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Organosodium compounds of N-substituted benzimidazoles

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

1-Alkylbenzimidazoles and 1-benzylbenzimidazole react with phenylsodium to form the corresponding 2-sodio derivatives. 5-Bromo-1-ethylbenzimidazole does not react with phenyl- and amylsodium. The metallation of 1-arylbenzimidazoles with phenylsodium is appreciably complicated by side processes. A path for the preparation of 2-sodio-1-arylbenzimidazoles from 1-arylbenzimidazoles and o-anisylsodium is proposed. Some transformations of the organosodium compounds of N-substituted benzimidazoles were studied.

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Authors and Affiliations

  1. Rostov State University, Rostov-on-Don

    B. A. Tertov, A. V. Koblik & N. I. Avdyunina

Authors
  1. B. A. Tertov
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  2. A. V. Koblik
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  3. N. I. Avdyunina
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Additional information

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1238–1242, September, 1971.

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Tertov, B.A., Koblik, A.V. & Avdyunina, N.I. Organosodium compounds of N-substituted benzimidazoles. Chem Heterocycl Compd 7, 1163–1167 (1971). https://doi.org/10.1007/BF00510028

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  • DOI: https://doi.org/10.1007/BF00510028

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