Skip to main content
SpringerLink
Log in

Direct conversion of ethanol and fusel oils to alkane–aromatic hydrocarbons in the presence of a pilot Pd–Zn/TsVM catalyst

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

The conversion of ethanol and fusel oils to a С3–С12 alkane–aromatic fraction with high activity and selectivity in the presence of the Pd–Zn/TsVM pilot catalyst has been demonstrated. It has been shown that the ethanol conversion to alkanes and aromatic hydrocarbons in the presence of this catalyst proceeds by various routes to give ethylene and diethyl ether as intermediate products providing a 90–95% yield on the converted ethanol carbon basis for the target С3–С12 fraction containing up to 40% of branched alkanes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A. Demirbas, Biodiesel: A Realistic Fuel Alternative for Diesel Engines (Springer, London, 2008).

    Google Scholar 

  2. I. I. Ostromyslenskii, Zh. Russ. Fiz.-Khim. O-va 47, 1494 (1915).

    Google Scholar 

  3. C. V. Lebedev, Zh. Org. Khim. 3, 698 (1933).

    CAS  Google Scholar 

  4. M. V. Tsodikov, V. Ya. Kugel’, F. A. Yandieva, et al., Kinet. Catal. 45, 854 (2004).

    Article  CAS  Google Scholar 

  5. M. V. Tsodikov, F. A. Yandieva, V. Ya. Kugel, et al., Catal. Lett. 1, 25 (2008).

    Google Scholar 

  6. A. V. Chistyakov, M. V. Tsodikov, V. Yu. Murzin, et al., Kinet. Catal. 52, 258 (2011).

    Article  CAS  Google Scholar 

  7. V. F. Tret’yakov, Yu. I. Makarfi, R. M. Talyshinskii, N. A. Frantsuzova, K. V. Tret’yakov, Vestn. Mosk. Inst. Tonk. Khim. Tekhnol. 5, 5 (2010).

    Google Scholar 

  8. K. Inoue, M. Inaba, I. Takahara, and K. Murata, Catal. Lett. 136, 14 (2010).

    Article  CAS  Google Scholar 

  9. E. Derouane, J. B. Nagy, P. Dejaifve, et al., J. Catal. 53, 40 (1978).

    Article  CAS  Google Scholar 

  10. R. Johansson, S. L. Hruby, J. Rass-Hansen, and C. H. Christensen, Catal. Lett. 127, 6 (2009).

    Article  Google Scholar 

  11. A. M. Varvarin, K. N. Khomenko, and V. V. Brei, Theor. Exp. Chem. 47, 36 (2001).

    Article  Google Scholar 

  12. C. W. Ingram and R. J. Lancashire, Catal. Lett. 31, 395 (1995).

    Article  CAS  Google Scholar 

  13. A. T. Aguayo, A. G. Gayubo, A. Atutxa, et al., Ind. Eng. Chem. Res. 41, 4216 (2002).

    Article  CAS  Google Scholar 

  14. V. V. Yushchenko, Russ. J. Phys. Chem. 71, 547 (1997).

    Google Scholar 

  15. A. Chistyakov, M. Tsodikov, M. Chudakova, A. Gekhman, I. Moiseev, Chem. Eng. Trans. 24, 175 (2011).

    Google Scholar 

  16. A. V. Chistyakov, V. Yu. Murzin, M. V. Chudakova, and M. A. Gubanov, in Proceedings of the Russian Congress on Catalysis “Roskataliz” (Moscow, 2011), p. 115 [in Russian].

    Google Scholar 

  17. N. I. Shuikin and I. F. Bel’skii, Dokl. Akad. Nauk SSSR 120 (3), 19 (1958).

    Google Scholar 

  18. A. L. Liberman, O. V. Bragin, and T. V. Vasina, Izv. Akad. Nauk SSSR, Ser. Khim., No. 7, 1352 (1963).

    Google Scholar 

  19. F. A. Yandieva, M. V. Tsodikov, A. V. Chistyakov, et al., Kinet. Catal. 51, 548 (2010).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    A. V. Chistyakov, M. V. Tsodikov, M. V. Chudakova, M. A. Gubanov, P. A. Zharova, Z. M. Bukina, N. V. Kolesnichenko & S. N. Khadzhiev

  2. Moscow Institute of Physics and Technology (State University), Dolgoprudnyi, Moscow oblast, Russia

    A. V. Chistyakov, M. V. Tsodikov, P. A. Zharova & A. E. Gekhman

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

    A. E. Gekhman

Authors
  1. A. V. Chistyakov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. V. Tsodikov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. M. V. Chudakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. A. Gubanov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. P. A. Zharova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Z. M. Bukina
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. N. V. Kolesnichenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. A. E. Gekhman
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. S. N. Khadzhiev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. V. Chistyakov.

Additional information

Original Russian Text © A.V. Chistyakov, M.V. Tsodikov, M.V. Chudakova, M.A. Gubanov, P.A. Zharova, Z.M. Bukina, N.V. Kolesnichenko, A.E. Gekhman, S.N. Khadzhiev, 2018, published in Neftekhimiya, 2018, Vol. 58, No. 1, pp. 36–46.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chistyakov, A.V., Tsodikov, M.V., Chudakova, M.V. et al. Direct conversion of ethanol and fusel oils to alkane–aromatic hydrocarbons in the presence of a pilot Pd–Zn/TsVM catalyst. Pet. Chem. 58, 32–42 (2018). https://doi.org/10.1134/S096554411801005X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S096554411801005X

Keywords

Search

Navigation