Skip to main content
SpringerLink
Log in

A diamagnetic Mossbauer probe method for studying a solid-gas interface and related catalytic processes

  • Published:
Moscow University Chemistry Bulletin Aims and scope

Abstract

The results of recent studies involving the application of diamagnetic Mossbauer dopant cations for the investigation of heterogeneous catalytic reactions are described. Possibilities for using the information contained in Mossbauer spectra to clarify the nature of active catalytic centers are discussed. It is shown that, in some cases, the catalytic tests allow the correctness of the chemical interpretation of spectral parameters of the dopant atoms under study to be verified.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Fabrichnyi, P.B., Zh. Vses. Khim. O-va im. D.I. Mendeleeva, 1985, vol. 30, p. 143.

    CAS  Google Scholar 

  2. Fabrichnyi, P.B., Afanasov, M.I., Korolenko, M.V., and Morozova, N.I., Abstracts of Papers, X Mezhdunarodnaya konferentsiya “Messbauerovskaya spektroskopiya i ee primeneniya” (X Int. Conf. on Mossbauer Spectroscopy and its Application), Izhevsk, 2006, p. 48

  3. Afanasov, M.I. and Fabrichnyi, P.B., Ross. Khim. Zh., 1996, vol. 40, p. 54.

    CAS  Google Scholar 

  4. Fabrichnyi, P.B., Protskii, A.N., and Gor’kov, V.P., Tran Min Dyuk, Demazeau, G., and Hagenmuller, P., Zh. Eksp. Teor. Fiz., 1981, vol. 81, p. 1145.

    CAS  Google Scholar 

  5. Foner, S., J. Phys. Radium, 1949, vol. 20, p. 336.

    Article  Google Scholar 

  6. Afanasov, M.I., Shvyryaev, A.A., Presnyakov, I.A., Demazeau, G., and Fabrichnyi, P.B., Zh. Neorg. Khim., 1990, vol. 35, p. 2912.

    CAS  Google Scholar 

  7. Afanasov, M.I., Korolenko, M.V., Danot, M., and Fabritchnyi, P.B., Solid State Commun., 2002, vol. 124, p. 407.

    Article  CAS  Google Scholar 

  8. Afanasov, M.I., Ryabchikov, A.A., Korolenko, M.V., et al., Izv. Akad. Nauk, Ser. Fiz., 2001, vol. 65, p. 1035.

    CAS  Google Scholar 

  9. Fabritchnyi, P.B., Korolenko, M.V., Afanasov, M.I., Danot, M., and Janod, E., Solid. State Commun., 2003, vol. 125, p. 341.

    Article  CAS  Google Scholar 

  10. Afanasov, M.I., Fabrichnyi, P.B., Korolenko, M.V., and Ivanova, T.M., Zh. Neorg. Khim., 2008, vol. 53, p. 1382 [Russ. J. Inorg. Chem. (Engl. Transl.), vol. 53, p. 1288].

    CAS  Google Scholar 

  11. Sudakova, N.R., in Materialy konferentsii molodykh uchenykh MGU (Proc. Conf. of Young Scientists of Moscow State Univ.), Moscow, 1988, part 2, p. 55.

  12. Fabritchnyi, P.B., Sudakova, N.R., Berentsveig, V.V., Demazeau, G., Afanasov, M.I., and Etourneau, J., J. Mater. Chem., 1992, vol. 2, p. 763.

    Article  Google Scholar 

  13. Fabrichnyi, P.B., Afanasov, M.I., Korolenko, M.V., and Morozova, N.I., Abstracts of Papers, VIII Mezhdunarodnaya konferentsiya “Messbauerovskaya spektroskopiya i ee primeneniya” (VIII Int. Conf. on Mossbauer Spectroscopy and its Application), St. Petersburg, 2002, p. 149.

  14. Morozova, N.I., Kulakova, I.I., Afanasov, M.I., and Fabritchnyi, P.B., Abstracts of Papers, II Int. Conf. on Highly-Organized Catalytic Systems, Moscow, 2004, p. 94.

  15. Morozova, N.I., Cand. Sci. (Chem.) Dissertation, Moscow, 2007.

  16. Miyamoto, A., Ui, T., and Murakami, Y., J. Catal., 1983, vol. 80, p. 106.

    Article  CAS  Google Scholar 

  17. Fabritchnyi, P.B., Sudakova, N.R., Gorkov, V.P., Berentsveig, V.V., Demazeau, G., and Hagenmuller, P., Mater. Res. Bull., 1993, vol. 28, p. 179.

    Article  Google Scholar 

  18. Afanasov, M.I., Ryabchikov, A.A., Korolenko, M.V., Morozova, N.I., and Fabrichnyi, P.B., Izv. Akad. Nauk, Ser. Fiz., 2001, vol. 65, p. 1035.

    CAS  Google Scholar 

  19. Morozova, N.I., Kulakova, I.I., Afanasov, M.I., and Fabrichnyi, P.B., Vestn. Mosk. Univ., Ser. 2: Khim., 2006, vol. 47, p. 353.

    CAS  Google Scholar 

  20. Balandin, A.A., Rozhdestvenskaya, I.D., and Slinkin, A.A., Dokl. Akad. Nauk SSSR, 1960, vol. 134, p. 110.

    CAS  Google Scholar 

  21. Morozova, N.I., Kulakova, I.I., Afanasov, M.I., and Fabrichnyi, P.B., Kinet. Katal., 2005, vol. 46, p. 406 [Kinet. Catal. (Engl. Transl.), vol. 46, p. 380].

    Article  Google Scholar 

  22. Fabritchnyi, P.B. and Fefilatiev, L.P., Solid State Commun., 1978, vol. 28, p. 513.

    Article  Google Scholar 

  23. Morozova, N.I., Abstracts of Papers, XXIII Vserossiiskaya shkola-simpozium molodykh uchenykh po khimicheskoi kinetike (XXIII All-Russ. School-Symp. of Yong Scientists on Chemical Kinetics), 2005, p. 76.

  24. Shirane, G., Pickart, S.J., and Ishikawa, Y., J. Phys. Soc. Jpn., 1959, vol. 14, p. 1352.

    Article  CAS  Google Scholar 

  25. Fabrichnyi, P.B., Afanasov, M.I., and Danot, M., Ross. Khim. Zh., 2007, vol. 51, p. 44 [Russ. J. Gen. Chem. (Engl. Transl.), 2008, vol. 78, no. 5, p. 1060].

    CAS  Google Scholar 

  26. Fabritchnyi, P.B., Afanasov, M.I., and Korolenko, M.V., Z. Naturforsch., B: Chem. Sci., 2008, vol. 63, p. 637.

    CAS  Google Scholar 

  27. Sazonov, I.S., Khokhlova, T.P., Sushchentseva, G.M., and Keier, N.P., Kinet. Katal., 1964, vol. 5, p. 1086.

    Google Scholar 

  28. Glavatskikh, P.S., Astashkin, R.A., Korolenko, M.V., Morozova, N.I., Kulakova, I.I., Afanasov, M.I., and Fabrichnyi, P.B., Abstracts of Papers, XI Mezhdunarodnaya konferentsiya “Messbauerovskaya spektroskopiya i ee primeneniya” (XI Int. Conf. on Mossbauer Spectroscopy and its Application), Ekaterinburg, 2009, p. 133.

  29. Fabritchnyi, P.B., Wattiaux, A., Korolenko, M.V., Afanasov, M.I., and Delmas, C., Solid State Commun., 2009, vol. 149, p. 1535.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Specialized Educational-Scientific Center, Moscow State University, Moscow, 119992, Russia

    N. I. Morozova

  2. Department of Radiochemistry, Moscow State University, Moscow, 119992, Russia

    M. I. Afanasov & P. B. Fabrichnyi

  3. Faculty of Chemistry, Moscow State University, Moscow, 119992, Russia

    R. A. Astashkin & M. V. Korolenko

  4. Department of Petroleum Chemistry and Organic Catalysis, Moscow State University, Moscow, 119992, Russia

    I. I. Kulakova

Authors
  1. N. I. Morozova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. I. Afanasov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. R. A. Astashkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. V. Korolenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. I. I. Kulakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. P. B. Fabrichnyi
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. I. Morozova.

Additional information

Original Russian Text © N.I. Morozova, M.I. Afanasov, R.A. Astashkin, M.V. Korolenko, I.I. Kulakova, P.B. Fabrichnyi, 2009, published in Vestnik Moskovskogo Universiteta. Khimiya, 2009, No. 5, pp. 317–327.

About this article

Cite this article

Morozova, N.I., Afanasov, M.I., Astashkin, R.A. et al. A diamagnetic Mossbauer probe method for studying a solid-gas interface and related catalytic processes. Moscow Univ. Chem. Bull. 64, 249–258 (2009). https://doi.org/10.3103/S0027131409050046

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.3103/S0027131409050046

Key words

Search

Navigation