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Synthesis, Characterization, and Application of Hybrid Inorganic–Organic Composites (K/Na)ZrSi(R)Ox

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Abstract

Hybrid inorganic–organic composites, (K/Na)ZrSi(R)Ox, were synthesized from the hydrolysis of the mixture of zirconium n-propoxide (Zr(OPrn)4) and 3-glycidyloxypropyltrimethoxy silane (GPTS) in 1:1 mol ratio. The hydrolysis reaction was carried out with 0.1 molar HCl in 150 ml of butanol. Then, the synthesized Zr(OPrn)4-GPTS-hydrolyzate reacted with KOBut and NaOSiMe3 in 1:1 mol ratio at 40 and 50 °C for 24 h, respectively. After these stages, composites were washed and dried under vacuum. Composites and their oxide prepared at 1250 °C by calcinations were characterized by a combination of powder X-ray diffraction, scanning electron microscope, energy dispersive X-ray, Brunauer–Emmett–Teller analysis, Barrett–Joyner–Halenda analysis, and Fourier transform infrared spectroscopies. These hybrid inorganic–organic composites except oxides were used as catalysts in order to see their activities in the polymerization of ε-caprolactone (ε-CL). This study showed that new composite materials except their oxides were effective catalyst in ε-CL polymerization.

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Acknowledgments

This study was supported by the research foundation of Kocaeli University, (Project No:2014/17).

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Authors and Affiliations

  1. Department of Chemistry, Kocaeli University, Kocaeli, 41380, Turkey

    Asgar Kayan

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  1. Asgar Kayan
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Correspondence to Asgar Kayan.

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Kayan, A. Synthesis, Characterization, and Application of Hybrid Inorganic–Organic Composites (K/Na)ZrSi(R)Ox . J Inorg Organomet Polym 26, 640–647 (2016). https://doi.org/10.1007/s10904-016-0349-z

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