M. Gürsul

  2. ICMA (CSIC-Universidad de Zaragoza), María de Luna, 3, 50018, Zaragoza, Spain

    A. Sotelo & M. A. Madre

Authors
  1. B. Özçelik
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. Tangüner
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. Gürsul
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. Sotelo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. A. Madre
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to B. Özçelik.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Özçelik, B., Tangüner, A., Gürsul, M. et al. Thermal Conductivity and Thermoelectric Power of Potassium and Sodium-Substituted Bi-2212 Superconductor Prepared by PEI Technique. J Supercond Nov Magn 28, 2641–2647 (2015). https://doi.org/10.1007/s10948-015-3087-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10948-015-3087-5

Keywords

Search

Navigation