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Enhanced lithium ionic intercalation and conduction performance of flexible iron oxide films using an atmospheric pressure plasma jet

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Abstract

Enhancement on lithium ionic intercalation and conduction performance of flexible-organo-iron oxide (FeO y C z ) films, via a rapid co-synthesis with lithium oxides (LiO y C z ) onto 40 ohm/square flexible polyethylene terephthalate/indium tin oxide substrates at a short exposed duration of 35 s, using an atmospheric pressure plasma jet (APPJ) by mixed ferrocene [Fe(C5H5)2] and lithium tert-butoxide [(CH3)3COLi] precursors, was investigated. APPJ-synthesized-lithiated iron oxide (Li x FeO y C z ) films exhibit the prominent Li+ ionic intercalation performance in a 1 M LiClO4-propylene carbonate electrolyte potential analyzed both by potential sweep and potential step in situ Li+ ionic intercalation. The important Li+ ionic conduction performance of APPJ-synthesized Li x FeO y C z films is proven by electrochemical impedance spectroscopy in the device of PET/ITO/NiO x /Li x FeO y C z /NiO x /ITO. The Li+ ionic diffusion coefficient and conductivity of 1.16 × 10−10 cm2/s and 9.7 × 10−10 S/cm for FeO y C z films are, respectively, improved to 3.89 × 10−10 cm2/s and 838.0 × 10−10 S/cm for Li x FeO y C z films even after being bent 360° around a 2.5-cm-diameter rod for 1000 cycles.

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Acknowledgements

This study was supported by the Ministry of Science and Technology of the Republic of China (MOST104-2221-E-035-076 and MOST105-2221-E-035-089).

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Authors and Affiliations

  1. Department of Chemical Engineering, Feng Chia University, No.100, Wenhwa Road., Seatwen, Taichung, 40724, Taiwan, Republic of China

    Yung-Sen Lin, Sheng-Wei Lin, Pin-Cheng Chen, Yin-Li Wang & Min-Chin Liao

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  1. Yung-Sen Lin
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  2. Sheng-Wei Lin
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Correspondence to Yung-Sen Lin.

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Lin, YS., Lin, SW., Chen, PC. et al. Enhanced lithium ionic intercalation and conduction performance of flexible iron oxide films using an atmospheric pressure plasma jet. J Solid State Electrochem 21, 2185–2200 (2017). https://doi.org/10.1007/s10008-017-3551-1

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  • DOI: https://doi.org/10.1007/s10008-017-3551-1

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