Skip to main content
Log in

Dispersion production by semi-continuous radical vinyl acetate emulsion polymerization with silane co-monomer and characterization of final products

  • Paper
  • Published:
Chinese Journal of Polymer Science Aims and scope Submit manuscript

Abstract

Vinyl acetate radical emulsion polymerization in water with GF51 silane co-monomer was performed by semi continuous way. The GF51 impacts on dispersion rheology as well on films and bonding strength properties were determined. It should be stated that even low quantities of GF51 (up to 6% from VAc) determined high viscosity of dispersions. The GF51 modified films have low water absorption and high affinity to glass. Molecular mass and thermal properties of GF51 modified polymers were determined accordingly.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Tonnar, J., Pouget, E., Lacroix-Desmazers., P. and Boutevin, B., Eur. Polym. J., 2008, 44: 318

    Article  CAS  Google Scholar 

  2. Maynard, D.H., Lyu, S.P., Fredrickson, H.G., Wudl, F. and Chmelka, F.B., Polymer, 2001, 42: 7567

    Article  CAS  Google Scholar 

  3. Jia, X., Li, Y., Cheng, Q., Zhang, S. and Zhang, B., Eur. Polym. J., 2007, 43: 1123

    Article  CAS  Google Scholar 

  4. Kruenate, J., Tongpool, R. and Kongrat, P., Journal of Metastable and Nanocrystalline Materials, 2005, 23: 227

    Article  CAS  Google Scholar 

  5. Nguyen, V., Yoshida, W. and Cohen, Y., J. Appl. Polym. Sci., 2002, 87(2): 300

    Article  Google Scholar 

  6. Geniosil GF51 Material Safety Data Sheet for US market, http://sdb.wacker.com/pf/e/result/report.jsp?PLANGU=E&PSYS=2&PSSN=490&PREP=00000000000000000030&PRES=1172&PSPEC=R, Cited 9 July 2012

  7. Mitschka, P., Reological Acta, 1982, 21: 207

    Article  CAS  Google Scholar 

  8. Brandrup, J., Immergut, E.H. and Grulke, E.A., in “Polymer handbook, fourth edition”, John Wiley & Sons, New York, VII-68, 1999

    Google Scholar 

  9. Sheen Pendulum Hardness Rocker datasheet, http://www.sheeninstruments.com/datasheets/pen2.pdf, Cited 9 July 2012

  10. Woodward, P.R., Contact Angle Measurements Using the Drop Shape Method, http://www.firsttenangstroms.com/pdfdocs/CAPaper.pdf, Cited 9 July 2012

  11. Naghash, H.J., Mallakpour, S. and Mokhtarian, N., Prog. Org. Coat., 2006, 55: 375

    Article  CAS  Google Scholar 

  12. Petrie, E.M., in “Handbook of adhesives and sealants, Vol. 2”, McGraw-Hill, New York, 2007, p. 290

    Google Scholar 

  13. Liu, X.H., Yi, S.P., Li, H.B. and Huang, C., Iranian Polym. J., 2007, 16(3): 207

    CAS  Google Scholar 

  14. Zhou, X.H., Tu, W.P. and Xia, Z.P., J. Mater. Prot., 2004, 37: 21

    CAS  Google Scholar 

  15. O’Donnell, T., Mesrobian, R.B. and Woodward, A.E., J. Polym. Sci., 1958, 28(116): 171

    Article  Google Scholar 

  16. Bataille, P., Van, B.T. and Pham, Q.B., J. Appl. Polym. Sci., 1978, 22: 3145

    Article  CAS  Google Scholar 

  17. Friis, N., “A kinetic study of the emulsion polymerization of vinyl acetate”, Thesis, Technical University of Denmark, Lyngby, 1973

    Google Scholar 

  18. Donescu, D., Gosa, K., Diaconescu, I., Mazare, M. and Carp, N., in “Emulsion polymerization of vinyl acetate”, eds. by El-Aasser, M.S. and Vanderhoff, J.W., Applied Science Publishers, London, 1981, p. 203

    Chapter  Google Scholar 

  19. Donescu, D., Gosa, K., Ciupitoiu, A. and Languri, I., J. Macromol. Sci., Chem., 1985, A22: 931

    CAS  Google Scholar 

  20. Zhu, M.Y., Qiao, W.H., Liu, H.Z. and Sun, Y.L., J. Appl. Polym. Sci., 2008, 107: 624

    Article  CAS  Google Scholar 

  21. European Standard EN 204 “Classification of thermoplastic wood adhesives for non-structural applications”, 2005

  22. Vick, C.B., “Adhesive bonding of wood materials”, in “Wood handbook: wood as an engineering material”, Chapter 9, Gen. Tech. Rept. FPL-GRT-113. USDA Forest Serv., Forest Prod. Lab., Madison, WI, 1999, p. 2, http://www.esf.edu/scme/wus/documents/WoodHandbook-fplgtr113.pdf, Cited 9 July 2012

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mindaugas Dubininkas.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Dubininkas, M., Buika, G. Dispersion production by semi-continuous radical vinyl acetate emulsion polymerization with silane co-monomer and characterization of final products. Chin J Polym Sci 31, 346–354 (2013). https://doi.org/10.1007/s10118-013-1220-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10118-013-1220-0

Keywords

Navigation