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Selective Hydrogenation of Cinnamaldehyde over Pt/ZrO2 Catalyst Modified by Cr, Mn, Fe, Co and Ni

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Hydrogenation properties of cinnamaldehyde (CMA) have been studied over Pt/ZrO2 and PtM/ZrO2 catalysts (M = Cr, Mn, Fe, Co and Ni) in ethanol at 343 K and 2.0 MPa. The effect of different content of Ni and base has also been investigated over PtNi/ZrO2 catalyst. With introduction of transition metals to Pt/ZrO2 catalyst shows a significant influence on the catalytic properties. PtCo/ZrO2 catalysts show the best yield of cinnamyl alcohol (CMO), and PtNi/ZrO2 catalyst shows good yield of hydrocinnamaldehyde (HCMA). In the presence of base solution, rate of the hydrogenation of CMA over PtNi/ZrO2(0.4 wt%) catalyst increases significantly and side reaction is remarkably inhibited. More bare metal atoms situated remote from the interface region on PtNi/ZrO2 catalyst surface are the reason of good selectivity of HCMA for PtNi/ZrO2 catalyst.

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  1. Institute of Catalysis, Zhejiang University, Hangzhou, 310028, P.R. China

    Xiaoxiang Han, Renxian Zhou, Baohua Yue & Xiaoming Zheng

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  1. Xiaoxiang Han
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  2. Renxian Zhou
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  4. Xiaoming Zheng
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Han, X., Zhou, R., Yue, B. et al. Selective Hydrogenation of Cinnamaldehyde over Pt/ZrO2 Catalyst Modified by Cr, Mn, Fe, Co and Ni. Catal Lett 109, 157–161 (2006). https://doi.org/10.1007/s10562-006-0080-4

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  • DOI: https://doi.org/10.1007/s10562-006-0080-4

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