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Regularities in the consumption of the initial reactants in various kinetic regimes

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Abstract

Using hydrogen oxidation as an example, it is demonstrated that, when gas ignition is prevented by means of inhibition, there is practically no consumption of the initial reactants because reaction chains do not form for lack of time and the rates of intermolecular reactions are insignificant. When the propagating flame and detonation wave are partially suppressed, the inhibitor is consumed only in chain termination reactions involving reactive intermediate species. Oxygen is additionally consumed in its reactions with products of incomplete inhibitor conversion.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Research Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, 142432, Russia

    V. V. Azatyan, G. V. Balayan, V. M. Prokopenko & N. V. Chapysheva

Authors
  1. V. V. Azatyan
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  2. G. V. Balayan
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  3. V. M. Prokopenko
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  4. N. V. Chapysheva
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Correspondence to V. V. Azatyan.

Additional information

Original Russian Text © V.V. Azatyan, G.V. Balayan, V.M. Prokopenko, N.V. Chapysheva, 2016, published in Kinetika i Kataliz, 2016, Vol. 57, No. 1, pp. 20–24.

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Azatyan, V.V., Balayan, G.V., Prokopenko, V.M. et al. Regularities in the consumption of the initial reactants in various kinetic regimes. Kinet Catal 57, 17–21 (2016). https://doi.org/10.1134/S0023158416010018

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  • DOI: https://doi.org/10.1134/S0023158416010018

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