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Influence of structural deformations on the magnetic properties of Jahn-Teller complexes of divalent copper in CaxSr1−x F2 mixed crystals

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Abstract

Crystals of variable constituency CaxSr1−x F2:Cu (0⩽x⩽0.05, x≅0.5, 1.0⩾x⩾0.95) are investigated by EPR and x-ray structural analysis. The electron-Zeeman, intrinsic hyperfine, and ligand hyperfine interaction parameters are determined; they characterize the magnetic properties of the copper paramagnetic complexes formed in the crystals. Models of the molecular structures of these complexes are discussed, along with the influence of structural deformations and vibronic interactions on their magnetic properties.

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References

  1. M. C. M. O’Brien, Phys. Rev. B 187, 407 (1969).

    Google Scholar 

  2. M. M. Zaripov and V. A. Ulanov, Fiz. Tverd. Tela (Leningrad) 30, 1547 (1988) [Sov. Phys. Solid State 30, 896 (1988)].

    Google Scholar 

  3. M. M. Zaripov and V. A. Ulanov, Fiz. Tverd. Tela (Leningrad) 31(10), 251 (1989) [Sov. Phys. Solid State 31, 1796 (1989)].

    Google Scholar 

  4. H. Bill, Phys. Lett. A 44, 11 (1973).

    Article  ADS  Google Scholar 

  5. M. M. Zaripov, V. A. Ulanov, and M. L. Falin, Fiz. Tverd. Tela (Leningrad) 31(2), 248 (1989) [Sov. Phys. Solid State 31, 319 (1989)].

    Google Scholar 

  6. M. M. Zaripov, V. A. Ulanov, and M. L. Falin, Fiz. Tverd. Tela (Leningrad) 31(11), 289 (1989) [Sov. Phys. Solid State 31, 2004 (1989)].

    Google Scholar 

  7. H. Bill and R. Lacroix, in Proceedings of the Twelfth Congress Ampere (1973), p. 233.

  8. C. A. Bates, W. S. Moore, K. J. Standley, and K. W. H. Stevens, Proc. Phys. Soc. London 79, 73 (1962).

    Google Scholar 

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Fiz. Tverd. Tela (St. Petersburg) 40, 445–451 (March 1998)

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Ulanov, V.A., Zaripov, M.M., Shustov, V.A. et al. Influence of structural deformations on the magnetic properties of Jahn-Teller complexes of divalent copper in CaxSr1−x F2 mixed crystals. Phys. Solid State 40, 408–414 (1998). https://doi.org/10.1134/1.1130334

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  • DOI: https://doi.org/10.1134/1.1130334

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