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Hydrogen bond in the excited state of [2.2.2.2](1,2,4,5)cyclophane quinhydrones

  • Physicochemical Studies of Systems and Processes
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Abstract

Intra- and intermolecular hydrogen bond was studied in electron-donor-acceptor complexes in the excited state. It was shown that low-frequency shifts of electron-transfer bands are correlated with the strength of the hydrogen bond in the ground electron state. A satisfactory agreement was obtained between the results of quantum-chemical calculations of [2.2.2.2](1,2,4,5)cyclophane bisquinones and their reduced forms, [2.2.2.2] (1,2,4,5)cyclophane quinhydrones, with experimental data, and unusual physicochemical properties of quinhydrones are noted.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    K. K. Kalnin’sh

  2. St. Petersburg State University, St. Petersburg, Russia

    S. G. Semenov

Authors
  1. K. K. Kalnin’sh
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  2. S. G. Semenov
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Original Russian Text © K.K. Kalnin’sh, S.G. Semenov, 2011, published in Zhurnal Prikladnoi Khimii, 2011, Vol. 84, No. 1, pp. 61–67.

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Kalnin’sh, K.K., Semenov, S.G. Hydrogen bond in the excited state of [2.2.2.2](1,2,4,5)cyclophane quinhydrones. Russ J Appl Chem 84, 60–67 (2011). https://doi.org/10.1134/S1070427211010101

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  • DOI: https://doi.org/10.1134/S1070427211010101

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