Abstract
This mini-review article focuses on metallodendrimers containing redox-robust systems that are attached to branches at the dendrimer periphery, and specifically on the properties, functions and applications of these nano-materials. The mini-review is illustrated essentially with the dendrimers containing metal-sandwich termini such as ferrocenes, cobaltocenes and mixed-sandwich complexes of the [FeCp(η6-arene)] family that have been developed in the author’s laboratory. Synthetic aspects have been developed and reviewed elsewhere, and here emphasis is placed on stoichiometric and catalytic electron-transfer processes involving redox recognition, redox sensing, redox catalysis and molecular materials aspects. Finally uses of redox metallocenes and metallocene-containing macromolecules as components of batteries are briefly discussed.
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Invaluable contributions from the colleagues and students cited in the references and financial support from the University of Bordeaux, the Centre National de la Recherche Scientifique, the Institut Universitaire de France (DA) and L’Oréal are gratefully acknowledged
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This mini-review article is dedicated to our esteemed colleague Professor Ben Zhong Tang, in recognition of his excellent contribution to polymer chemistry and materials science.
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Astruc, D., Ruiz, J. The Redox Functions of Metallodendrimers. J Inorg Organomet Polym 25, 2–11 (2015). https://doi.org/10.1007/s10904-014-0091-3
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DOI: https://doi.org/10.1007/s10904-014-0091-3