Abstract
In this communication, we introduce a chitosan polymer gel ionic actuator with dilute acid as electrolyte solution replacing ionic liquid. Interestingly, the switch not only produces obvious improvements in actuation performance, but the actuator bends towards the opposite direction. It presents a cathode deflection phenomenon instead of the usual anode deflection. Moreover, ion channels inside the electrolyte layer are obtained through a natural crosslinking treatment, so it allows an effective ions transportation inside the electrolyte layer.
References
Bar-Cohen Y, Zhang Q (2008) Electroactive polymer actuators and sensors. MRS Bull 33(03):173–181
Baughman RH (2005) Playing nature’s game with artificial muscles. Science 308(5718):63–65
Cai Z, Kim J (2008) Characterization and electromechanical performance of cellulose–chitosan blend electro-active paper. Smart Mater Struct 17(3):035028
Chen SC, Wu YC, Mi FL (2004) A novel pH-sensitive hydrogel composed of N, O-carboxymethyl chitosan and alginate cross-linked by genipin for protein drug delivery. J Control Release 96(2):285–300
Di Martino A, Sittinger M, Risbud MV (2005) Chitosan: a versatile biopolymer for orthopaedic tissue-engineering. Biomaterials 26(30):5983–5990
dos Santos DS, Riul A, Malmegrim RR (2003) A layer-by-layer film of chitosan in a taste sensor application. Macromol Biosci 3(10):591–595
He Q, Yu M, Yang X (2015) An ionic electro-active actuator made with graphene film electrode, chitosan and ionic liquid. Smart Mater Struct 24(6):065026
Kim J, Wang N, Chen Y (2007a) Electroactive-paper actuator made with cellulose/NaOH/urea and sodium alginate. Cellulose 14(3):217–223
Kim J, Wang N, Chen Y (2007b) Effect of chitosan and ions on actuation behavior of cellulose–chitosan laminated films as electro-active paper actuators. Cellulose 14(5):439–445
Li J, Ma W, Song L (2011) Superfast-response and ultrahigh-power-density electromechanical actuators based on hierarchal carbon nanotube electrodes and chitosan. Nano Lett 11(11):4636–4641
Lu L, Chen W (2010) Biocompatible composite actuator: a supramolecular structure consisting of the biopolymer chitosan, carbon nanotubes, and an ionic liquid. Adv Mater 22(33):3745–3748
Lu L, Liu J, Hu Y (2013) Graphene-stabilized silver nanoparticle electrochemical electrode for actuator design. Adv Mater 25(9):1270–1274
Moura MJ, Figueiredo MM, Gil MH (2007) Rheological study of genipin cross-linked chitosan hydrogels. Biomacromolecules 8(12):3823–3829
Neto CGT, Dantas TNC, Fonseca JLC (2005) Permeability studies in chitosan membranes. Effects of crosslinking and poly (ethylene oxide) addition. Carbohyd Res 340(17):2630–2636
Pujana MA, Pérez-Álvarez L, Iturbe LCC (2013) Biodegradable chitosan nanogels crosslinked with genipin. Carbohyd Polym 94(2):836–842
Roundy S, Wright PK (2004) A piezoelectric vibration based generator for wireless electronics. Smart Mater Struct 13(5):1131
Acknowledgments
This work was supported by the National Natural Science Foundation of China (NSFC) (51675112).
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Sun, Z., Zhao, G. & Song, W. A naturally crosslinked chitosan based ionic actuator with cathode deflection phenomenon. Cellulose 24, 441–445 (2017). https://doi.org/10.1007/s10570-016-1161-1
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DOI: https://doi.org/10.1007/s10570-016-1161-1