Abstract
Upon the interaction of cobalt chelate compounds (containing a carbonyl or imino group) with Al, Mg and Li organic compounds in aromatic hydrocarbons, Co(0) complexes are formed. The coordination sphere of Co(0) includes an arene molecule, an organometallic molecule and a chelate ligand of the initial cobalt complex.
Abstract
При взаимодействии хелатных соединений кобальта, содержащих карбонильную или иминную группу, с Al-, Mg-, Li-органическими соединениями в среде ароматических углеводородов образуются комплексы Co(0). В координационную сферу Co(0) входят молекула арена, молекула метаlqlлорганического соединения и хелатный лиганд исходного комплекса кобальта.
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References
V.V. Saraev, F.K. Shmidt, G.M. Larin, V.G. Lipovich: Izv. Akad. Nauk SSSR, Ser. Khim., 211 (1974).
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Shmidt, F.K., Sarayev, V.V., Levkovskii, Y.S. et al. Investigation of the composition of Co(0) complexes in Ziegler type catalytic systems. React Kinet Catal Lett 10, 195–199 (1979). https://doi.org/10.1007/BF02075993
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DOI: https://doi.org/10.1007/BF02075993