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Application of HS-SPME with Poly(1-Vinyl-3-Hexylimidazolium Chloride) Polymeric Ionic Liquid Coating Using GC–MS to Determine Volatile Fatty Acids in Dairy Wastewater

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Abstract

Volatile fatty acids were determined in this study using headspace solid-phase microextraction (HS-SPME) with a poly(1-vinyl-3-hexylimidazolium chloride) polymeric ionic liquid coated fiber followed by gas chromatography–mass spectrometry. Experimental parameters such as extraction time and temperature, sample volume as well as desorption time and temperature were optimized. Detection limits of the method were in the range of 0.13–0.26 mg/L. The coefficient of variation ranged from 0.12 to 6.9 %. The method was applied to determine volatile fatty acids in dairy wastewater from different operations and in bulk wastewater.

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Acknowledgments

This work was supported by the project: “The development of interdisciplinary doctoral studies at the Gdansk University of Technology in modern technologies” (Project No: POKL.04.01.01-00-368/09); Duration: 1.10.2009–30.09.2015. This work was also financially supported by the National Science Center (Poland) in the framework of the “PRELUDIUM” (Decision No.: DEC-2012/05/N/ST4/02026). This research work was supported by the European Social Fund, the State Budget and the Pomorskie Voivodeship Budget according to the Operational Programme Human Capital, Priority VIII, Action 8.2, Under-action 8.2.2: ‘Regional Innovation Strategy’ within the system project of the Pomorskie Voivodeship “InnoDoktorant—Scholarships for PhD students, Vth edition”.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Chemical Faculty, Gdańsk University of Technology, Narutowicza 11/12, 80-233, Gdańsk, Poland

    Marta Wasielewska & Bogdan Zygmunt

  2. Department of Chemistry, The University of Toledo, Toledo, OH, 43606, USA

    Jared L. Anderson

Authors
  1. Marta Wasielewska
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  2. Bogdan Zygmunt
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  3. Jared L. Anderson
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Correspondence to Marta Wasielewska.

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Wasielewska, M., Zygmunt, B. & Anderson, J.L. Application of HS-SPME with Poly(1-Vinyl-3-Hexylimidazolium Chloride) Polymeric Ionic Liquid Coating Using GC–MS to Determine Volatile Fatty Acids in Dairy Wastewater. Chromatographia 77, 151–158 (2014). https://doi.org/10.1007/s10337-013-2572-x

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  • DOI: https://doi.org/10.1007/s10337-013-2572-x

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