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Kinetics of ethynylation of formaldehyde to butynediol

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Abstract

Activity of Cu catalysts and kinetics of ethynylation of formaldehyde using Cu2C2 catalyst has been studied. The reaction was found to be 0.41 and 0.58 order with respect to acetylene and formaldehyde concentrations, respectively. The activation energy of the reaction was found to be 15.13 kcal/mol.

Abstract

Была исследована активность медных катализаторов и кинетика этинилирования формальдегида с помощью Cu2C2 в качестве катализатора. Реакция имеет порядок 0,41 по концентрации ацетилена и 0,58 по концентрации формальдегида. Энергия активации реакции равна 15,13 ккал/моль.

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References

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Authors and Affiliations

  1. Chemical Engineering Division, National Chemical Laboratory, 411 008, Poona, India

    S. P. Gupte, P. B. Jadkar & R. V. Chaudhari

Authors
  1. S. P. Gupte
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  2. P. B. Jadkar
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  3. R. V. Chaudhari
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NCL Communication No.: 3095

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Gupte, S.P., Jadkar, P.B. & Chaudhari, R.V. Kinetics of ethynylation of formaldehyde to butynediol. React Kinet Catal Lett 24, 173–177 (1984). https://doi.org/10.1007/BF02069623

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  • DOI: https://doi.org/10.1007/BF02069623

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