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Synthesis and Properties of Acidic 3d-Metal Urates

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Abstract

Acidic urates [Mn(HL)2] · H2O, [FeOH(HL)2]2 · 4H2O, [Co(HL)2(H2O)2] · 2H2O, and [Ni(HL)2(H2O)2] · 2H2O (H2L is uric acid) were synthesized and their structures and physicochemical properties were studied using IR spectroscopy, diffuse reflection spectroscopy, DTA, and magnetochemistry methods. The metals were shown to coordinate the urate anion through oxygen and nitrogen atoms. The [FeOH(HL)2]2 · 4H2O complex has a dimeric structure.

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  1. Mechnikov National University, Odessa, Ukraine

    T. V. Koksharova

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  1. T. V. Koksharova
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Koksharova, T.V. Synthesis and Properties of Acidic 3d-Metal Urates. Russian Journal of Coordination Chemistry 28, 505–509 (2002). https://doi.org/10.1023/A:1016257429532

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