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Neodymium(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and photophysical properties

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Abstract

The reaction of NdCl3 with 1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dione (HL) and 1,10-phenanthroline (Phen) in the presence of a base afforded complex [Nd(L)3Phen] (I). Unstable solvate I · 2CH2Cl2 was obtained from a solution of the complex in dichloromethane, and its structure was determined by X-ray diffraction analysis. The photophysical properties of the complex were studied. Possible routes for the energy transfer in the course of photoluminescence were proposed.

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References

  1. Binnemans, K., in Handbook of the Physics and Chemistry of Rare-Earths, Gschneidner, K.A., Bunzli, J.G., Pecharsky, V.K., Eds., New York: Elsevier, 2005, vol. 35, p. 107.

  2. Zimnyakov, D.A. and Tuchin, V.V., Kvant. Elektronika, 2002, vol. 32, no. 10, p. 849.

    Article  CAS  Google Scholar 

  3. Rusakova, N.V., Meshkova, S.B., Venchikov, V.Ya., et al., Zh. Prikl. Spektrosk., 1992, vol. 56, nos. 5–6, p. 799.

    Google Scholar 

  4. Taydakov, I.V. and Krasnosel’skii, S.S., Khim. Geterotsikl. Soedin., 2011, no. 6, p. 843.

    Google Scholar 

  5. APEX II (version 2.0-1), SADABS (version 2004/1), Madison (WI, USA): Bruker AXS Inc., 2005.

  6. Sheldrick G.M., SHELXTL PLUS (version 5.10). Structure Determination Software Suite, Madison (WI, USA): Bruker AXS Inc. 1998.

    Google Scholar 

  7. Spek, A.L., PLATON: A Multipurpose Crystallographic Tool, Utrecht (The Netherlands): Utrecht Univ., 1999.

    Google Scholar 

  8. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Crystallogr., 2008, vol. 64, p. 112.

    Article  CAS  Google Scholar 

  9. Leipoldt, J.G., Bok, D.C.L., Basson, S.S., et al., J. Inorg. Nucl. Chem., 1976, vol. 38, p. 1477.

    Article  CAS  Google Scholar 

  10. Puntus, L.N., Lyssenko, K.A., Bunzli, J.-C.G., et al., J. Phys. Chem., B, 2009, vol. 113, p. 9265.

    Article  CAS  Google Scholar 

  11. Chen, D., Wang, Y., Yu, Y., et al., Mater. Sci. Eng., B, 2005, vol. 123, p. 1.

    Article  Google Scholar 

  12. She, J., Li, D., Hou, C., et al., J. Rare. Earths, 2011, vol. 29, p. 193.

    Article  CAS  Google Scholar 

  13. Wyart, J.-F., Meftah, A., Bachelier, A., et al., J. Phys. B, 2006, vol. 39, p. L77.

    Article  CAS  Google Scholar 

  14. Taydakov, I.V., Zaitsev, B.E., Krasnosel’skii, S.S., et al., Russ. J. Inorg. Chem., 2011, vol. 56, no 3, p. 345.

    Article  CAS  Google Scholar 

  15. Xu, C., Monatsh. Chem., 2010, vol. 141, p. 631.

    Article  CAS  Google Scholar 

  16. Binnemans, K., Van Deun, R., Gorller-Walrand, C., et al., J. Alloys Comp., 1998, vols. 275–277, p. 455.

    Article  Google Scholar 

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Authors and Affiliations

  1. Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, Moscow, 119991, Russia

    I. V. Taidakov, A. N. Lobanov, L. S. Lepnev & A. G. Vitukhnovskii

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  1. I. V. Taidakov
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  2. A. N. Lobanov
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  3. L. S. Lepnev
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  4. A. G. Vitukhnovskii
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Correspondence to I. V. Taidakov.

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Original Russian Text © I.V. Taidakov, A.N. Lobanov, L.S. Lepnev, A.G. Vitukhnovskii, 2014, published in Koordinatsionnaya Khimiya, 2014, Vol. 40, No. 1, pp. 20–26.

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Taidakov, I.V., Lobanov, A.N., Lepnev, L.S. et al. Neodymium(III) tris(1,3-bis(1,3-dimethyl-1H-pyrazol-4-yl)propane-1,3-dionato)(1,10-phenanthroline): Synthesis and photophysical properties. Russ J Coord Chem 40, 16–22 (2014). https://doi.org/10.1134/S1070328414010060

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  • DOI: https://doi.org/10.1134/S1070328414010060

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