Skip to main content
SpringerLink
Log in

HPLC determination of chlorobenzenes, benzenesulphonyl chlorides and benzenesulphonic acids in industrial waste water

  • Originals
  • Column Liquid Chromatography
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

An HPLC method has been developed for the determination of chlorobenzenes, benzenesulphonyl chlorides, benzenesulphonic acids and related compounds in industrial waste water. The separation and determination of diphenylsulphone, 1,4-dichlorobenzene, 1,2,3,4-tetrachlorobenzene 1,2,3,5-tetrachlorobenzene and pentachlorobenzene was performed in reversed-phase system with octadecylsilica gel stationary phase and aqueous-methanolic mobile phase. Successful separation of ionic and polar compounds as water pollutants such as: benzenesulphonamide, benzenesulphonic acid, 1,3-benzenedisulphonic acid, 4-chlorobenzenesulphonic acid, 2,5-dichlorobenzenesulphonyl chloride, 2,3,4-trichlorobenzenesulphonyl chloride and 2,4,5-trichlorobenzenesulphonyl chloride requires addition of a salt (sodium sulphate) to the mobile phase. Addition of a buffer or of an ion-pair reagent to aqueous-methanolic mobile phases did not yield satifactory improvement in separation selectivity nor of peak shape. Polar and ionic compounds diphenylsulphone and chlorobenzenes, were separated and determined by a two-step, reversed-phase LC method. On-line sample enrichment on an adsorption column packed either with octadecyl silica or with aminopropyl silica connected to an LC column improved the limits of detection of the pollutants.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Reemtsma, T.J. Chromatogr. A 1996,733, 473.

    Article  CAS  Google Scholar 

  2. Jandera, P.; Prokeš, B.J. Chromatogr. 1991,550, 495.

    Article  CAS  Google Scholar 

  3. Jandera, P.; Churáček, J.; Taraba, B.J. Chromatogr. 1983,262, 121.

    Article  CAS  Google Scholar 

  4. Jandera, P.; Fischer, J.; Staněk, V.; Kučerová, M.; Zvoníček, P.J. Chromatogr. A 1996,738, 201.

    Article  CAS  Google Scholar 

  5. Zerbinati, O., Ostacoli, G.; Castaldi, D.; Zelano, V.J. Chromatogr. 1993,640, 231.

    Article  CAS  Google Scholar 

  6. Storm, T.; Reemtsma, T.; Jekel, M.J. Chromatogr. A 1999,854, 175.

    Article  CAS  Google Scholar 

  7. Angelino, S.; Prevot, A.B.; Gennaro, M.C.; Pramauro, E.J. Chromatogr. A 1999,845, 257.

    Article  CAS  Google Scholar 

  8. Marengo, E.; Gennaro, M.C.; Gianotti, V.Chemometrics and Intelligent Laboratory Systems 2000,53, 57.

    Article  CAS  Google Scholar 

  9. Perez-Urquiza, M.; Prat, M.; Beltran, J.L.J. Chromatogr. A 2000,871, 227.

    Article  CAS  Google Scholar 

  10. Jandera, P., Bunčeková, S.; Planeta, J.J. Chromatogr. A 2000,871, 139.

    Article  CAS  Google Scholar 

  11. Loos, R.; Alonso, M.C.; Barceló, D.J. Chromatogr. A 2000,890, 225.

    Article  CAS  Google Scholar 

  12. Alonso, M.C.; Barceló, D.Anal. Chim. Acta 1999,400, 211.

    Article  CAS  Google Scholar 

  13. Pocurull, E.; Aguilar, C.; Alonso, M.C.; Barceló, D.; Borull, F.; Marcé, R.M.J. Chromatogr. A 1999,854, 187.

    Article  CAS  Google Scholar 

  14. Jandera, P.; Churáček, J.J. Chromatogr. 1980,197, 181.

    Article  CAS  Google Scholar 

  15. Rao, R.N.; Alvi, S.N.; Husain, S.HRC-J. High Resolut. Chromatogr. 2000,23, 329.

    Article  CAS  Google Scholar 

  16. Bruins, A.P.; Weidolf, L.O.G.; Henion, J.D.; Dudde, W.L.Anal. Chem. 1987,59, 2647.

    Article  CAS  Google Scholar 

  17. Chen, M.; Moir, D.; Benoit, F.M.; Kubwabo, C.J. Chromatogr. A 1998,825, 37.

    Article  CAS  Google Scholar 

  18. Holčapek, M.; Jandera, P.; Přikryl, J.Dyes Pigm. 1999,43, 127.

    Article  Google Scholar 

  19. Jandera, P.; Churáček, J.; Bartošová, J.Chromatographia 1980,13, 485.

    Article  CAS  Google Scholar 

  20. Wilder, D.R.; Tindall, G.W.; Cunningham, M.J.J. Chromatogr. 1993,635, 221.

    Article  CAS  Google Scholar 

  21. Cugat, M.J.; Borrell, F.; Callul, M.Chromatographia 1999,49, 261.

    Article  CAS  Google Scholar 

  22. Perez-Urquiza, M.; Beltran, J.L.J. Chromatogr. A 2000,883, 277.

    Article  CAS  Google Scholar 

  23. Fischer, J.; Jandera, P.; Staněk, V.J. Chromatogr. A 1997,772, 385.

    Article  CAS  Google Scholar 

  24. Frei, R.W.; Nielen, M.W.F.; Brinkman, U.A.Th.Int. J. Environ. Anal. Chem. 1986,25, 3.

    Article  CAS  Google Scholar 

  25. Nielen, M.W.F.; Frei, R.W.; Brinkman, U.A.Th. InSample Handling and Detection in High-Performance Liquid Chromatography, Part A: Zech, K.; Frei, R.W., Eds, Elsevier, Amsterdam,1988.

    Google Scholar 

  26. Little, C.J.; Tompkins, D.J.; Stahel, O.; Frei, R.W.; Werkhoven-Goewie, C.E.;J. Chromatogr. 1983,264, 183.

    Article  CAS  Google Scholar 

  27. van Vliet, H.P.M.; Bootsman, T.C.; Frei, R.W.; Brinkman, U.A.Th.J. Chromatogr. 1979,185, 483.

    Article  Google Scholar 

  28. Kok, T.W.; Brinkman, U.A.Th.; Frei, R.W.; Hanekamp, H.B.; Nooitgedacht, F.; Pope, H.J. Chromatogr. 1982,237, 357.

    Article  CAS  Google Scholar 

  29. Nielen, M.W.F.; Koomen, G.; Frei, R.W.; Brinkman, U.A.Th.J. Liquid Chromatogr. 1985,8, 315.

    Article  CAS  Google Scholar 

  30. Maris, F.A.; Geerdink, R.B.; Frei, R.W.; Brinkman, U.A.Th.J. Chromatogr. 1985,323, 113.

    Article  CAS  Google Scholar 

  31. Werkhoven-Goewie, C.E.; Boon, W.M.; Praat, A.J.J.; Frei, R.W.; Brinkman, U.A.Th.; Little, C.J.Chromatographia 1982,16, 53.

    Article  CAS  Google Scholar 

  32. Jandera, P.; Svoboda, L.; Kubát, J.; Schvantner, J.; Churáček, J.,J. Chromatogr. 1984,292, 71.

    Article  CAS  Google Scholar 

  33. Kambhapati, I.; Roinestad, K.S.; Hartman, T.G.; Rosen, J.D.; Fukuda, E.K.; Lippincott, R.L.; Rosen, R.T.J. Chromatogr. A 1994,688, 67.

    Article  Google Scholar 

  34. Nielen, M.W.F.; Brinkman, U.A.Th.; Frei, R.W.Anal. Chem. 1985,57, 806.

    Article  CAS  Google Scholar 

  35. Castillo, M.; Alonso, M.C.; Riu, J.; Barceló, D.Environ. Sci. Technol. 1999,33, 1300.

    Article  CAS  Google Scholar 

  36. Castillo, M.; Ventura, F.; Barceló, J.D.Waste Management 1999,19, 101.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Analytical Chemistry, University of Pardubice, Nám. Čs. legif 565, 532 10, Pardubice, Czech Republic

    P. Jandera, J. Fischer & B. Prokeš

Authors
  1. P. Jandera
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. Fischer
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. Prokeš
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jandera, P., Fischer, J. & Prokeš, B. HPLC determination of chlorobenzenes, benzenesulphonyl chlorides and benzenesulphonic acids in industrial waste water. Chromatographia 54, 581–587 (2001). https://doi.org/10.1007/BF02492182

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02492182

Key Words

Search

Navigation