Mechanical activation of the inorganic polymer fl int and its mixtures with sevilen and polyamide polymers and SiO2 nanoparticles was studied using IR spectroscopy and x-ray phase analysis. It was found that active acidic centers appeared on the fl int surface during mechanical activation. Adsorbed water did not form H-bonds to them. Sevilen reacted with fl int during mechanical activation. SiO2 nanoparticles did not affect mechanical activation of flint. Polyamide did not react mechanochemically with flint, in contrast with sevilen.
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A. A. Okhlopkova, A. V. Vinogradov, and L. S. Pinchuk, Plastics Filled with Ultradispersed Inorganic Compounds [in Russian], IMMS NANB, Gomel (1999), pp. 16–17.
V. V. Mikhailova, in: Proceedings of the Republic Scientifi c-Technical Conference "Regional Industry: Problems and Prospects of Innovation" [in Russian], May 19–20, 2011, Grodno Gos. Univ., Grodno (2011), pp. 18–25.
E. V. Ovchinnikov, I. Yu. Larin, and V. A. Struk, in: Proceedings of the IInd International Conference on Waste-Tech Waste Management "Composite Construction Materials Based on Regenerated Thermoplasts Filled with Inorganic Modifi ers" [in Russian], June 5–8, 2001, Moscow, SIBIKO International (2001), p. 211.
E. I. Eisymont, E. V. Ovchinnikov, and T. F. Grigor’eva, Vesn. Grodzensk. Dzyarzh. Univ., Ser. 6, Tekh., 141, No. 4, 101–112 (2012).
A. A. Ryskunov, in: Proceedings of the Republic Scientifi c-Technical Conference "Regional Industry: Problems and Prospects of Innovation" [in Russian], May 19–20, 2011, Grodno Gos. Univ., Grodno (2011), pp. 31–49.
E. L. Kalinichev, E. A. Militskova, and Yu. V. Tsvetkova, in: NII TEKhIM Collected Works "Polyamide Construction Materials" [in Russian], Moscow (1986), pp. 175–177.
V. S. Osipchik, A. V. Sukhinina, and Yu. A. Gur′ev, Plast. Massy, No. 6, 31–33 (2008).
A. L. Smith, Applied Infrared Spectroscopy: Fundamentals, Techniques, and Analytical Problem Solving, John Wiley and Sons, New York (1979) [Russ. transl. pp. 93–95].
I. I. Plyusnina, Infrared Spectra of Minerals [in Russian], MGU, Moscow (1977), pp. 51–76.
T. G. Balicheva and O. A. Lobaneva, Electronic and Vibrational Spectra of Inorganic and Coordination Compounds [in Russian], LGU, Leningrad (1983), pp. 55–59.
I. A. Vorsina, T. F. Grigor’eva, A. P. Barinova, and N. Z. Lyakhov, Khim. Interesakh Ustoich. Razvit., 19, No. 1, 1–10 (2011).
G. V. Yukhnevich, Infrared Spectroscopy of Water [in Russian], Nauka, Moscow (1973), pp. 67–110.
A. Ikekawa and S. Hayakawa, Sib. Khim. Zh., No. 5, 19–24 (1991).
N. Z. Lyakhov, I. A. Vorsina, T. F. Grigorieva, T. A. Udalova, S. V. Vosmerikov, E. V. Ovchinnikov, and V. A. Struk, in: Proceedings of the 12th Israeli-Russian Bi-National Workshop "The Optimization of the Composition, Structure and Properties of Metals, Oxides, Composites, Nano and Amorphous Materials," Jerusalem, Tel-Aviv, Ariel (Israel), July 8–10, (2013), pp. 42–48.
N. I. Baramboim, Mechanochemistry of High-Molecular-Weight Compounds [in Russian], Khimiya, Moscow (1978), pp. 13–47.
S. Yariv and H. Cross, Organo-Clay Complexes and Interaction, Marcel Dekker Inc., New York, Basel (1989), pp. 34–101.
I. A. Vorsina, T. F. Grigor’eva, T. A. Udalova, S. V. Vosmerikov, E. V. Ovchinnikov, V. A. Struk, and N. Z. Lyakhov, Zh. Prikl. Spektrosk., 81, No. 2, 250–255 (2014).
I. A. Vorsina, T. F. Grigor’eva, T. A. Udalova, S. V. Vosmerikov, V. A. Struk, E. V. Ovchinnikov, and N. Z. Lyakhov, Khim. Interesakh Ustoich. Razvit., 22, No. 1, 17–23 (2014).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 5, pp. 717–722, September–October, 2014.
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Vorsina, I.A., Grigoreva, T.F., Udalova, T.A. et al. IR Spectroscopic Study of the Mechanical Activation of Flint and its Mixtures with SiO2 Nanoparticles and Polymers. J Appl Spectrosc 81, 789–794 (2014). https://doi.org/10.1007/s10812-014-0007-6
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DOI: https://doi.org/10.1007/s10812-014-0007-6