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Adsorption of tetrakis(p-sulfonatophenyl)porphyrin on kaolinite

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Abstract

The surface modification of kaolinite to introduce the adsorption sites for anionic species was reported. The introduction of an anion exchange site was as follows; intercalation of 2-aminoethanol into kaolinite by using dimethyl sulfoxide-kaolinite intercalation compound as a precursor and subsequent hydrochlorination of 2-aminoethanol-kaolinite in 1,4-dioxane. The hydrochlorination of 2-aminoethanol-kaolinite was confirmed by the increase in the basal spacing (0.2 nm, corresponding to the diameter of chlorine) and the appearance of the infrared absorption bands due to ammonium groups. The modified kaolinite adsorbed an anionic dye, tetrakis(p-sulfonatophenyl)porphyrin, from a N,N-dimethylformamide solution. Initial slope of the adsorption isotherm of tetrakis(p-sulfonatophenyl)porphyrin on the hydrochlorinated 2-aminoethanol-kaolinite was steep, showing strong adsorbate-adsorbent interactions. The gallery height after the adsorption of tetrakis(p-sulfonatophenyl)porphyrin was close to the thickness of the porphyrin ring, suggesting that tetrakis(p-sulfonatophenyl)porphyrin was intercalated as a monomolecular layer and that chlorine simultaneously deintercalated.

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Acknowledgments

This work was supported by a Grant-in-Aid for Scientific Research on Priority Areas (417) from the Ministry of Education, Culture, Sports, Science and Technology (MEXT) of the Japanese Government and by CREST (JST). One of the authors (T.O.) also thanks MEXT of the Japanese Government (Grant-in-Aid for Scientific Research on Young Scientists [B]) and Research Foundation for the Electrotechnology of Chubu.

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Authors and Affiliations

  1. Graduate School of Science and Engineering, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo, 169-8050, Japan

    Yusuke Tanaka & Makoto Ogawa

  2. Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, Wakasato 4-17-1, Nagano, 380-8553, Japan

    Tomohiko Okada

  3. Department of Earth Sciences, Waseda University, Nishiwaseda 1-6-1, Shinjuku-ku, Tokyo, 169-8050, Japan

    Makoto Ogawa

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  1. Yusuke Tanaka
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  2. Tomohiko Okada
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Correspondence to Makoto Ogawa.

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Tanaka, Y., Okada, T. & Ogawa, M. Adsorption of tetrakis(p-sulfonatophenyl)porphyrin on kaolinite. J Porous Mater 16, 623–629 (2009). https://doi.org/10.1007/s10934-008-9240-9

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