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New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms

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Abstract

New hexanuclear Fe(III)–Mn(II, III) pivalates [Fe2 III Mn4 II(O)2(Piv)10(HPiv)4] (I) or [Fe4 III Mn2 III(O)2(Piv)12(CH2O2)(HPiv)2] · Et2O (II) are synthesized using the solid-state thermolysis of [Fe2Mn(O)(Piv)6(HPiv)3] (90°С). Complexes I and II differ by the ratio of iron and manganese ions, which depends on the atmospheric composition during thermolysis. The structures of compounds I and II are determined by X-ray diffraction studies. According to the parameters of the Mössbauer spectrum, complex I contains the Fe3+ ions in the high-spin state in the octahedral environment of oxygen atoms.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    I. A. Lutsenko, M. A. Kiskin, A. A. Sidorov & I. L. Eremenko

  2. Semenov Institute of Chemical Physics, Russian Academy of Sciences, ul. Kosygina 4, Moscow, 119991, Russia

    V. K. Imshennik & Yu. V. Maksimov

Authors
  1. I. A. Lutsenko
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  2. M. A. Kiskin
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  3. V. K. Imshennik
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  4. Yu. V. Maksimov
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  5. A. A. Sidorov
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  6. I. L. Eremenko
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Correspondence to I. A. Lutsenko.

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Original Russian Text © I.A. Lutsenko, M.A. Kiskin, V.K. Imshennik, Yu.V. Maksimov, A.A. Sidorov, I.L. Eremenko, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 6, pp. 323–329.

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Lutsenko, I.A., Kiskin, M.A., Imshennik, V.K. et al. New approach to the synthesis of polynuclear heterometallic pivalates with iron and manganese atoms. Russ J Coord Chem 43, 345–351 (2017). https://doi.org/10.1134/S1070328417060033

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  • DOI: https://doi.org/10.1134/S1070328417060033

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