Abstract
A new equation of state in the acentric factor system is developed on the basis of high-precision data. The region inT r,ρ r space where there is good agreement is identified, as well as the regions of significant departures. The equation fits very well in the critical region.
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References
K. S. Pitzer,J. Am. Chem. Soc. 77:3427 (1955).
K. S. Pitzer, D. Z. Lippmann, R. F. Curl, Jr., C. M. Huggins, and D. E. Petersen,J. Am. Chem. Soc. 77:3433 (1955).
R. F. Curl, Jr., and K. S. Pitzer,Ind. Eng. Chem. 50:265 (1958).
K. S. Pitzer and R. F. Curl, Jr.,J. Am. Chem. Soc. 79:2369 (1957).
J. B. Opfell, B. H. Sage, and K. S. Pitzer,Ind. Eng. Chem. 48:2069 (1956).
T. Yamada,AIChE J. 19:286 (1973).
J. C. Dymond and E. B. Smith,The Second Virial Coefficients of Gases: A Critical Compilation (Clarendon, Oxford, 1980).
V. A. Rabinovich, A. A. Vasserman, V. I. Nedostup, and L. S. Veksler,Thermophysical Properties of Neon, Argon, Krypton, and Xenon (English translation) (Hemisphere, Washington, D.C., 1988).
B. A. Younglove and J. F. Ely,J. Phys. Chem. Ref. Data 16:577 (1987).
R. B. Jacobsen, Ph.D. thesis (Washington State University, Pullman, 1972).
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Schreiber, D.R., Pitzer, K.S. Selected equation of state in the acentric factor system. Int J Thermophys 9, 965–974 (1988). https://doi.org/10.1007/BF01133264
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DOI: https://doi.org/10.1007/BF01133264