We have studied the spectral luminescent properties of Tb(III) and Eu(III) complexes with a number of novel derivatives of oxoquinoline-3-carboxylic acid amides (L1–L5 ). We have observed quenching of the luminescence of 1:1 Tb(III)–L1–5 complexes by hemoglobin (Hb), which is explained by resonance energy transfer of electronic excitation from the donor (Tb(III)–L1–5 ) to the acceptor (Hb). Using the novel luminescent probe Tb(III)–L1, we have developed a method for determining Hb in human blood. The calibration Stern–Volmer plot is linear in the Hb concentration range 0.6–36.0 μg/mL, detection limit 0.2 μg/mL (3·10–9 mol/L).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 4, pp. 616–621, July–August, 2014.
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Yegorova, A.V., Leonenko, I.I., Aleksandrova, D.I. et al. Novel Luminescent Probe Based on a Terbium(III) Complex for Hemoglobin Determination. J Appl Spectrosc 81, 672–677 (2014). https://doi.org/10.1007/s10812-014-9988-4
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DOI: https://doi.org/10.1007/s10812-014-9988-4