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The isotope effect in formation of surface water clusters in heterogeneous systems

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Abstract

Using the method of low-temperature 1H NMR-spectroscopy we investigated isotope effects in adsorption of water and hydrochloric acid by the surface of nanosilica A-300 and in particular dehydrated cells Saccharomyces cerevisiae. It is shown that replacement of protium by deuterium results in the growth of the amount of water bound with silica. Solutions of H(D)2O-H(D)Cl are characterized by the formation of several types of cluster structures different in concentration of acid. The ratio of intensities of signals corresponding to various types of clusters substantially depends on the isotope composition and for samples enriched with deuterium it shifts to the side of less associated forms of water.

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References

  1. Goncharuk, V.V., Science about water, Kiev: Nauk. Dumka, 2010.

    Google Scholar 

  2. Shishelova, T.I., Korzun, N.L., and Tolstoi, M.Yu., Perspectives and trends in the study of water, Moscow: Izd-vo Academiya Estestvoznaniya, 2014.

    Google Scholar 

  3. Ptushinski, Yu.G., Fizika Nizkikh Temperatur, 2004, vol. 30, no. 1, pp. 3–37.

    Google Scholar 

  4. Gasserm R.O.H., Morton, T.N., Overton, J.M., and Miss A.K., Surface Sci., 1971, vol. 28, no. 2, pp. 574–580.

    Article  Google Scholar 

  5. Mosin, O,V., Biotechnology, 1996, no. 4, pp. 19–27.

    Google Scholar 

  6. Lobyshev, V.N. and Kalinichenko, L.P., Izotopnye effekty D 2 O v biologicheskikh sistemakh (Isotope Effects D2O in biological systemakh), Moscow: Nauka, 1978.

    Google Scholar 

  7. Pshenichnikova, A.B., Nevo, A.N.S., Volkova. E.V., Skladnev, D.A., and Shvets, V.I., Prikl. Biokhimiya i mikrobiologiiya (Applied Biochemistry and Microbiology), 2004, vol. 40, no. 1, pp. 24–27.

    CAS  Google Scholar 

  8. Kuteshenko, V.P., Molekilyar. Biologiya, 2001, vol. 35, no 1, pp. 90–99.

    Google Scholar 

  9. Kuteshenko, V.P. and Yurkevich, D.I., Biofizika (Biophysiics), 1999, no. 2, p. 28.

    Google Scholar 

  10. Gun’ko, V.M., Turov, V.V., and Gorbik, P.P., Water on the phase boundary, Kiev: Nauk. Dumka., 2009.

    Google Scholar 

  11. Gun’ko, V.M. and Turov, V.V., Nuclear magnetic resonance studies of interfacial phenomena, New York: Taylor & Francis, 2013.

    Book  Google Scholar 

  12. Turov, V.V., Gun’ko, V.M., Klasrezovannaya voda i puti ee ispolzovaniya (Cluster Water and Ways To Use It), Kiev: Nauk. Dumka, 2011.

    Google Scholar 

  13. Gun’ko, V.M., Turov, V.V., Bogatyrev V.M., Zarko, V.I., Leboda, R., Goncharuk, V.V., Novza, A.A., Turov, A.V., and Chuiko, A.A., Adv. Colloid Interface Sci., 2005, vol. 118, p. 125–172.

    Google Scholar 

  14. Aksnes, D.W. and Kimtys, L., Solid State Nuclear Resonance, 2004, vol. 25, pp. 146–163.

    Article  CAS  Google Scholar 

  15. Petrov, O.V. and Furo, I., Prgr, NMR, 2009, vol. 54, pp. 97–122.

    Article  CAS  Google Scholar 

  16. Kinney, D.R., Chaung, I-S., and Maciel, G.E., J. Amer. Chem. Soc., 1993, vol. 115, pp. 6786–6794.

    Article  CAS  Google Scholar 

  17. Termodinamicheskie svostva individualnykh veshchestv (Termodynamic properties of individual substances, Glushko, V.P. (Ed.), Moscow: Nauka, 1978.

  18. Pople, J.A., Schneider, W.G., Bernstein, H.J., High-resolutions nuclear magnetic resonance, New York: McGraw-Hill BookCompany, 1959.

    Google Scholar 

  19. Turov, V.V., Gun’ko, V.M., Krupskakaya, T.V., Lipkovskaya, N.A., and Turova, A.A., Biofizika (Biophysics), 2014, vol. 59, no. 3, pp. 492–499.

    CAS  Google Scholar 

  20. Turov, V.V., Gun’ko, V.M., Turova, A.A., Morozova, L.P., Voronina, E.E., Colloids and Surface A, 2011, vol. 390, pp. 48–55.

    Article  CAS  Google Scholar 

  21. Golubev, N.S., Shchepkin, D.N., Shenderovich, I.G., Schah-Mohammedi, P., Limbach H.-H. Magnetic Resonance and Related Phenomena, in Proc. of the Joint 29 AMPERE. 13 ISMAR In. Conf. (Berlin, July 2, 1998), Berlin, 1998, vol. 1, pp. 174–175.

    Google Scholar 

  22. Wiggins, P.M., MacClement, B.A.A., Int. Rev. Cytol., 1987, vol. 108, pp. 249–303.

    Article  CAS  Google Scholar 

  23. Chaplin, M.F., Biophys. Chem., 1999, vol. 83, pp. 211–221.

    Article  Google Scholar 

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Authors and Affiliations

  1. Chuiko Institute of Chemistry of Surfaces, National Academy of Sciences of Ukraine, Kiev, Ukraine

    V. V. Turov & T. V. Krupskaya

  2. Dumanskii Institute of Colloid Chemistry and the Chemistry of Water, National Academy of Sciences of Ukraine, Kiev, Ukraine

    V. V. Goncharuk

  3. Vernadskii Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine

    V. M. Ogenko

  4. Taras Shevchenko National University, Kiev, Ukraine

    M. D. Tsapko

Authors
  1. V. V. Turov
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  2. V. V. Goncharuk
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  3. V. M. Ogenko
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  4. T. V. Krupskaya
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  5. M. D. Tsapko
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Corresponding author

Correspondence to V. V. Turov.

Additional information

Original Russian Text © V.V. Turov, V.V. Goncharuk, V.M. Ogenko, T.V. Krupskaya, M.D. Tsapko, 2015, published in Khimiya i Tekhnologiya Vody, 2015, Vol. 37, No. 5, pp. 387–400.

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Turov, V.V., Goncharuk, V.V., Ogenko, V.M. et al. The isotope effect in formation of surface water clusters in heterogeneous systems. J. Water Chem. Technol. 37, 211–218 (2015). https://doi.org/10.3103/S1063455X1505001X

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  • DOI: https://doi.org/10.3103/S1063455X1505001X

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