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Explosive style, magma degassing and evolution in the Chaimilla eruption, Villarrica volcano, Southern Andes

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Abstract

Villarrica (Chile) is a basaltic stratovolcano, currently in an open-conduit condition. It now has relatively frequent Strombolian and effusive eruptions, but it had large explosive eruptions in prehistoric times. Among them, the most recent eruption was Chaimilla, which occurred about 3100 years ago and produced deposits that indicate complex, multiphase eruptive dynamics. Significant differences in mineralogy and glass compositions of the erupted scoria suggest the eruption was fed by two distinct magma batches with similar bulk compositions but distinct crystallization and degassing histories. The lower sequence scoria has a complex crystal assemblage with several crystal populations produced by mixing between a relatively degassed magma containing Fo75-79 olivine, normally or reversely zoned plagioclase (An70-94) and augite (type 1 magma), and a subordinate volume of more-primitive and more volatile-rich magma rising from depth (type 2 magma) and carrying normally zoned plagioclase and higher-Mg (Fo81-85) olivine crystals. Type 2 magma was the main component emitted during the larger and more explosive eruptive phase that deposited the upper sequence. The Chaimilla eruption occurred under closed-vent conditions and was fed by water-rich magmas. When compared with the petrological features of the magma currently erupted at Villarrica, which has slightly more-evolved bulk compositions, lower crystal content and lower water content, these results suggest that the evolution in eruptive style of the volcano from highly explosive to a lava lake/Strombolian activity corresponds to significant changes in the shallow plumbing system (which is now at much shallower depths); these plumbing-system changes were not associated with significant changes in the parental magma compositions.

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References

  • Anderson AT (1991) Hourglass inclusions: theory and application to the Bishop rhyolitic tuff. Am Mineral 76:530–547

    Google Scholar 

  • Asimow PD, Ghiorso MS (1998) Algorithmic modifications extending MELTS to calculate subsolidus phase relations. Am Mineral 83:1127–1132

    Google Scholar 

  • Baker RD (2008) The fidelity of melt inclusions as records of melt composition. Contrib Mineral Petrol 156:377–395

  • Blundy J, Cashman K (2005) Rapid decompression-driven crystallization recorded by melt inclusions from Mount St Helens volcano. Geology 33:793–796

    Article  Google Scholar 

  • Caldwell DA, Kyle PR (1994) Mineralogy and geochemistry of ejecta erupted from Mount Erebus, Antarctica, between 1972 and 1986. Ant Res Series 66:147–162

    Article  Google Scholar 

  • Cashman K.V (2004) Volatile controls on magma ascent and eruption. In: The State of the Planet: Frontiers and Challenges in Geophysics. AGU Geophys Monogr Series 150. Sparks R.S.J, Hawkesworth CJ (Eds), Washington DC, 109-124

  • Castruccio A, Clavero J, Rivera A (2010) Comparative study of lahars generated by the 1961 and 1971 eruptions of Calbuco and Villarrica volcanoes, Southern Andes of Chile. J Volcanol Geotherm Res 190:297–311

    Article  Google Scholar 

  • Cervantes P, Wallace P (2003) Magma degassing and basaltic eruption styles: a case study of ∼2000 years BP Xitle volcano in central Mexico. J Volcanol Geotherm Res 120:249–270

    Article  Google Scholar 

  • Clavero J, Moreno H (1994) Ignimbritas Licán y Pucón. Congreso Geológico Chileno, Concepción, Chile

    Google Scholar 

  • Clavero J, Moreno H (2004) Evolution of Villarrica Volcano. In: Lara LE, Clavero J (eds) Villarrica Volcano (39.5°S), Southern Andes, Chile. Servic Nac Geol Miner Bol 61:17–27

  • Costantini L, Pioli L, Bonadonna C, Clavero J, Longchamp C (2011) A late Holocene explosive mafic eruption of Villarrica volcano, Southern Andes: the Chaimilla deposit. J Volcanol Geoth Res 200:143–158

    Article  Google Scholar 

  • Danyushevsky LV, Sobolev AV (1996) Ferric-Ferrous ratios and oxygen fugacity calculations for primitive mantle derived melts: calibration of an empirical technique. Mineral Petrol 57:229–241

    Article  Google Scholar 

  • Del Carlo P, Pompilio M (2004) The relationships between volatile content and the eruptive style of basaltic magma: the Etna case. Annals Geophys 47(4). doi:10.4401/ag-4402

  • Di Muro A, Neri A, Rosi M (2004) Contemporaneous convective and collapsing eruptive dynamics: the transitional regime of explosive eruptions. Geophys Res Lett 31, L10607. doi:10.1029/2004GL019079

    Article  Google Scholar 

  • Erlund EJ, Cashman KV, Wallace, PJ, Pioli L, Rosi M, Johnson E, Delgado Granados H (2010) Compositional evolution of magma from Paricutin volcano, Mexico: the tephra record. J Volcanol Geoth Res 197:167–187

  • Ghiorso MS, Sack RO (1995) Chemical mass transfer in magmatic processes. IV. A revised and internally consistent thermodynamic model for the interpolation and extrapolation of liquid-solid equilibria in magmatic systems at elevated temperatures and pressures. Contrib Mineral Petrol 119:197–212

    Article  Google Scholar 

  • Goepfert K, Gardner JE (2010) Influence of pre-eruptive storage conditions and volatile contents on explosive Plinian style eruptions of basic magma. Bull Volcanol 72:511–521

    Article  Google Scholar 

  • Grove TL, Baker M, Price RC, Parman SW, Elkins-Tanton LT, Chatterjee N, Muentener O (2005) Magnesian andesite and dacite lavas from Mt. Shasta, northern California: products of fractional crystallization of H2O-rich mantle melts. Contrib Mineral Petrol 148:542–565

    Article  Google Scholar 

  • Gurenko AA, Belousov AB, Trumbull RB, Sobolev AV (2005) Explosive basaltic volcanism of the Chikurachki Volcano (Kurile arc, Russia): insights on pre-eruptive magmatic conditions and volatile budget revealed from phenocryst-hosted melt inclusions and groundmass glasses. J Volcanol Geotherm Res 147:203–232

    Article  Google Scholar 

  • Gurioli L, Harris AJ, Houghton BF, Polacci M, Ripepe M (2008) Textural and geophysical characterization of explosive basaltic activity at Villarrica volcano. J Geophys Res 113, B08206. doi:10.1029/2007JB005328

    Google Scholar 

  • Hamada M, Fuji T (2007) H2O-rich island arc low-K tholeiite magma inferred from Ca-rich plagioclase-melt inclusion equilibria. Geoch J 41:437–461

  • Johnson E, Wallace PJ, Cashman KV, Delgado Granados H, Kent A (2008) Volatile contents and degassing induced crystallization at Volcan Jorullo, Mexico: implications for melt evolution and the plumbing system of monogenetic volcanoes. Earth Planet Sci Lett 269:478–487

    Article  Google Scholar 

  • Kamenetsky VS, Crawford AJ, Meffre S (2001) Factors controlling chemistry of magmatic spinel: an empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocks. J Petrol 42:655–671

    Article  Google Scholar 

  • Kamenetsky VS, Pompilio M, Métrich N, Sobolev AV, Kuzmin DV, Thomas R (2007) Arrival of extremely volatile-rich High-Mg magmas changes explosivity of Mount Etna. Geology 35:255–258

    Article  Google Scholar 

  • Landi P, Francalanci L, Pompilio M, Rosi M, Corsaro RA, Petrone CM, Nardini I, Miraglia L (2006) The December 2002-July 2003 effusive event at Stromboli volcano, Italy: insights into the shallow plumbing system by petrochemical studies. J Volcanol Geotherm Res 155:263–284

    Article  Google Scholar 

  • Lara LE (2004) Overview of Villarrica Volcano. In: Lara LE, Clavero J (Eds), Villarrica volcano (39.5°S), southern Andes, Chile. Servic Nat Geol Miner Bol 61: 5-12

  • Lohmar S, Robin C, Parada MA, Gourgaud A, López-Escobar L, Moreno H, Naranjo J (2005) The two major postglacial (13-14,00 BP) pyroclastic eruptions of Llaima and Villarrica volcanoes (Southern Andes): a comparison. 6th International Symposium on Andean Geodynamics, Barcelona, extended Abstracts pp 442–445

  • Lohmar S, Parada M, Gutierrez F, Robin C, Gerbe MC (2012) Mineralogical and numerical approaches to establish the pre-eruptive conditions of the mafic Lican Ignimbrite, Villarrica volcano (Chilean Southern Andes). J Volcanol Geoth Res 235–236:55–69

    Article  Google Scholar 

  • Maurel C, Maurel P (1982) Etude expérimentale de l’equilibre Fe2+-Fe3+ dans les spinelles chromifères et les liquids silicates basiques coexistants, à 1 atm. CR Acad Sci Paris 295:209–212

    Google Scholar 

  • Melnik O (2000) Dynamics of two-phase conduit flow of high-viscosity gas-saturated magma: large variations of sustained explosive eruption intensity. Bull Volcanol 62:153–170

    Article  Google Scholar 

  • Métrich N, Bertagnini A, Di Muro A (2010) Conditions of magma storage, degassing and ascent at Stromboli: new insights into the volcano plumbing system with inferences on the eruptive dynamics. J Petrol 51:603–626

    Article  Google Scholar 

  • Moreno H, Clavero J (2006) Geología del volcán Villarrica, Regiones de la Araucanía y de los Lagos. Servicio Nacional de Geología y Minería, Carta Geologíca de Chile, Serie Geología Básica, 98, 1 mapa escala 1:50.000, Santiago

  • Moreno H, Clavero J, Lara L (1994) Actividad explosiva post-glacial del Volcan Villarrica. Andes del Sur. Septimo Congreso Geologico Chileno. Universidad de Concepcion, Concepcion, Chile, pp 329–333

    Google Scholar 

  • Newman S, Stolper, EM, Stern RJ (2000) H2O and CO2 in magmas from Mariana arc and back arc systems. Geochem Geophys Geosyst 1: 1999GC000027

  • Palma JL, Calder ES, Basualto D, Blake S, Rothery DA (2008) Correlation between SO2 flux, seismicity and outgassing activity at the open vent of Villarrica volcano, Chile. J Geophys Res 113, B10201. doi:10.1029/2008JB005577

    Article  Google Scholar 

  • Papale P, Moretti R, Barbato D (2006) The compositional dependence of the saturation surface of H2O + CO2 fluids in silicate melts. Chem Geol 229:78–95

    Article  Google Scholar 

  • Pichavant M, Mysen BO, Macdonald R (2002) Source and H2O content of high-MgO magmas in islands arc settings: an experimental study of a primitive calc-alkaline basalt from St. Vincent, Lesser Antilles arc. Geochim Cosmochim Acta 66:2193–2209

    Article  Google Scholar 

  • Putirka KD (2008) Thermometers and barometers for volcanic systems. In: Putirka KD, Tepely III (Eds.), Minerals, Inclusions and Volcanic Processes. Min Soc Am Geotherm Soc 61-120

  • Putirka K, Perfit M, Ryerson FJ, Jackson MG (2007) Ambient and excess mantle temperatures, olivine thermometry, and active vs passive upwelling. Chem Geol 241:177–206

    Article  Google Scholar 

  • Ripepe M, Bonadonna C, Marchetti E, Harris AJL, Pioli L, Ulivieri G (2010) Monochromatic infrasonic tremor driven by persistent degassing and convection at Villarrica volcano, Chile. Geophys Res Lett 37, L15303. doi:10.1029/2010GL043516

    Google Scholar 

  • Rivera A, Corripio JG, Brock B, Clavero J (2008) Monitoring ice-capped active volcan Villarrica, southern Chile, using terrestrial photography, combined with automatic weather stations and global positioning systems. J Glacial 54:920–930

    Article  Google Scholar 

  • Roggensack K, Herving RL, McKnight SB, Williams SN (1997) Explosive basaltic volcanism from Cerro Negro volcano: influence of volatiles on eruptive style. Science 277:1639–1642

    Article  Google Scholar 

  • Silva Parejas CS, Druitt TH, Robin C, Moreno H, Naranjo JA (2010) The Holocene Pucón of Volcán Villarrica, Chile: deposit architecture and éruption chronology. Bull Volcanol 72:247–259

    Article  Google Scholar 

  • Spilliaert N, Allard P, Métrich N, Sobolev AV (2006) Melt inclusion record of the conditions of ascent, degassing, and extrusion of volatile-rich alkali basalt during the powerful 2002 flank eruption of mount Etna (Italy). J Geophys Res 111:B04203

    Google Scholar 

  • Sun SS, McDonough WF (1989) Chemical and isotopic systematics of oceanic basalts: implications for mantle compositions and processes. Geol Lond Spec Pub 42:313–345

    Article  Google Scholar 

  • Toplis MJ (2004) Thermodynamics of iron and magnesium partitioning between olivine and liquid: criteria for assessing and predicting equilibrium in natural and experimental system. Contrib Mineral Petrol 149:22–39

    Article  Google Scholar 

  • Van Daele M, Moernaut J, Silversmith G, Schmidt S, Fontijn K, Heirman K, Vandoorne W, De Clercq M, Van Acker J, Woff C, Pino M, Urrutia R, Roberts SJ, Vincze L, De Batist M (2014) The 600 yr eruptive history of Villarrica Volcano (Chile) revealed by annually laminated lake sediments. Geol Soc Am Bull 126:481–498

    Article  Google Scholar 

  • Vargas R, Moreno H, Lopez L, Frey F (1989) Geochemical variations in Andean basaltic and silicic lavas from the Villarrica-Lanin volcanic chain (39.5°S): an evaluation of source heterogeneity, fractional crystallization and crustal assimilation. Cont Mineral Petrol 103:361–386

    Article  Google Scholar 

  • Villiger S, Ulmer P, Muntener O, Thompson AB (2004) The liquid line of descent of anhydrous, mantle-derived, tholeitic liquids by fractional and equilibrium crystallization- an experimental study at 1.0 GPa. J Petrol 45:2369–2388

    Article  Google Scholar 

  • Wehrmann H, Hoernle K, Garbe-Schonberg D, Jacques G, Mahlke J, Schumann K (2014) Insights from trace element geochemistry as to the roles of subduction zone geometry and subduction input on the chemistry of arc magmas. Int J Earth Sci 103:1929–1944

    Article  Google Scholar 

  • Wilson L, Sparks RSJ, Walker GPL (1980) Explosive volcanic eruptions IV. The control of magma properties and conduit geometry on eruption column behaviour. Geophys J R Astron Soc 63:117–148

    Article  Google Scholar 

  • Witter JB, Kress VC, Delmelle P, Stix J (2004) Volatile degassing, petrology, and magma dynamics of the Villarrica Lake, Southern Chile. J Volcanol Geotherm Res 134:303–337

    Article  Google Scholar 

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Acknowledgments

This work was supported by SNFS grants number 200021-116335 and 200021-122268. The authors are grateful to Oulfa Belhadj for her help in the olivine grains preparation for FTIR and micro-Raman analyses and to C. Bouvet de Maisonneuve and Y. Suzuki for fruitful discussions; R. Avanzinelli, K. Cashman and R. Cioni for constructive comments on a previous version of the manuscript; A. Mc Carthy for assistance during microprobe analyses; A. Martigner for assistance during SEM observations and A. Ulianov for assistance during collection and treatment of LA-ICP-MS data. We are also grateful to an anonymous reviewer and M. Clynne for their constructive comments and J. Fierstein and J. White for editorial handling.

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Pioli, L., Scalisi, L., Costantini, L. et al. Explosive style, magma degassing and evolution in the Chaimilla eruption, Villarrica volcano, Southern Andes. Bull Volcanol 77, 93 (2015). https://doi.org/10.1007/s00445-015-0976-1

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