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Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis

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Abstract

The influence of the size of conjugated π-system on catalytic activity of cobalt complex with β-octaphenylporphyrin and its tetraaza-, tetrabenzo and tetrabenzotetraaza derivatives was studied in present work. It is found that catalytic activity for oxidation of sulfur-containing compounds increases under extension of conjugated macrocycle system according to the following series CoP < CoBP ≤ CoPz < CoPPz ≪ CoPc.

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Acknowledgements

The synthesis, extraction and purification of investigated compounds and materials based on it were financially supported by Russian Science Foundation (project 14-23-00204), physical and chemical researches were partially supported by Russian President’s grant for young scientists—PhD (MK-2776.2015.3).

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    Artur Vashurin, Ilya Kuzmin & Svetlana Pukhovskaya

  2. Research Institute of Macroheterocycles, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    Artur Vashurin, Mikhail Razumov & Oscar Koifman

  3. Department of Technology of Fine Organic Synthesis, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    Vladimir Maizlish

  4. Department of Organic Chemistry, Ivanovo State University of Chemistry and Technology, 153000, Ivanovo, Russia

    Oleg Petrov & Oleg Golubchikov

  5. Kazan Federal University, 420008, Kazan, Russia

    Artur Vashurin

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Vashurin, A., Maizlish, V., Kuzmin, I. et al. Aza-substitution, benzo-annulation effects and catalytic activity of β-octaphenyl-substituted tetrapyrrolic macroheterocyclic cobalt complexes. I. heterogeneous catalysis. J Incl Phenom Macrocycl Chem 87, 37–43 (2017). https://doi.org/10.1007/s10847-016-0674-4

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