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Voltammetry of benzodiazepines on meniscus-modified silver solid amalgam electrode

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Abstract

This paper describes voltammetric behavior of 1,4-benzodiazepines (BDZs) on meniscus-modified silver solid amalgam electrode with aim of their determination. Cyclic voltammetry was used for the study of electrochemical behavior (reversibility, adsorption-diffusion process, and charge transfer coefficient) of BDZs. Differential pulse voltammetry was utilized for proposing reaction mechanism, finding supporting electrolyte with optimal pH, and determining diazepam in urine. The pH effect was studied in different media (Britton-Robinson, phosphate, citrate buffer, and 0.1 mol dm−3 NaOH). The calibration dependences exhibited good linearity in the range from 10−7 to 10−4 mol dm−3 under the optimum pH conditions. The advantage of the developed methods was simple, fast, and low-cost procedure for the determination of BDZs. The developed method was successfully used for the diazepam determination in the model sample of urine. The proposed method exhibits the recovery 97.8 % with standard deviation of 2.28 %.

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Acknowledgments

The authors are grateful for the financial support of the projects SGS05/PřF/2014 (Ostrava University), MSK DT3 02679/2014/RRC (Moravian-Silesian Region, Science and Research Grant), MŠMT ČR (The Ministry of Education, Youth and Sports, MSM 0021620857), and Grant Agency of the Czech Republic (Czech Science Foundation, Project P206/12/G151).

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, University of Ostrava, 30. dubna 22, 701 03, Ostrava, Czech Republic

    Petr Samiec & Zuzana Navrátilová

  2. Charles University in Prague, Faculty of Science, Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Hlavova 2030/8, 128 43, Prague 2, Czech Republic

    Jan Fischer

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  1. Petr Samiec
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  2. Zuzana Navrátilová
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  3. Jan Fischer
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Correspondence to Petr Samiec.

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Samiec, P., Navrátilová, Z. & Fischer, J. Voltammetry of benzodiazepines on meniscus-modified silver solid amalgam electrode. Monatsh Chem 147, 127–134 (2016). https://doi.org/10.1007/s00706-015-1594-5

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  • DOI: https://doi.org/10.1007/s00706-015-1594-5

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