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Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts

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Abstract

Palladium nanoparticles with an average size of 2.5±0.5 nm formed from palladium acetate in the presence of tri-tert-butyl(decyl)phosphonium tetrafluoroborate without an additional reducing agent exhibit high activity as a catalyst for the Suzuki cross-coupling reaction involving bromo- and chloroarenes under mild conditions.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088, Kazan, Russian Federation

    V. V. Ermolaev, D. M. Arkhipova, L. Sh. Nigmatullina, I. Kh. Rizvanov, V. A. Milyukov & O. G. Sinyashin

Authors
  1. V. V. Ermolaev
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  2. D. M. Arkhipova
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  3. L. Sh. Nigmatullina
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  4. I. Kh. Rizvanov
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  5. V. A. Milyukov
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  6. O. G. Sinyashin
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Corresponding author

Correspondence to V. A. Milyukov.

Additional information

Dedicated to the Academician of the Russian Academy of Sciences I. P. Beletskaya on the occasion of her anniversary.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 0656–0659, March, 2013.

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Ermolaev, V.V., Arkhipova, D.M., Nigmatullina, L.S. et al. Palladium nanoparticles stabilized by sterically hindered phosphonium salts as Suzuki cross-coupling catalysts. Russ Chem Bull 62, 657–660 (2013). https://doi.org/10.1007/s11172-013-0088-z

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  • DOI: https://doi.org/10.1007/s11172-013-0088-z

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