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Mössbauer study of stability and growth confinement of magnetic Fe3 O 4 drug carrier

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Abstract

Bare Fe3O4 and Fe3O4/zeolite composites have been investigated by Mössbauer spectroscopy. A confined growth of the nanoparticles has been observed after introduction of zeolite in the process of precipitation. Increase in the concentration of zeolite further decrease the particle size. A comparative study on the synthesis with zeolites 13x and ZSM5 has been done. Annealing on these nanoparticles shows that apart from the confinement of nanoparticles, zeolite enhances stability on the nanoparticles.

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References

  1. Candiani, A., Konstantaki, M., Margulis, W., Pissadakis, S.: A spectrally tunable microstructured optical fibre Bragg grating utilizing an infiltrated ferrofluid. Optics Express 18, 24654 (2010)

    Article  ADS  Google Scholar 

  2. Zhang, J., Zhao, S., Zhu, M., Zhu, Y., Zhang, Y., Liud, Z., Zhang, C.: 3D-printed magnetic Fe3O4/MBG/PCL composite scaffolds with multifunctionality of bone regeneration, local anticancer drug delivery and hyperthermia. J. Mater. Chem. B 2, 7583 (2014)

    Article  Google Scholar 

  3. Dib, S., Boufatit, M., Chelouaou, S., Sadi-Hassaine, F., Croissant, J., Long, J., Raehm, L., Charnay, C., Durand, J.O.: Versatile heavy metals removal via magnetic mesoporous nanocontainers. RSC Adv. 4, 24838 (2014)

    Article  Google Scholar 

  4. Lee, S.H., Yu, S.-H., Lee, J.E., Jin, A., Lee, D.J., Lee, N., Jo, H., Shin, K., Ahn, T.-Y, Kim, Y.-W., Choe, H., Sung, Y.-E., Hyeon, T.: Self-Assembled Fe3O4 nanoparticle clusters as high-performance anodes for lithium ion batteries via geometric confinement. Nano Lett. 13, 4249 (2013)

    Article  Google Scholar 

  5. Bello, S.M., Luckie, R.A.M., Santos, L.F., Hinestroza, J.P., Mendieta, V.S.: Size-controlled synthesis of Fe2O3 and Fe3O4 nanoparticles onto zeolite by means of a modified activated-coprecipitation method: effect of the HCl concentration during the activation. J. Nanopart. Res. 14, 1242 (2012)

    Article  Google Scholar 

  6. Zhang, J.-M., Zhai, S.-R., Zhai, B., An, Q.-D., Ge, T.: Crucial factors affecting the physicochemical properties of sol–gel produced Fe3O4@SiO2–NH2 core–shell nanomaterials. J. Sol-Gel Sci. Technol. 64, 347 (2012)

    Article  Google Scholar 

  7. Zheng, J., Liu, Z.Q., Zhao, X.S., Liu, M., Liu, X., Chu, W.: One-step solvothermal synthesis of Fe3O4@C core–shell nanoparticles with tunable sizes. Nanotechnology 23, 165601 (2012)

  8. Lei, P., Boies, A.M., Calder, S., Girshick, S.L.: Thermal plasma synthesis of superparamagnetic iron oxide nanoparticles. Plasma Chem. Plasma Process 32, 519 (2012)

    Article  Google Scholar 

  9. Yao, Y., Jiang, H., Wu, J., Gu, D., Shen, L.: Synthesis of Fe3O4 /polyaniline nanocomposite in reversed micelle systems and its performance characteristics. Procedia Eng. 27, 664 (2012)

    Article  Google Scholar 

  10. Alam, S., Anand, C., Ariga, K., Mori, T., Vinu, A.: Unusual magnetic properties of size-controlled iron oxide nanoparticles grown in a nanoporous matrix with tunable pores. Angew. Chem. 121, 7494 (2009)

    Article  Google Scholar 

  11. Gal, I.J., Radovano, P.: Ion-exchange Equihbria of Synthetic 13X Zeolite with Ni2+, Co2+, Zn 2+ and Cd2+ Ions. J. Chem. Soc., Faraday Trans. I 71, 1671 (1975)

    Article  Google Scholar 

  12. Arruebo, M., Pacheco, R.F., Irusta, S., Arbiol, J., Ibarra, M.R., Santamaria, J.: Sustained release of doxorubicin from zeolite–magnetite nanocomposites prepared by mechanical activation. Nanotechnology 17, 4057 (2006)

    Article  ADS  Google Scholar 

  13. Habrowska, A.M., Popiel, E.S.: Positron annihilation in zeolite 13X. J. Appl. Phys. 62, 15 (1987)

    Article  Google Scholar 

  14. Kokotailo, G.T., Lawton, S.L., Olson, D.H., Meier, W.M.: Structure of synthetic zeolite ZSM-5. Nature 272, 437 (1978)

    Article  ADS  Google Scholar 

  15. Zahmakiran, M., Ozkar, S.: Zeolite-confined ruthenium(0) nanoclusters catalyst: record catalytic activity, reusability, and lifetime in hydrogen generation from the hydrolysis of sodium borohydride. Langmuir 25, 2667 (2009)

    Article  Google Scholar 

  16. Zahmakiran, M., Durap, F., Ozkar, S.: Zeolite confined copper(0) nanoclusters as cost-effective and reusable catalyst in hydrogen generation from the hydrolysis of ammonia-borane. Int. J. Hydrog. Energy 35, 187 (2010)

    Article  Google Scholar 

  17. Erdem, E., Karapinar, N., Donat, R.: The removal of heavy metal cations by natural zeolites. J. Colloid Interface Sci. 280, 309 (2004)

    Article  Google Scholar 

  18. Babarao, R., Jiang, J.: Unprecedentedly High selective adsorption of gas mixtures in rho zeolite-like metal-organic framework: A molecular simulation study. J. Am. Chem. Soc. 131, 11417 (2009)

    Article  Google Scholar 

  19. Kuznicki, S.M., Bell, V.A., Nair, S., Hillhouse, H.W., Jacubinas, R.M., Braunbarth, C.M., Toby, B.H., Tsapatsisl, M.: A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules. Nature 412, 720 (2001)

    Article  ADS  Google Scholar 

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Authors and Affiliations

  1. Institute of Physics, University of Brasília, 70910-970, Brasília, DF, Brazil

    L. Herojit Singh, S. S. Pati, A. C. Oliveira & V. K. Garg

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  1. L. Herojit Singh
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  2. S. S. Pati
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  3. A. C. Oliveira
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  4. V. K. Garg
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Correspondence to L. Herojit Singh.

Additional information

Proceedings of the 14th Latin American Conference on the Applications of the Mössbauer Effect (LACAME 2014), Toluca, Mexico, 10-14 November 2014

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Herojit Singh, L., Pati, S.S., Oliveira, A.C. et al. Mössbauer study of stability and growth confinement of magnetic Fe3 O 4 drug carrier. Hyperfine Interact 232, 79–85 (2015). https://doi.org/10.1007/s10751-014-1105-9

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