Skip to main content
Log in

Analysis for sulfur compounds in lipid extracts from the orgueil meteorite

  • Technical
  • Symposium: Lipids of the Past and Present Conducted by the American Oil Chemists' Society at Its 56th Annual Meeting, Houston, Texas April 25–28, 1965
  • Published:
Journal of the American Oil Chemists’ Society

Abstract

Solvent extracts of the Orgueil carbonaceous meteorite were investigated by thin-layer chromatography, ultraviolet, infrared, and mass spectrometry, and by ultramicro elemental analysis for sulfur. Long chain thiols were absent but trace amounts of open-chain sulfides and some heterocyclic compounds containing sulfur appear to be present in the meteorite lipid fraction. The conditions for the formation of the sulfur compounds are in agreement with the generally accepted concepts regarding the environment of the meteorite parent body (ies). The meteorite lipid fraction appears to differ in part from petroleum.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Schutz, K., and R. Elofson, Geochim. Cosmochim. Acta29, 157 (1965).

    Article  Google Scholar 

  2. Nagy, B., Geol. Fören. Stockholm För, in press.

  3. Wiik, H. B., Geochim. Cosmochim. Acta,9, 279 (1956).

    Article  CAS  Google Scholar 

  4. Boato, G., Geochim. Cosmochim. Acta6, 209 (1954).

    Article  Google Scholar 

  5. Nagy, B., W. G. Meinschein and D. J. Hennessy, Ann. N. Y. Acad. Sci.108, Art. 2, 534 (1963).

    Article  CAS  Google Scholar 

  6. Marshall, R. R., Jet Propulsion Lab. Cal. Inst. Technol., Tech. Dept. No. 32-216. (March 19, 1962).

  7. Urey, H. C., Science147, 1262 (1965).

    Article  CAS  Google Scholar 

  8. Berthelot, M., Compt. rend.67, 849 (1868).

    Google Scholar 

  9. Nagy, B., W. G. Meinschein and D. J. Hennessy, Ann. N. Y. Acad. Sci.93, 25 (1961).

    Article  CAS  Google Scholar 

  10. Meinschein, W. G., B. Nagy and D. J. Hennessy, N. Y. Acad. Sci.108, 553 (1963).

    Article  CAS  Google Scholar 

  11. Briggs, M., and G. Mamikunian, Space Sci. Rev.1, 647 (1962).

    Article  Google Scholar 

  12. Nagy, B., and S. M. C. Bitz, Arch. Biochem. Biophys.101, 240 (1963).

    Article  CAS  Google Scholar 

  13. Hayatsu, R., Science,146, 1291 (1964).

    Article  CAS  Google Scholar 

  14. Nagy, B., Sr. M. T. J. Murphy, V. E. Modzeleski, G. Rouser, G. Claus, D. J. Hennessy, U. Colombo and F. Gazzarrini, Nature202, 228 (1964).

    Article  CAS  Google Scholar 

  15. Hayatsu, R., Science149, 443 (1965).

    Article  Google Scholar 

  16. Hodgson, G. W., and B. L. Baker, Nature202, 125 (1964).

    Article  CAS  Google Scholar 

  17. Vallentyne, J. R., Two Aspects of the Geochemistry of Amino Acids, in “The Origins of Prebiological Systems and their Molecular Matrices,” New York, Academic Press, 1965.

    Google Scholar 

  18. Hamilton, P., private communication (1965).

  19. Kaplan, I. R., E. T. Degens and J. H. Reuter, Geochim. Cosmochim. Acta27, 805 (1963).

    Article  CAS  Google Scholar 

  20. Hamilton, P., Nature205, 4968 (1965).

    Article  Google Scholar 

  21. Murphy, Sr. M. T. J., B. Nagy, G. Rouser and G. Kritchevsky, JAOCS42, 475 (1965).

    Article  CAS  Google Scholar 

  22. Oro, J., and H. Skewes, Nature207 1042 (1965).

    Article  CAS  Google Scholar 

  23. Smith, H. M., H. N. Dunning, H. T. Rall and J. S. Ball, Am. Pet. Institute, Division of Refining, N. Y., May 29, 1959.

  24. Thompson, C. J., H. J. Coleman, R. L. Hopkins and H. T. Rall, J. Chem. Eng. Data9, 473 (1964).

    Article  CAS  Google Scholar 

  25. Coleman, H. J., C. J. Thompson, C. C. Ward and H. T. Rall, Anal. Chem.30, 1592 (1958).

    Article  CAS  Google Scholar 

  26. Hopkins, R. L., and H. M. Smith, Anal. Chem.26, 206 (1954).

    Article  CAS  Google Scholar 

  27. Thompson, C. J., H. J. Coleman, H. T. Rall and H. M. Smith, Anal. Chem.27, 175 (1955).

    Article  CAS  Google Scholar 

  28. Coleman, H. J., N. G. Adams, B. H. Eccleston, R. L. Hopkins, L. Mikkelsen, H. T. Rall, D. Richardson, C. J. Thompson and H. M. Smith, Anal. Chem.28, 175 (1955).

    Google Scholar 

  29. Breger, I., “Organic Geochemistry,” Pergamon Press, New York, 1963.

    Google Scholar 

  30. Cox, B. B., Bull. Amer. Assoc. Petroleum Geologists30, 645 (1946).

    CAS  Google Scholar 

  31. Whitehead, W., and I. Breger, Geochemistry of Petroleum, in “Organic Geochemistry,” Pergamon Press, New York, 1963.

    Google Scholar 

  32. Anders, E., Ann. N. Y. Acad. Sci.108, 514 (1963).

    Article  CAS  Google Scholar 

  33. DuFresne, E. R., and E. Anders, Geochim. Cosmochim. Acta26, 1085 (1962).

    Article  CAS  Google Scholar 

  34. Schwarzkopf, O., private communication (1965).

  35. Lorant, I., J. Physiol. Chem. 185 (1929).

  36. Roth, H., Mikrochemie,36–7, 379 (1951).

    Google Scholar 

  37. Johnson, C., and H. Nishita, Anal. Chem.24, 736 (1952).

    Article  Google Scholar 

  38. Gustafson, L., Talanta4, 227, 237 (1960).

    Google Scholar 

  39. Bendoraitis, J. G., private communication (1964).

  40. Lang, L., “Absorption Spectra in the Ultraviolet and Visible Region,” Academic Press Inc., New York, 1961.

    Google Scholar 

  41. Biemann, K., private communication (1965).

  42. Ryhage, R., private communication (1965).

  43. Oro, J., D. Nooner, A. Zlatkis and S. A. Wikström, in press.

  44. Eccleston, B., M. Morrison and H. M. Smith, Anal. Chem.24, 1745 (1952).

    Article  CAS  Google Scholar 

  45. Coleman, H. J., C. J. Thompson, H. T. Rall and H. M. Smith, Ind. Eng. Chem.45, 2706 (1953).

    Article  CAS  Google Scholar 

  46. Bryce, W. A., and C. Hinshelwood, J. Chem. Soc. 3379 (1949).

  47. Hennessy, D. J., private communication (1965).

  48. Garrels, R., “Mineral Equilibria,” Harper and Brothers, New York, 1960.

    Google Scholar 

  49. Schoberl, A., and A. Wagner, Methoden der Organischen Chemie9, 3 (1955).

    Google Scholar 

  50. Farmer, E., J. Soc. Chem. Ind. (London)66, 86 (1947).

    CAS  Google Scholar 

  51. Urey, H. C., Astrophys. J. Suppl.1, 147 (1954).

    Article  CAS  Google Scholar 

  52. Vaughan, W., and F. Rust, J. Org. Chem.7, 471 (1942).

    Google Scholar 

  53. Knight, A. R., O. Strausz and H. Gunning, J. Am. Chem. Soc.85, 2349 (1963).

    Article  CAS  Google Scholar 

  54. Horton, A. W., J. Org. Chem.,14, 761 (1949).

    Article  CAS  Google Scholar 

  55. Constantinides, G., and G. Arich, Non-Hydrocarbon Compounds in Petroleum, in “Fundamental Aspects of the Geochemistry of Petroleum,” Amsterdam, Elsevier Publishing Company, in press.

Download references

Author information

Authors and Affiliations

Authors

About this article

Cite this article

Teresa Joseph Murphy, S.M., Nagy, B. Analysis for sulfur compounds in lipid extracts from the orgueil meteorite. J Am Oil Chem Soc 43, 189–196 (1966). https://doi.org/10.1007/BF02641086

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02641086

Keywords

Navigation