Skip to main content
Log in

Highly efficient visible light-induced photocatalytic degradation of methylene blue over InVO4/BiVO4 composite photocatalyst

  • Original Paper
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

A Correction to this article was published on 16 October 2020

This article has been updated

Abstract

A highly efficient and visible light responsive photocatalyst was developed by indium vanadate (InVO4)/bismuth vanadate (BiVO4) composite photocatalyst. The samples were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller, scanning electron microscopy, transmission electron microscopy (TEM), UV–Vis diffuse reflectance spectra, XPS, zeta potential, and photoluminescence techniques. The XRD, TEM, and XPS results indicated the prepared sample was actually a two-phase composite: InVO4 and BiVO4. Photocatalytic activities of all catalysts were evaluated for the degradation of methylene blue in aqueous solution under visible light irradiation. The highest activity was obtained in the InVO4/BiVO4 composite using 0.8:0.2 mol ratio of InVO4:BiVO4. On the basis of the calculated energy band positions, the mechanism of enhanced photocatalytic activity was discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9

Similar content being viewed by others

Change history

  • 16 October 2020

    After the manuscript was reviewed thoroughly, two errors were found in the original article. Here, the corrections for the errors in the article have been described as follows:

References

  1. Yan Y, Sun S, Song Y, Yan X, Guan W, Liu X, Shi W (2013) Microwave-assisted in situ synthesis of reduced graphene oxide-BiVO4 composite photocatalysts and their enhanced photocatalytic performance for the degradation of ciprofloxacin. J Hazard Mater 250–251:106–114

    Article  Google Scholar 

  2. Zhang Z, Wang W, Shang M, Yin W (2010) Photocatalytic degradation of rhodamine B and phenol by solution combustion synthesized BiVO4 photocatalyst. Catal Commun 11:982–986

    Article  Google Scholar 

  3. Lin X, Li H, Yu L, Zhao H, Yan Y, Liu C, Zhai H (2013) Efficient removal rhodamine B over hydrothermally synthesized fishbone like BiVO4. Mater Res Bull 48:4424–4429

    Article  Google Scholar 

  4. Shang M, Wang W, Zhou L, Sun S, Yin W (2009) Nanosized BiVO4 with high visible-light-induced photocatalytic activity: ultrasonic-assisted synthesis and protective effect of surfactant. J Hazard Mater 172:338–344

    Article  Google Scholar 

  5. Yan Y, Cai F, Song Y, Shi W (2013) InVO4 nanocrystal photocatalysts: microwave-assisted synthesis and size-dependent activities of hydrogen production from water splitting under visible light. Chem Eng J 233:1–7

    Article  Google Scholar 

  6. Wang Y, Dai H, Deng J, Liu Y, Zhao Z, Li X, Arandiyan H (2013) Three-dimensionally ordered macroporous InVO4: fabrication and excellent visible-light-driven photocatalytic performance for methylene blue degradation. Chem Eng J 226:87–94

    Article  Google Scholar 

  7. Lee DK, Cho I, Lee S, Bae S, Noh JH, Kim DW, Hong KS (2010) Effects of carbon content on the photocatalytic activity of C/BiVO4 composites under visible light irradiation. Mater Chem Phys 119:106–111

    Article  Google Scholar 

  8. Pérez UMG, Guzmán SS, Cruz AM, Méndez UO (2011) Photocatalytic activity of BiVO4 nanospheres obtained by solution combustion synthesis using sodium carboxymethyl cellulose. J Mol Catal A 335:169–175

    Article  Google Scholar 

  9. Sang L, Dai H, Sun J, Xu L, Wang F, Ma C (2010) Fabrication of the hydrogen-evolving photocatalyst with mesoporous structure. Int J Hydrog Energy 35:7098–7103

    Article  Google Scholar 

  10. Mina Y, Zhang K, Chen YC, Zhang YG (2011) Synthesis of novel visible light responding vanadate/TiO2 heterostructure photocatalysts for application of organic pollutants. Chem Eng J 175:76–83

    Article  Google Scholar 

  11. Obregón S, Colón G (2013) On the different photocatalytic performance of BiVO4 catalysts for methylene blue and rhodamine B degradation. J Mol Catal A 376:40–47

    Article  Google Scholar 

  12. Ke D, Peng T, Ma L, Cai P, Jiang P (2008) Photocatalytic water splitting for O2 production under visible-light irradiation on BiVO4 nanoparticles in different sacrificial reagent solutions. Appl Catal A 350:111–117

    Article  Google Scholar 

  13. Wang W, Huang X, Wu S, Zhou Y, Wang L, Shi H, Liang Y, Zou B (2013) Preparation of p–n junction Cu2O/BiVO4 heterogeneous nanostructures with enhanced visible-light photocatalytic activity. Appl Catal B 134–135:293–301

    Article  Google Scholar 

  14. Zhang X, Gong Y, Dong X, Zhang X, Ma C, Shi F (2012) Fabrication and efficient visible light-induced photocatalytic activity of Bi2WO6/BiVO4 heterojunction. Mater Chem Phys 136:472–476

    Article  Google Scholar 

  15. Wetchakun N, Chaiwichain S, Inceesungvorn B, Pingmuang K, Phanichphant S, Minett AI, Chen J (2012) BiVO4/CeO2 nanocomposites with high visible-light-induced photocatalytic activity. ACS Appl Mater Interfaces 4:3718–3723

    Article  Google Scholar 

  16. Min Y, Zhang K, Chen Y, Zhang Y (2012) Sonodegradation and photodegradation of methyl orange by InVO4/TiO2 nanojunction composites under ultrasonic and visible light irradiation. Ultrason Sonochem 19:883–889

    Article  Google Scholar 

  17. Ye J, Zou Z, Oshikiri M, Matsushita A, Shimoda M, Imai M, Shishido T (2002) A novel hydrogen-evolving photocatalyst InVO4 active under visible light irradiation. Chem Phys Lett 356:221–226

    Article  Google Scholar 

  18. Yu J, Zhang Y, Kudo A (2009) Synthesis and photocatalytic performances of BiVO4 by ammonia co-precipitation process. J Solid State Chem 182:223–228

    Article  Google Scholar 

  19. Huang CM, Pan GT, Peng PY, Yang TCK (2010) In situ DRIFT study of photocatalytic degradation of gaseous isopropanol over BiVO4 under indoor illumination. J Mol Catal A 327:38–44

    Article  Google Scholar 

  20. Yan Y, Liu X, Fan W, Lv P, Shi W (2012) InVO4 microspheres: preparation, characterization and visible-light-driven photocatalytic activities. Chem Eng J 200–202:310–316

    Article  Google Scholar 

  21. Liu J, Wang H, Wang S, Yan H (2003) Hydrothermal preparation of BiVO4 powders. Mater Sci Eng B 104:36–39

    Article  Google Scholar 

  22. Fan H, Wang D, Wang L, Li H, Wang P, Jiang T, Xi T (2011) Hydrothermal synthesis and photoelectric properties of BiVO4 with different morphologies: an efficient visible-light photocatalyst. Appl Surf Sci 257:7758–7762

    Article  Google Scholar 

  23. Zhang L, Long J, Pan W, Zhou S, Zhu J, Zhao Y, Wang X, Cao G (2012) Efficient removal of methylene blue over composite-phase BiVO4 fabricated by hydrothermal control synthesis. Mater Chem Phys 136:897–902

    Article  Google Scholar 

  24. Obregón S, Caballero A, Colón G (2012) Hydrothermal synthesis of BiVO4: structural and morphological influence on the photocatalytic activity. Appl Catal B 117–118:59–66

    Article  Google Scholar 

  25. Jia K, Deng J, Zang H, Han J, Arandiyan H, Dai H (2015) Fabrication and high photocatalytic performance of noble metal nanoparticles supported on 3DOM InVO4–BiVO4 for the visible-light-driven degradation of rhodamine B and methylene blue. Appl Catal B 165:285–295

    Article  Google Scholar 

  26. Parks JH, Kim S, Bard AJ (2006) Novel carbon-doped TiO2 nanotube arrays with high aspect ratios for efficient solar water splitting. Nano Lett 6:24–28

    Article  Google Scholar 

  27. Li H, Liu G, Duan X (2009) Monoclinic BiVO4 with regular morphologies: hydrothermal synthesis, characterization and photocatalytic properties. Mater Chem Phys 115:9–13

    Article  Google Scholar 

  28. Liu S, Yu J (2008) Cooperative self-construction and enhanced optical absorption of nanoplates-assembled hierarchical Bi2WO6 flowers. J Solid State Chem 181:1048–1055

    Article  Google Scholar 

  29. Yu J, Su Y, Cheng B, Zhou M (2008) Effects of pH on the microstructures and photocatalytic activity of mesoporous nanocrystalline titania powders prepared via hydrothermal method. J Mol Catal A 258:104–112

    Article  Google Scholar 

  30. Zhang A, Zhang J (2010) Synthesis and characterization of Ag/BiVO4 composite photocatalyst. Appl Surf Sci 256:3224–3227

    Article  Google Scholar 

  31. Shen J, Yang H, Shen Q, You Z (2014) Synthesis and characterization of InVO4 nano-materials and their photoluminescence properties. Procedia Eng 94:64–70

    Article  Google Scholar 

  32. Sacco O, Vaiano V, Han C, Sannino D, Dionysiou DD (2015) Photocatalytic removal of atrazine using N-doped TiO2 supported on phosphors. Appl Catal B 164:462–474

    Article  Google Scholar 

  33. Hea GH, Hea GL, Li AJ, Li X, Wang XJ, Fang YP, Xu YH (2014) Synthesis and visible light photocatalytic behavior of WO3 (core)/Bi2WO6 (shell). J Mol Catal A 385:106–111

    Article  Google Scholar 

  34. Shi W, Guo F, Chen J, Che G, Lin X (2014) Hydrothermal synthesis of InVO4/Graphitic carbon nitride heterojunctions and excellent visible-light-driven photocatalytic performance for rhodamine B. J Alloy Compd 612:143–148

    Article  Google Scholar 

  35. Cimino N, Artuso F, Decker F, Orel B, Šurca Vuk A, Zanoni R (2003) XPS and IR studies of transparent InVO4 films upon Li charge–discharge reactions. Solid State Ion 165:89–96

    Article  Google Scholar 

  36. Abrutis A, Parafianovic L, Kazlauskiene V, Kubilius V, Sauthier G, Figueras A (2010) Atmospheric pressure chemical vapour deposition and characterisation of crystalline InTaO4, InNbO4 and InVO4 coatings. Surf Coat Technol 204:3864–3870

    Article  Google Scholar 

  37. Yu C, Yang K, Yu JC, Cao F, Li X, Zhou X (2011) Fast fabrication of Co3O4 and CuO/BiVO4 composite photocatalysts with high crystallinity and enhanced photocatalytic activity via ultrasound irradiation. J Alloy Compd 509:4547–4552

    Article  Google Scholar 

  38. Xiao G, Wang X, Li D, Fu X (2008) InVO4-sensitized TiO2 photocatalysts for efficient air purification with visible light. J Photochem Photobiol A 193:213–221

    Article  Google Scholar 

  39. Zhang J, Cui H, Wang B, Li C, Zhai J, Li Q (2013) Fly ash cenospheres supported visible-light-driven BiVO4 photocatalyst: synthesis, characterization and photocatalytic application. Chem Eng J 223:737–746

    Article  Google Scholar 

  40. Dong S, Cui Y, Wang Y, Li Y, Hu L, Sun J, Sun J (2014) Designing three-dimensional acicular sheaf shaped BiVO4/reduced graphene oxide composites for efficient sunlight-driven photocatalytic degradation of dye wastewater. Chem Eng J 249:102–110

    Article  Google Scholar 

  41. Zhang L, Tann G, Wei S, Ren H, Xia A, Luo Y (2013) Microwave hydrothermal synthesis and photocatalytic properties of TiO2/BiVO4 composite photocatalysts. Ceram Int 39:8597–8604

    Article  Google Scholar 

  42. Jiang HQ, Endo H, Natori H, Nagai M, Kobayashi K (2009) Fabrication and efficient photocatalytic degradation of methylene blue over CuO/BiVO4 composite under visible-light irradiation. Mater Res Bull 44:700–706

    Article  Google Scholar 

  43. Xiang Q, Yu J, Wong PK (2011) Quantitative characterization of hydroxyl radicals produced by various photocatalysts. J Colloid Interface Sci 357:163–167

    Article  Google Scholar 

  44. Castillo NC, Heel A, Graule T, Pulgarin C (2010) Flame-assisted synthesis of nanoscale, amorphous and crystalline, spherical BiVO4 with visible-light photocatalytic activity. Appl Catal B 95:335–347

    Article  Google Scholar 

  45. Magesh G, Viswanathan B, Viswanath RP, Varadarajan TK (2009) Photocatalytic behavior of CeO2-TiO2 system for the degradation of methylene blue. Indian J Chem 48A:480–488

    Google Scholar 

  46. Ge L, Xu M, Fang H (2006) Preparation and characterization of silver and indium vanadate co-doped TiO2 thin films as visible-light-activated photocatalyst. J Sol Gel Sci Technol 40:65–73

    Article  Google Scholar 

  47. Guo F, Shi W, Lin X, Yan X, Guo Y, Che G (2015) Novel BiVO4/InVO4 heterojunctions: facile synthesis and efficient visible-light photocatalytic performance for the degradation of rhodamine B. Sep Purif Technol 141:246–255

    Article  Google Scholar 

  48. Boonprakob N, Wetchakun N, Phanichphant S, Waxler D, Sherrell P, Nattestad A, Chen J, Inceesungvorn B (2014) Enhanced visible-light photocatalytic activity of g-C3N4/TiO2 films. J Colloid Interface Sci 417:402–409

    Article  Google Scholar 

Download references

Acknowledgements

This work was financially supported by the National Research University Project under Thailand’s Office of the Higher Education Commission, Materials Science Research Center; the Thailand Research Fund (TRF) and the Commission on Higher Education (CHE) Grant; the Thailand Graduate Institute of Science and Technology (TGIST), the National Nanotechnology Center (NANOTEC), the National Science and Technology Development Agency (NSTDA); Department of Chemistry and Department of Physics and Materials Science, Faculty of Science; and the Graduate School Chiang Mai University.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Natda Wetchakun.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Lamdab, U., Wetchakun, K., Phanichphant, S. et al. Highly efficient visible light-induced photocatalytic degradation of methylene blue over InVO4/BiVO4 composite photocatalyst. J Mater Sci 50, 5788–5798 (2015). https://doi.org/10.1007/s10853-015-9126-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10853-015-9126-6

Keywords

Navigation