Abstract
A new model based on rough hard-sphere theory is proposed for the thermal conductivity of molten salts. The model incorporates a smooth hard-sphere contribution using the properties of argon, as well as characteristic parameters based on the melting point of the molten salt. It is demonstrated that it is possible to correlate the thermal conductivity of monovalent and multivalent molten salts within experimental error using this approach. Furthermore, in salts with a common anion, the single adjustable parameter in the model exhibits regular behavior with the molecular weight of the salt. It is also shown that the thermal conductivity of several molten-salt mixtures can be predicted without any mixture parameters.
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References
E.A. Smol’nikov, L.M. Sarmanova, A.A. Lukhvich, V.I. Sharando, Met. Sci. Heat Treat. 29, 131 (1987)
R.E. Thoma, B.J. Sturm, E.H. Guinn, Molten-Salt Solvents for Fluoride Volatility Processing of Aluminium-Matrix Nuclear Fuel Elements (Oak Ridge National Laboratory, Oak Ridge, TN, 1964)
Q. Peng, X. Yang, J. Ding, X. Wei, J. Yang, Appl. Energy 112, 682 (2013)
T. Bauer, N. Pfleger, N. Breidenbach, M. Eck, D. Laing, S. Kaesche, Appl. Energy 111, 1114 (2013)
J.W. Raade, D. Padowitz, J. Sol. Energy 133, 031013 (2011)
N. Ohtori, T. Oono, K. Takase, J. Chem. Phys. 130, 044505 (2009)
R.M. DiGuilio, A.S. Teja, Int. J. Thermophys. 13, 855 (1992)
P.W. Bridegman, The Physics of High Pressures (G. Bell and Sons Ltd., London, 1949)
J.F. Kincaid, H. Eyring, J. Chem. Phys. 6, 620 (1938)
Y. Nagasaka, A. Nagashima, Int. J. Thermophys. 12, 769 (1991)
A.G. Turnbull, Aust. J. Appl. Sci. 9, 324 (1961)
M.R. Rao, J. Chem. Phys. 9, 120 (1941)
L.R. White, H.T. Davis, J. Chem. Phys. 47, 5433 (1967)
R.E. Young, J.P. O’Connell, Ind. Eng. Chem. Fundam. 10, 418 (1971)
D. Chandler, J. Chem. Phys. 62, 1358 (1975)
S.F.Y. Li, R.D. Trengove, W.A. Wakeham, M. Zalaf, Int. J. Thermophys. 7, 273 (1986)
M.J. Assael, J.H. Dymond, M. Papadaki, P.M. Patterson, Int. J. Thermophys. 13, 269 (1992)
M.J. Assael, J.H. Dymond, M. Papadaki, P.M. Patterson, Fluid Phase Equilib. 75, 245 (1992)
M.J. Assael, J.H. Dymond, P.M. Patterson, Int. J. Thermophys. 13, 895 (1992)
M.J. Assael, J.H. Dymond, S.K. Polimatidou, Int. J. Thermophys. 15, 189 (1994)
M.J. Assael, J.H. Dymond, S.K. Polimatidou, Int. J. Thermophys. 16, 761 (1995)
T. Sun, A.S. Teja, J. Chem. Eng. Data 54, 2527 (2009)
Y.S. Touloukian, P.E. Liley, S.C. Saxena (eds.), Thermal Conductivity of Argon. Nonmetallic Liquids and Gases. Thermal Conductivity (IFI/Plenum Press, New York, 1970)
B.A. Younglove, H.J.M. Hanley, J. Phys. Chem. Ref. Data 15, 1323 (1986)
H.M. Roder, C.A. Nieto de Castro, U.V. Mardolcar, Int. J. Thermophys. 8, 521 (1987)
V.A. Rabinovich, A.A. Wasserman, V.I. Nedostup, L.S. Veksler, Properties of Neon, Argon, Krypton and Xenon (IZD Standartov, Moscow, 1976); translation from Russian in Monograph of the National Standard Reference Data Service of the USSR (Hemisphere Publishing Co., New York, 1988)
Y. Nagasaka, N. Nakazawa, A. Nagashima, Int. J. Thermophys. 13, 555 (1992)
S. Kitade, Y. Kobayashi, A. Nagashima, High Temp. High Press. 21, 219 (1989)
N. Nakazawa, Y. Nagasaka, A. Nagashima, Int. J. Thermophys. 13, 763 (1992)
N. Nakazawa, Y. Nagasaka, A. Nagashima, Int. J. Thermophys. 13, 753 (1992)
G.J. Janz, Molten Salts Handbook (Academic Press, New York, 1967)
R. Tufeu, J.P. Petitet, L. Denielou, B. Neindre, Int. J. Thermophys. 6, 315 (1985)
T. Omotani, Y. Nagasaka, A. Nagashima, Int. J. Thermophys. 3, 17 (1982)
M.V. Smirnov, V.A. Khokhlov, E.S. Filatov, Electrochim. Acta 32, 1019 (1987)
T. Omotani, A. Nagashima, J. Chem. Eng. Data 29, 1 (1984)
Acknowledgments
Partial support for this research was provided by the United States Department of Energy (Award # DE-EE0005942) and the Grassman Foundation.
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Hossain, M.Z., Kassaee, M.H., Jeter, S. et al. A New Model for the Thermal Conductivity of Molten Salts. Int J Thermophys 35, 246–255 (2014). https://doi.org/10.1007/s10765-014-1573-9
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DOI: https://doi.org/10.1007/s10765-014-1573-9