Skip to main content
SpringerLink
Log in

Syntheses and structures of [UO2(L)5](ClO4)2 and [U(L′)4(H2O)4](ClO4)4 (L is dimethylformamide, L′ is N,N-dimethylcarbamide)

  • Structure of Organic Compounds
  • Published:
Crystallography Reports Aims and scope Submit manuscript

Abstract

The reaction of aqueous solutions of uranyl perchlorate with selected organic amides was studied in the dark and under the sunlight. The complexes [UVIO2(C3H7NO)5](ClO4)2 (I) and [UIV(C3H8N2O)4(Н2О)4](ClO4)4 (II), where C3H7NO is N,N-dimethylformamide (Dmfa) and C3H8N2O is N,N-dimethylcarbamide (a-Dmur), were studied by X-ray diffraction. Complex II and the complex UIV(s-Dmur)4(Н2О)4(ClO4)4 (III), where s-Dmur is N,N'-dimethylcarbamide, were studied by IR spectroscopy. Crystals I and II are composed of mononuclear [UO2(Dmfa)5]2+ and [U(Dmur)4(Н2О)4]4+ groups as uranium-containing structural units belonging to the crystal-chemical groups AМ 7 1 (А = UVI, М 1 = O2– and Dmfa) and AМ 8 1 (А = UIV, М 1 = Dmur and Н2О) of uranium complexes, respectively. The mononuclear uranium- containing complexes in the crystals of U(IV) and U(VI) perchlorates were found to obey the 14 neighbors rule.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. E. Rabinowitch and R. L. Belford, Spectroscopy and Photochemistry of Uranyl Compounds (Pergamon Press, London, 1964).

    Google Scholar 

  2. A. L. Buchachenko and I. V. Khudyakov, Usp. Khim. 60 (6), 1105 (1991).

    Article  Google Scholar 

  3. C. K. Jøgensen, Rev. Chim. Mineral. 14, 127 (1977).

    Google Scholar 

  4. Complex Uranium Compounds, Ed. by I. I. Chernyaev (Nauka, Moscow, 1964) [in Russian].

  5. J. G. Conway, J. Chem. Phys. 31, 1002 (1959).

    Article  ADS  Google Scholar 

  6. D. Cohen and W. T. Carnall, J. Phys. Chem. 64, 1933 (1960).

    Article  Google Scholar 

  7. A. Cabeza, M. A. G. Aranda, F. M. Cantero, et al., J. Solid State Chem. 121, 181 (1996).

    Article  ADS  Google Scholar 

  8. M. Karbowiak, A. Mech, and J. Drożdżyński, Chem. Phys. 308, 135 (2005).

    Article  ADS  Google Scholar 

  9. L. B. Serezhkina, A. V. Vologzhanina, E. O. Prudnikova, and V. N. Serezhkin, Crystallogr. Rep. 55 (5), 780 (2010).

    Article  ADS  Google Scholar 

  10. P. A. Vigato, U. Casellato, and M. Vidali, Gazz. Chim. Ital. 107, 61 (1977).

    Google Scholar 

  11. K. Takao, S. Takao, Y. Ikeda, et al., Dalton Trans. 42, 13101 (2013).

    Article  Google Scholar 

  12. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed. (Wiley, New York, 1986).

    Google Scholar 

  13. Y. Mido and H. Murata, Bull. Chem. Soc. Jpn. 42 (12), 3372 (1969).

    Article  Google Scholar 

  14. Bruker (2005). APEX2 Software Package (Bruker AXS Inc., Madison, WI, 2005).

  15. G. M. Sheldrick, SADABS v. 2.01, Bruker/Siemens Area Detector Absorption Correction Program (Bruker AXS, Madison, 1998).

    Google Scholar 

  16. G. M. Sheldrick, Acta Crystallogr. A 71, 3 (2015).

    Article  Google Scholar 

  17. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, et al., J. Appl. Crystallogr. 42, 339 (2009).

    Article  Google Scholar 

  18. V. N. Serezhkin, T. N. Polynova, and M. A. Porai-Koshits, Koord. Khim. 21 (4), 253 (1995).

    Google Scholar 

  19. V. N. Serezhkin, Ya. A. Medvedkov, L. B. Serezhkina, and D. V. Pushkin, Zh. Fiz. Khim. 89 (6), 978 (2015).

    Google Scholar 

  20. V. N. Serezhkin, Structural Chemistry of Inorganic Actinide Compounds, Ed. by S. V. Krivovichev (Elsevier, Amsterdam, 2007), p. 31.

    Book  Google Scholar 

  21. V. N. Serezhkin, M. O. Karasev, and L. B. Serezhkina, Radiochemistry 55 (2), 137 (2013).

    Article  Google Scholar 

  22. V. N. Cerezhkin, Yu. N. Mikhailov, and Yu. A. Buslaev, Zh. Neorg. Khim. 42 (12), 2036 (1997).

    Google Scholar 

  23. D. V. Korol’kov and G. A. Skorobogatov, Theoretical Chemistry (Izd-vo S.-PbGU, St. Petersburg, 2005) [in Russian].

    Google Scholar 

  24. V. N. Serezhkin, A. G. Verevkin, D. V. Pushkin, and L. B. Serezhkina, Russ. J. Coord. Chem. 34 (3), 225 (2008).

    Article  Google Scholar 

  25. V. N. Serezhkin, D. V. Pushkin, and L. B. Serezhkina, Russ. J. Coord. Chem. 32 (11), 801 (2006).

    Article  Google Scholar 

  26. V. N. Serezhkin, L. B. Serezhkina, and D. V. Pushkin, Zh. Strukt. Khim. 50, S18 (2009).

    Google Scholar 

  27. A. Fischer, Z. Anorg. Allg. Chem. 629 (6), 1012 (2003).

    Article  Google Scholar 

  28. N. W. Alcock and S. Esperas, J. Chem. Soc. Dalton Trans. 893 (1977).

    Google Scholar 

  29. G. B. Andreev, M. Yu. Antipin, N. A. Budantseva, et al., Russ. J. Coord. Chem. 30 (12), 919 (2004).

    Article  Google Scholar 

  30. G. J. Honan, D. L. Kepert, S. F. Lincoln, et al., Aust. J. Chem. 33 (1), 69 (1980).

    Article  Google Scholar 

  31. J. M. Harrowfield, D. L. Kepert, J. M. Patrick, et al., J. Chem. Soc., Dalton Trans., No. 2, 393 (1983).

    Article  Google Scholar 

  32. J. M. Harrowfield, M. I. Ogden, B. W. Skelton, and A. H. White, J. Chem. Soc., Dalton Trans. 39, 8313 (2010).

    Article  Google Scholar 

  33. N. Koshino, Y. Kachi, T. R. Varga, et al., Inorg. Chim. Acta 362 (10), 3433 (2009).

    Article  Google Scholar 

  34. N. A. Budantseva, M. S. Grigor’ev, V. I. Mishkevich, et al., Russ. J. Coord. Chem. 37 (9), 701 (2011).

    Article  Google Scholar 

  35. R. D. Rogers, L. K. Kurihara, and M. M. Benning, J. Inclusion Phenom. Mol. Recog. Chem. 5, 645 (1987).

    Article  Google Scholar 

  36. M. S. Grigor’ev and N. N. Krot, Radiokhimiya 52 (4), 318 (2010).

    Google Scholar 

  37. Inorganic Crystal Structure Database (Gmelin-institut fur Anoranische Chemie & FIC, Karlsruhe, 2012).

  38. Cambridge Structural Database System (Cambridge Crystallographic Data Centre, Cambridge, 2015).

  39. V. N. Serezhkin and L. B. Serezhkina, Crystallogr. Rep. 57 (1), 33 (2012).

    Article  ADS  Google Scholar 

  40. V. N. Serezhkin, L. B. Serezhkina, and A. V. Vologzhanina, Acta Crystallogr. B. 68 (3), 305 (2012).

    Article  Google Scholar 

  41. V. N. Serezhkin and A. V. Savchenkov, Cryst. Growth Des. 15, 2878 (2015).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Samara National Research University, Samara, 443011, Russia

    V. N. Serezhkin, D. V. Pushkin, D. A. Astashkina, A. V. Savchenkov & L. B. Serezhkina

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, 119991, Russia

    A. V. Vologzhanina

Authors
  1. V. N. Serezhkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. V. Vologzhanina
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. D. V. Pushkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. D. A. Astashkina
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. V. Savchenkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. L. B. Serezhkina
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. N. Serezhkin.

Additional information

Original Russian Text © V.N. Serezhkin, A.V. Vologzhanina, D.V. Pushkin, D.A. Astashkina, A.V. Savchenkov, L.B. Serezhkina, 2017, published in Kristallografiya, 2017, Vol. 62, No. 5, pp. 751–760.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Serezhkin, V.N., Vologzhanina, A.V., Pushkin, D.V. et al. Syntheses and structures of [UO2(L)5](ClO4)2 and [U(L′)4(H2O)4](ClO4)4 (L is dimethylformamide, L′ is N,N-dimethylcarbamide). Crystallogr. Rep. 62, 725–733 (2017). https://doi.org/10.1134/S1063774517050170

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063774517050170

Search

Navigation