Abstract
In this work, formation of self-organized Si nanostructures induced by pure Fe incorporation during normal incidence low-energy (1keV) Ar\(^+\) ion bombardment is presented. It has been observed that the incorporation of Fe affects the evolution of the surface topography. The addition of Fe generates pronounced nanopatterns, such as dots, ripples and combinations of dots and ripples. The orientation of the ripple wave vector of the patterns formed is found to be in a direction normal to the Fe flow. The nanoripples with wavelength of the order of 39 nm produced is expected to be the lowest wavelength of the patterns reported on ion-beam-eroded structures under the incorporation of metallic impurities as per our knowledge. From the AFM and GISAXS analysis, it has been confirmed that the ripples formed are asymmetric in nature. The effect of the concentration of the Fe on morphological transition of the patterns has been studied using Rutherford backscattering measurements.
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References
C. Boragno, R. Felici, Synchrotron X-ray scattering from metal surfaces nanostructured by IBS. J. Phys. Condens. Matter 21, 224006 (2009)
W.L. Chan, E. Chason, Sputter ripples and radiation-enhanced surface kinetics on Cu(001). Phys. Rev. B 72, 165418 (2005)
K.V. Sarathlal, S. Potdar, M. Gangrade, V. Ganesan, A. Gupta, Azimuthal angle dependence of nanoripple formation on Si (100) by low energy ion erosion. Adv. Mat. Lett. 4, 398–401 (2013)
A.-D. Brown, J. Erlebacher, Temperature and fluence effects on the evolution of regular surface morphologies on ion-sputtered Si(111). Phys. Rev. B 72, 075350 (2005)
X. Ou, A. Keller, M. Helm, J. Fassbender, S. Facsko, Reverse epitaxy of Ge: ordered and faceted surface patterns. Phy. Rev. Lett. 111, 016101 (2013)
X. Ou, K.H. Heinig, R. Hübner, J. Grenzer, X. Wang, M. Helm, J. Fassbender, S. Facsko, Faceted nanostructure arrays with extreme regularity by self-assembly of vacancies. Nanoscale 7, 18928 (2015)
R.L. Headrick, H. Zhou, Ripple formation and smoothening on insulating surfaces. J. Phys. Condens. Matter 21, 224005 (2009)
A. Toma, F. Buatier de Mongeot, R. Buzio, G. Firpo, S.R. Bhattacharyya, C. Boragno, U. Valbusa, Ion beam erosion of amorphous materials: evolution of surface morphology. Nucl. Instrum. Methods B 230, 551 (2005)
Q. Weia, J. Lianb, S. Zhuc, W. Lia, K. Suna, L. Wang, Ordered nanocrystals on argon ion sputtered polymer film. Chem. Phy. Lett. 452, 124128 (2008)
R.M. Bradley, M. Harper, Theory of ripple topography induced by ion bombardment. J. Vac. Sci. Technol. A 6, 2390 (1988)
R. Cuerno, A.L. Barabsi, Dynamic scaling of ion-sputtered surfaces. Phys. Rev. Lett. 74, 4746 (1995)
G. Carter, V. Vishnyakov, Roughening and ripple instabilities on ion-bombarded Si. Phys. Rev. B 54, 17647 (1996)
S. Rusponi, C. Boragno, U. Valbusa, Ripple structure on Ag (110) surface induced by ion sputtering. Phys. Rev. Lett. 78, 2795 (1997)
M.A. Makeev, A.L. Barabsi, Ion-induced effective surface diffusion in ion sputtering. Appl. Phys. Lett. 71, 2800 (1997)
J. Erlebacher, M.J. Aziz, E. Chason, M.B. Sinclair, J.A. Floro, Sputter rippling kinetics of Si(001): pattern forming instabilities on the atomic scale. Phys. Rev. Lett. 82, 2330 (1999)
S.V. Roth, G. Santoro, J.F.H. Risch, S. Yu, M. Schwartzkopf, T. Boese, R. Döhrmann, P. Zhang, B. Besner, P. Bremer, D. Rukser, M.A. Rübhausen, N.J. Terrill, P.A. Staniec, Y. Yao, E. Metwalli, P. Müller-Buschbaum, Patterned diblock co-polymer thin films as templates for advanced anisotropic metal nanostructures. ACS Appl. Mater. Interfaces 7, 12470 (2015)
K.V. Sarathlal, D. Kumar, A. Gupta, Growth study of Co thin film on nanorippled Si (100) substrate. Appl. Phys. Lett. 98, 12311 (2011)
K.V. Sarathlal, D. Kumar, V. Ganesan, A. Gupta, In-situ study of magnetic thin films on nanorippled Si (1 0 0) substrates. Appl. Surf. Sci. 258, 41164121 (2012)
M.A. Arranz, J.M. Colino, F.J. Palomares, On the limits of uniaxial magnetic anisotropy tuning by a ripple surface pattern. J. Appl. Phy. 115, 183906 (2014)
K. Chen, R. Frömter, S. Rössler, N. Mikuszeit, H.P. Oepen, Uniaxial magnetic anisotropy of cobalt lms deposited on sputtered MgO (001) substrates. Phys. Rev. B 86, 064432 (2012)
M.O. Liedke, M. Krner, K. Lenz, F. Grossmann, S. Facsko, J. Fassbender, Magnetic anisotropy engineering: single-crystalline Fe films on ion eroded ripple surfaces. Appl. Phys. Lett 100, 242405 (2012)
M. Ranjan, T.W.H. Oates, S. Facsko, W. Möller, Optical properties of silver nanowire arrays with 35 nm periodicity. Opt. Lett. 35, 2576 (2010)
S. Camelio, D. Babonneau, D. Lantiat, L. Simonot, F. Pailloux, Anisotropic optical properties of silver nanoparticle arrays on rippled dielectric surfaces produced by low-energy ion erosion. Phys. Rev. B 80, 155434 (2009)
J. Erlebacher, M.J. Aziz, Spontaneous pattern formation on ion bombarded Si (001). Phys. Rev. Lett. 82, 2330–2333 (1999)
F. Frost, B. Rauschenbach, Nanostructuring of solid surfaces by ion-beam erosion. Appl. Phys. A Mater. Sci. Process. 77, 1–9 (2003)
B. Ziberi, F. Frost, Th Höche, B. Rauschenbach, Ripple pattern formation on silicon surfaces by low-energy ion-beam erosion: experiment and theory. Phy. Rev. B 72, 235310 (2005)
S. Facsko, T. Dekorsy, C. Koerdt, C. Trappe, H. Kurz, A. Vogt, H.L. Hartnagel, Formation of ordered nanoscale semiconductor dots by ion sputtering. Science 285, 1551–1553 (1999)
K. Zhang, M. Brötzmann, H. Hofsäss, Surfactant-driven self-organized surface patterns by ion beam erosion. New. J. Phys. 13, 013033 (2011)
O. El-Atwani, S. Gonderman, A. DeMasi, A. Suslova, J. Fowler, M. ElAtwani, K. Ludwig, J.P. Allain, Nanopatterning of metal-coated silicon surfaces via ion beam irradiation: real time X-ray studies reveal the effect of silicide bonding. J. Appl. Phys. 113, 124305 (2013)
S.K. Vayalil, A. Gupta, S.V. Roth, V. Ganesan, Investigation of the mechanism of impurity assisted nanoripple formation on Si induced by low energy ion beam erosion. J. Appl. Phy. 117, 024309 (2015)
S. Macko, F. Frost, B. Ziberi, D.F. Förster, T. Michely, Is keV ion-induced pattern formation on Si (001) caused by metal impurities? Nanotechnology 21, 085301 (2010)
J.A. Sánchez-García, L. Vzquez, R. Gago, A. Redondo-Cubero, J.M. Albella, Z. Czigány, Tuning the surface morphology in self-organized ion beam nanopatterning of Si(001) via metal incorporation: from holes to dots. Nanotechnology 19, 355306 (2008)
B. Khanbabaee, B. Arezki, A. Biermanns, M. Cornejo, D. Lützenkirchen-Hecht, D. Hirsch, F. Frost, U. Pietsch, Depth prole investigation of the incorporated iron atoms during Kr+ ion beam sputtering on Si (001). Thin Solid Films 527, 349353 (2013)
R.M. Bradley, P.D. Shipman, Spontaneous pattern formation induced by ion bombardment of binary compounds. Phys. Rev. Lett. 105, 145501 (2010)
J. Zhou, M. Lu, Mechanism of Fe impurity motivated ion-nanopatterning of Si (100) surfaces. Phys. Rev. B 82, 125404 (2010)
R.M. Bradley, Nanoscale patterns produced by ion erosion of a solid with codeposition of impurities: the crucial effect of compound formation. Phy. Rev. B 87, 205408 (2013)
R.M. Bradley, P.D. Shipman, A surface layer of altered composition can play a key role in nanoscale pattern formation induced by ion bombardment. Appl. Surf. Sci. 258, 4161–4170 (2012)
H. Hofsäss, K. Zhang, Surfactant sputtering. Appl. Phys. A 92, 517–524 (2008)
G. Ozaydin, A.S. Özcan, Y. Wang, K.F. Ludwig, H. Zhou, R.L. Headrick, D.P. Siddons, Real-time X-ray studies of Mo-seeded Si nanodot formation during ion bombardment. Appl. Phys. Lett. 87, 163104 (2005)
K. Zhang, O. Bobes, H. Hofsäss, Designing self organized nanopatterns on Si by ion irradiation and metal co-deposition. Nanotechnology 25, 085301 (2014)
A. Hubert, R. Schäfer, Magnetic domains (Springer, Berlin, 1998)
D. Nečas, P. Klapetek, Gwyddion: open-source software for SPM data analysis. Cent. Eur. J. Phys. 10(1), 181 (2012)
P. Klapetek, D. Nečas, C. Anderson, Gwyddion user guide. http://gwyddion.net/documentation/ (2009)
M. Mayer, SIMNRA users guide, Max-Planck-Institut fr Plasmaphysik, Report IPP 9/113 (Garching, Germany, 1997)
A. Buffet, A. Rothkirch, R. Döhrmann, V. Körstgens, M.M.A. Kashem, J. Perlich, G. Herzog, M. Schwartzkopf, R. Gehrke, P. Müller-Buschbaum, S.V. Roth, P03, the microfocus and nanofocus X-ray scattering (MiNaXS) beamline of the PETRA III storage ring: the microfocus endstation. J. Synchr. Radiation 19, 647653 (2012)
G. Santoro, A. Buffet, R. Döhrmann, S. Yu, V. Körstgens, P. Müller-Buschbaum, U. Gedde, M. Hedenqvist, S.V. Roth, Use of intermediate focus for grazing incidence small and wide angle X-ray scattering experiments at the beamline P03 of PETRA III, DESY. Rev. Sci. Instrum. 85, 043901 (2014)
G. Benecke, W. Wagermaier, C. Li, M. Schwartzkopf, G. Flucke, R. Hoerth, I. Zizak, M. Burghammer, E. Metwalli, P. Müller-Buschbaum, M. Trebbin, S. Förster, O. Paris, S.V. Roth, P. Fratzl, A customizable software for fast reduction and analysis of large X-ray scattering data sets: applications of the new DPDAK package to small-angle X-ray scattering and grazing-incidence small-angle X-ray scattering. J. Appl. Cryst. 47, 1797–1803 (2014)
P. Müller-Buschbaum, Grazing incidence small-angle X-ray scattering: an advanced scattering technique for the investigation of nanostructured polymer films. Anal. Bioanal. Chem. 376, 3–10 (2003)
W.K. Chu, J.W. Mayer, M.A. Nicholet, Backscattering spectrometry (Academic, New York, 1978)
Acknowledgements
We would like to thank Dr. V Ganesan, Mohan Gangarade, UGC DAE CSR, Indore, for AFM measurements, and Dr. S. Balaji and Dr. B.S. Panigrahi, IGCAR, Kalpakkam, India, for RBS measurements.
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Koyiloth Vayalil, S., Gupta, A. & Roth, S.V. Study of pattern transition in nanopatterned Si(100) produced by impurity-assisted low-energy ion-beam erosion. Appl. Phys. A 123, 225 (2017). https://doi.org/10.1007/s00339-017-0756-1
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DOI: https://doi.org/10.1007/s00339-017-0756-1