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Donor and acceptor number effects for the solvatochromic behaviour ofbis-(2,2′-bipyridyl)-bis-cyanoiron(II) in binary aqueous mixtures

Effekte von Donor- und Akzeptor-Zahlen auf die Solvatochromie vonbis-(2,2′-Bipyridyl)-bis-cyanoeisen(II) in binären wäßrigen Lösungen

  • Anorganische Und Physikalische Chemie
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Summary

Correlation with acceptor numbers was made for the solvatochromic behaviour ofbis-(2,2′-bipyridyl)-bis-cyanoiron(II) in binary aqueous mixtures of acetonitrile andDMF. The relationship between isosolvation point and donor number of the organic cosolvent was proved to be linear. Preferential solvation occurs by water in the case of the binary acetonitrile mixtures and byDMF in the case of the binaryDMF, aqueous mixtures.

Zusammenfassung

Es wurde eine Korrelation zwischen Akzeptorzahl und dem solvatochromen Verhalten vonbis-(2,2′-bipyridyl)-bis-cyanoeisen(II) in binären wäßrigen Mischungen von Acetonitril undDMF durchgeführt. Die Beziehung zwischen Isosolvatisierungspunkt und Donorzahl der organischen Kosolventien erwies sich als linear. Bevorzugte Solvatisierung durch Wasser tritt im Fall der binären Acetonitrilmischungen auf, bei den wäßrigenDMF-Mischungen hingegen wird das Substrat bevorzugt durchDMF Solvatisiert.

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References

  1. Gutmann V., Wychera E. (1966) Nucl. Chem. Lett.2: 257

    Google Scholar 

  2. Erlich R. H., Popov A. I. (1971) J. Am. Chem. Soc.93: 5620

    Google Scholar 

  3. Mayer U., Gutmann V., Gerger W. (1975) Mh. Chem.106: 1235

    Google Scholar 

  4. Gutmann V. (1976) Electrochim. Acta21: 661

    Google Scholar 

  5. Burgess J., Patel M. S. (1990) Inorg. Chim. Acta170: 241

    Google Scholar 

  6. Burgess J., Drasdo D. N., Shraydeh B. (1992) J. Chem. Res. (S)8: 288

    Google Scholar 

  7. Toma H. E., Takasugi M. S. (1989) J. Sol. Chem.18(6): 575

    Google Scholar 

  8. Burgess J., Shraydeh B. (1992) Polyhedron11: 2015

    Google Scholar 

  9. Burgess J., Radulovic S., Sanchez F. (1987) Transition Met. Chem.12: 529

    Google Scholar 

  10. Gutmann V. (1988) Mh. Chem.119: 1251

    Google Scholar 

  11. Al Alousy A., Burgess J. (1990) Inorg. Chim. Acta169: 167

    Google Scholar 

  12. Shraydeh B., Burgess J. (1992) Mh. Chem.124: 877

    Google Scholar 

  13. Schilt A. A. (1960) J. Am. Chem. Soc.82: 3000

    Google Scholar 

  14. Frankel L. S., Stengle T. R., Langford C. H. (1965) Chem. Comm. 393

  15. Mayer U., Gerger W., Gutmann V. (1977) Mh. Chem.108: 489

    Google Scholar 

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, An-Najah National University, Nablus, West-Bank, Via Israel

    B. Farah Shraydeh & N. Zatar

Authors
  1. B. Farah Shraydeh
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  2. N. Zatar
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Farah Shraydeh, B., Zatar, N. Donor and acceptor number effects for the solvatochromic behaviour ofbis-(2,2′-bipyridyl)-bis-cyanoiron(II) in binary aqueous mixtures. Monatsh Chem 125, 655–659 (1994). https://doi.org/10.1007/BF01277624

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  • DOI: https://doi.org/10.1007/BF01277624

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