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A simple catalyst for aqueous phase Suzuki reactions based on palladium nanoparticles immobilized on an ionic polymer

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Abstract

Palladium nanoparticles immobilized on a cross-linked imidazolium-containing polymer were evaluated as a catalyst for Suzuki carbon-carbon cross-coupling reactions using water as the solvent. The nanocatalysts show good catalytic activities for aryl iodides and aryl bromides and moderate activity with aryl chloride substrates. Coupling of sterically hindered substrates could also be achieved in reasonable yields. The heterogeneous catalyst is stable, can be stored without precautions to exclude air or moisture, and can be easily recycled and reused.

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Authors and Affiliations

  1. Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique Fédérale de Lausanne, Lausanne, CH-1015, Switzerland

    Saeideh Ghazali-Esfahani, Emilia Păunescu, Zhaofu Fei, Gabor Laurenczy & Paul J. Dyson

  2. Chemistry Department, Sharif University of Technology, Tehran, 11155-3615, Iran

    Saeideh Ghazali-Esfahani & Mojtaba Bagherzadeh

Authors
  1. Saeideh Ghazali-Esfahani
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  2. Emilia Păunescu
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  3. Mojtaba Bagherzadeh
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  4. Zhaofu Fei
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  5. Gabor Laurenczy
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  6. Paul J. Dyson
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Corresponding author

Correspondence to Paul J. Dyson.

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Ghazali-Esfahani, S., Păunescu, E., Bagherzadeh, M. et al. A simple catalyst for aqueous phase Suzuki reactions based on palladium nanoparticles immobilized on an ionic polymer. Sci. China Chem. 59, 482–486 (2016). https://doi.org/10.1007/s11426-015-5542-3

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  • DOI: https://doi.org/10.1007/s11426-015-5542-3

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