Abstract
The mathematical model of thermal explosion and synthesis of products in a mechanically activated 3Ni + Al mixture is simulated in macroscopic approximation. It is shown that activation of original components significantly increases the formation rate of a Ni3Al intermetallide. The experimental data are used to determine the thermophysical and kinetic constants of the process.
Similar content being viewed by others
References
E. G. Avvakumov, Mechanical methods of Activation of Chemical Processes. Second Edition (Nauka, Novosibirsk, 1986) [in Russian].
V. K. Smolyakov and O. V. Lapshin, Macroscopic Kinetics of Mechanochemical Synthesis (Izd. Inst. Opt. Atm. Zueva, Sib Otd. Ross. Akad. Nauk, Tomsk, 2011) [in Russian].
M. A. Korchagin, “Thermal explosion in Mechanically Activated Low-Calorific-Value Compositions,” Fiz. Goreniya Vzryva 51 (5), 77–86 (2015) [Combust., Expl., Shock Waves 51 (5), 578–586 (2015)].
O. V. Lapshin and V. K. Smolyakov, “Formation of Layered Structures of Mechanocomposites in Grinding of Binary Mixtures,” Khim. Fiz. Mezoskop. 15 (2), 272–278 (2013).
V. I. Itin and Y. S. Naiborodenko, High-Temperature Synthesis of Intermetallic Compounds (Izd. Tomsk. Gos. Univ., Tomsk, 1989) [in Russian].
C. J. Smithells, Metals (Butterworth, 1949).
A. P. Babichev, N. A. Babushkina, A. M. Bratkovskii, et al., Physical Quantities: Reference Book, Ed. by I. S. Grigor’eva and E. Z. Meilikhova (Energoatomisdat, Moscow, 1991) [in Russian].
M. A. Korchagin, V. Yu. Filimonov, E. V. Smirnov, et al., “Thermal Explosion of a Mechanically Activated 3Ni + Al Mixture,” Fiz. Goreniya Vzryva 46 (1), 48–53 (2010) [Combust., Expl., Shock Waves 46 (1), 41–46 (2010)].
V. Yu. Filimonov, M. A. Korchagin, A. A. Smirnov, et al., “Kinetics of Mechanically Activated High-Temperature Synthesis of Ni3Al in the Thermal Explosion Mode,” Intermetallics, No. 19, 833–840 (2011).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © O.V. Lapshin, V.K. Smolyakov.
Published in Fizika Goreniya i Vzryva, Vol. 53, No. 5, pp. 64–69, September–October, 2017.
Rights and permissions
About this article
Cite this article
Lapshin, O.V., Smolyakov, V.K. Simulation of thermal explosion in a pre-activated 3Ni + Al mixture. Combust Explos Shock Waves 53, 548–553 (2017). https://doi.org/10.1134/S0010508217050070
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0010508217050070