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Acid treated clays: preparation, characterization and catalytic activity for synthesis of quinoxaline derivatives

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Abstract

The preparation, characterization, and catalytic properties of acid treated clay (ATC) are reported. ATC has been characterized by XRD (basal spacing, 14.82 Å), specific surface area (66 m2/g), pore volume and pore width using BET method, UV–Vis DRS, TGA, SEM, and surface acidity by TPD of NH3. The activity of was investigated by the reaction of benzil with o-phenylene diamine. Among the catalysts, ATC was found to be more active. The reaction of various substituted o-phenylenediamines with benzil was studied on ATC to obtain corresponding quinoxalines in good yields. The regeneration and reusability of ATC has also been investigated.

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Acknowledgments

This work is funded by the Department of Science and Technology, New Delhi, India, under Fast Track Scheme for Young Scientists (Project No. SR/FTP/CS-11/2006). The author is grateful to Prof. G. Ranga Rao, Department of Chemistry, IIT Madras, Chennai, India for his support and encouragement. Thanks are also due to the Sophisticated Analytical Instrument Facility, Indian Institute of Technology Madras for IR, HRMS, 1H and 13C NMR spectra.

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  1. Vijayakumar Badathala

    Present address: Department of Chemistry, Vel Tech High Tech Dr. Rangarajan Dr. Sakunthala Engineering College, Avadi, Chennai, 600062, India

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  1. Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600036, India

    Vijayakumar Badathala

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Badathala, V. Acid treated clays: preparation, characterization and catalytic activity for synthesis of quinoxaline derivatives. J Porous Mater 22, 779–786 (2015). https://doi.org/10.1007/s10934-015-9951-7

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