Abstract
Morphological and thermal properties of immiscible and incompatible polymer blends of commercial polyamide-6 (PA-6) and poly(methyl methacrylate) (PMMA) synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization have been studied in the presence of a compatibilizer consisting of either a random copolymer of styrene-maleic anhydride (SMA) or a diblock copolymer poly(methyl methacrylate) and polystyrene (PMMA-PS) also synthesized via RAFT polymerization. Blends of PA-6/PMMA were obtained by extrusion mixing. During melt compounding in the extruder, the functional groups of the polymer components were reacted in the presence of a compatibilizer, which changed considerably the morphology of the blend. After compatibilization, particles of PMMA in the PA-6 were smaller and better dispersed. The morphology and thermal properties of the blends were characterized using scanning electron microscopy (SEM) and differential scanning calorimetry (DCS).
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Acknowledgments
A. A. Khaydarov acknowledges the Royal Society for funding an International Incoming Short Visit to the University of Leeds. PEM thanks the EPSRC and Unilever for the provision of a scholarship. The authors thank Dr John Embery for assistance with the extrusion process.
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Khaydarov, A.A., Kazlauciunas, A., Mounterey, P.E. et al. Investigation of polymer blends of polyamide-6 and poly(methyl methacrylate) synthesized by RAFT polymerization. Polym. Bull. 66, 1089–1098 (2011). https://doi.org/10.1007/s00289-010-0392-9
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DOI: https://doi.org/10.1007/s00289-010-0392-9