Summary
Citronellol esterification catalyzed byCandida antarctica lipase is performed with high yields (74%) in a solvent-free medium. The use of dessicants gives a 10% yield enhancement and substrate excess consumption by adding calculated amounts of acetic acid lead to a 80% pure citronellyl acetate. Quantities up to 100 ml are treated with success.
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References
Akoh C.C. (1993).Biotechnol. Lett. 15, 949–954.
Akoh C.C., Cooper C. and Nwosu C.V. (1992).J. Am. Oil Chem. Soc. 69, 257–260.
Berger M., Laumen K. and Schneider M.P. (1992 a).J. Am. Oil Chem. Soc. 69, 955–960.
Berger M., Laumen K. and Schneider M.P. (1992 b).J. Am. Oil Chem. Soc. 69, 961–965.
Blecker C., Lognay G., Razafidralambo H., Fonteyn F., Marlier M., Wathelet J.P. and Severin M. (1994). J. Chem. Technol. Biotechnol., submitted for publication.
Claon P.A. and Akoh C.C. (1993).Biotechnol. Lett. 15, 1211–1216.
Gillies B., Yamazaki H. and Armstrong D.W. (1987). In: “Biocatalysis in organic media” (Laane C., Tramper J. and Lilly M.D.), Amsterdam, Elsevier, 227–232.
Halling P. (1990).Biotechnol. Bioeng. 35, 691–701.
Hayes D.G. and Gulari E. (1991).Biotechnol. Bioeng. 38, 507–517.
Iwai M., Okumura S. and Tsujisaka Y. (1980).Agric. Biol. Chem. 44, 2731–2732.
Janssen A.E.M., Van der Padt A., Van Sonsbeek H.M. and Van't Riet K. (1993 a).Biotechnol. Bioeng. 41, 95–103.
Janssen A.E.M., Van der Padt A. and Van't Riet K. (1993 b).Biotechnol. Bioeng. 42, 953–962.
Kim S.M. and Rhee J.S. (1991).J. Am. Oil Chem. Soc. 68, 499–503.
Langrand G., Triantaphylides C. and Baratti J. (1988).Biotechnol. Lett. 10, 549–554.
Manjon A., Iborra J.L. and Arocas A. (1991).Biotechnol. Lett. 13, 339–344.
Nishio T., Tkahashi K., Yoshimoto T., Kodera Y., Saito Y. and Inada Y. (1987).Biotechnol. Lett. 9, 187–190.
Takahashi K., Saito Y. and Inada Y. (1988).J. Am. Oil Chem. Soc. 65, 911–916.
Valivety R.H., Halling P.J. and Macrae A.R. (1993).Biotechnol. Lett. 15, 1133–1138.
Welsh F.W., Williams R.E. and Dawson K.H. (1990).J. Food Sci. 55, 1679–1682.
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Fonteyn, F., Blecker, C., Lognay, G. et al. Optimization of lipase-catalyzed synthesis of citronellyl acetate in solvent-free medium. Biotechnol Lett 16, 693–696 (1994). https://doi.org/10.1007/BF00136473
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DOI: https://doi.org/10.1007/BF00136473