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An Effective Co-promoted Platinum of Co–Pt/SBA-15 Catalyst for Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol

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Abstract

Pt–Co alloy supported on SBA-15 catalysts (Pt–Co/SBA-15) were prepared by impregnation and NaBH4 reduction method. Their catalytic performances were investigated for selective hydrogenation of cinnamaldehyde. It was found that the formation of Pt–Co markedly enhanced the conversion to cinnamaldehyde and selectivity to cinnamyl alcohol compared with Pt/SBA-15. Meanwhile, the Pt–Co/SBA-15-0.6 catalyst performed the best catalytic activity that 71 % CAL conversion and 91 % selectivity to COL were attained. Moreover, no obvious deactivation was observed after using 4 times for Pt–Co/SBA-15-0.6. This improvement was contributed to the formation of Pt–Co alloy, which increased the amount of the Pt0 species on the catalysts.

Graphical Abstract

Pt–Co alloy supported on SBA-15 catalyst shows excellent catalytic selective hydrogenation of cinnamaldehyde to cinnamyl alcohol

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Acknowledgments

This work is supported by Natural Sciences Fund of Heilongjiang Province (B2015009) and Postdoctoral Science-Research Developmental Foundation of Heilongjiang Province of China (LBH-Q12022). The Project sponsored by SRF for ROCS, Ministry of Human Resources and Social Security (2013-277), Innovative Research Project of Key Laboratory of Functional Inorganic Material Chemistry (Heilongjiang University), Ministry of Education (2015).

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Authors and Affiliations

  1. Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, School of Chemistry and Materials, Heilongjiang University, Harbin, 150080, People’s Republic of China

    Que Zheng, Dong Wang, Fulong Yuan, Qing Han, Yongli Dong, Yunfei Liu, Xiaoyu Niu & Yujun Zhu

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  1. Que Zheng
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  2. Dong Wang
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  3. Fulong Yuan
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  4. Qing Han
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  6. Yunfei Liu
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  7. Xiaoyu Niu
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  8. Yujun Zhu
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Correspondence to Xiaoyu Niu or Yujun Zhu.

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Zheng, Q., Wang, D., Yuan, F. et al. An Effective Co-promoted Platinum of Co–Pt/SBA-15 Catalyst for Selective Hydrogenation of Cinnamaldehyde to Cinnamyl Alcohol. Catal Lett 146, 1535–1543 (2016). https://doi.org/10.1007/s10562-016-1779-5

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