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Materials recovery from end-of-life wind turbine magnets

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Abstract

Neodymium–iron–boron permanent magnets are increasingly used in green energy technologies, such as wind turbines and electric vehicles. In the near future, an increasing amount of magnets will reach their end-of-life stage, andtherefore, it is imperative to develop proper recycling routes aimed at the valorization of this waste fraction. In this work, a room temperature hydrometallurgical process was developed aimed at the recovery of both iron and rare earths contained in end-of-life wind turbine magnets. The process is based on a leaching step with nitric acid, followed by two precipitation steps and calcination. Iron hydroxide(III) and rare earth oxide with purity grade equal to 98% and 99%, respectively, were obtained. Based on these results, a process flowsheet was proposed for industrial implementation.

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References

  • Alonso E, Sherman AM, Wallington TJ, Everson MP, Field FR, Roth R, Kirchain RE (2012) Evaluating rare earth element availability: a case with revolutionary demand from clean technologies. Environ Sci Technol 46:3406–3414

    Article  CAS  Google Scholar 

  • Bandara HMD, Field KD, Emmert MH (2016) Rare earth recovery from end-of-life motors employing green chemistry design principles. Green Chem 18:753–759

    Article  CAS  Google Scholar 

  • Binnemans K, Jones PT, Blanpain B, Van Gerven T, Yang Y, Walton A, Buchert M (2013) Recycling of rare earths: a critical review. J Clean Prod 51:1–22

    Article  CAS  Google Scholar 

  • Chironna RJ (2011) Wet scrubbing of acidic gases. Apc. https://www.s-k.com/pdf/wet_scrubbers.pdf. . Accessed 1 Mar 2021

  • De Almeida L, Grandjean S, Vigier N, Patisson F (2012) Insights into the thermal decomposition of Lanthanide(III) and Actinide(III) oxalates—from neodymium and cerium to plutonium. Eur J Inorg Chem 31:4986–4999

    Article  Google Scholar 

  • Du X, Graedel TE (2011) Global rare earth in-use stocks in NdFeB permanent magnets. J Ind Ecol 15:836–843

    Article  CAS  Google Scholar 

  • Elwert T, Goldmann D, Roemer F, Schwarz S (2017) Recycling of NdFeB magnets from electric drive motors of (hybrid) electric vehicles. J Sustain Metall 3:108–121

    Article  Google Scholar 

  • European Commission (2020) Study on the EU’s list of critical raw materials—Final Report. https://doi.org/10.2873/904613

  • European Commission COM (2020) 98 final. Communication from the Commission to the European Parliament, the Council, the European Economic and Social Committee and the Committee of the Regions—A new Circular Economy Action Plan For a cleaner and more competitive Europe

  • Fontana D, Pietrantonio M, Pucciarmati S, Rao C, Forte F (2019) A comprehensive characterization of End-of-Life mobile phones for secondary material resources identification. Waste Manag 99:22–30

    Article  Google Scholar 

  • González González M, Cabanelas JC, Baselga J (2011) Applications of FTIR on epoxy resins—identification, monitoring the curing process, phase separation and water uptake. In: InTech (ed) Infrared spectroscopy—materials science, engineering and technology, pp 261–284

  • Han KN (2020) Characteristics of precipitation of rare earth elements with various precipitants. Minerals 10:178

    Article  CAS  Google Scholar 

  • Horikawa T, Miura K, Itoh M, Machida KI (2006) Effective recycling for Nd–Fe–B sintered magnet scraps. J Alloys Compd 408–412:1386–1390

    Article  Google Scholar 

  • Huber C, Abert C, Bruckner F, Groenefeld M, Schuschnigg S, Teliban I, Vogler C, Wautischer G, Windl R, Suess D (2017) 3D printing of polymer-bonded rare-earth magnets with a variable magnetic compound fraction for a predefined stray field. Sci Rep 7:1–8

    Article  Google Scholar 

  • Itoh M, Miura K, Machida K-I (2009) Novel rare earth recovery process on Nd–Fe–B magnet scrap by selective chlorination using NH4Cl. J Alloys Compd 477:484–487

    Article  CAS  Google Scholar 

  • Kumari A, Sinha MK, Pramanik S, Sahu SK (2018) Recovery of rare earths from spent NdFeB magnets of wind turbine: leaching and kinetic aspects. Waste Manag 75:486–498

    Article  CAS  Google Scholar 

  • Lee CH, Chen YJ, Liao CH, Popuri SR, Tsai SL, Hung CE (2013) Selective leaching process for neodymium recovery from scrap Nd–Fe–B magnet. Metall Mater Trans A 44:5825–5833

    Article  CAS  Google Scholar 

  • Okabe TH, Takeda O, Fukuda K, Umetsu Y (2003) Direct extraction and recovery of neodymium metal from magnet scrap. Mater Trans 44:798–801

    Article  CAS  Google Scholar 

  • Önal MAR, Borra CR, Guo M, Blanpain B, Van Gerven T (2017) Hydrometallurgical recycling of NdFeB magnets: Complete leaching iron removal and electrolysis. J Rare Earths 35(6):574–584 https://doi.org/10.1016/S1002-0721(17)60950-5

    Article  Google Scholar 

  • Önal MAR, Dewilde S, Degri M, Pickering L, Saje B, Riaño S, Walton A, Binnemans K (2020) Recycling of bonded NdFeB permanent magnets using ionic liquids. Green Chem 22:2821–2830

    Article  Google Scholar 

  • Persson I (2018) Ferric chloride complexes in aqueous solution: an EXAFS study. J Solut Chem 47:797–805

    Article  CAS  Google Scholar 

  • Rademaker JH, Kleijn R, Yang Y (2013) Recycling as a strategy against rare earth element criticality: a systemic evaluation of the potential yield of NdFeB magnet recycling. Environ Sci Technol 47:10129–10136

    Article  CAS  Google Scholar 

  • Saito T, Sato H, Ozawa S, Yu J, Motegi T (2003) The extraction of Nd from waste Nd–Fe–B alloys by the glass slag method. J Alloys Compd 353:189–193

    Article  CAS  Google Scholar 

  • Sethurajan M, van Hullebusch ED, Fontana D, Akcil A, Deveci H, Batinic B, Leal JP, Gasche TA, Kucuker MA, Kuchta K, Neto IFF, Soares HMVM, Chmielarz A (2019) Recent advances on hydrometallurgical recovery of critical and precious elements from end of life electronic wastes—a review. Crit Rev Environ Sci Technol 49:212–275

    Article  CAS  Google Scholar 

  • Uda T (2002) Recovery of rare earths from magnet sludge by FeCl2. Mater Trans 43:55–62

    Article  CAS  Google Scholar 

  • Van Gosen BS, Verplanck PL, Gambogi J (2017) Rare-earth elements. In: Schulz KJ, DeYoung JH, Jr, Seal, RR, II, Bradley DC (ed) Critical mineral resources of the United States—economic and environmental geology and prospects for future supply, pp O1–O31. https://doi.org/10.3133/pp1802O

  • WindEurope (2019) Wind energy in Europe: Outlook to 2023. https://windeurope.org/about-wind/reports/wind-energy-in-europe-outlook-to-2023/. Accessed 1 Mar 2021

  • WindEurope (2020) Decommissioning of Onshore Wind Turbines—Industry Guidance Document. https://windeurope.org/intelligence-platform/product/decommissioning-of-onshore-wind-turbines/. Accessed 1 Mar 2021

  • Yang Y, Walton A, Sheridan R, Güth K, Gauß R, Gutfleisch O, Buchert M, Steenari BM, Van Gerven T, Jones PT, Binnemans K (2017) REE recovery from end-of-life NdFeB permanent magnet scrap: a critical review. J Sustain Metall 3:122–149

    Article  Google Scholar 

  • Zakotnik M, Harris IR, Williams AJ (2008) Possible methods of recycling NdFeB-type sintered magnets using the HD/degassing process. J Alloys Compd 450:525–531

    Article  CAS  Google Scholar 

  • Zhang Y, Gu F, Su Z, Liu S, Anderson C, Jiang T (2020) Hydrometallurgical recovery of rare earth elements from NdFeB permanent magnet scrap: a review. Metals 10:841

    Article  CAS  Google Scholar 

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Acknowledgements

The Authors acknowledge The Switch A Yaskawa Company for providing the magnet sample.

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The authors received no specific funding for this work.

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All authors contributed equally to the work.

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Correspondence to D. Fontana.

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This article does not contain any studies with human participants or animals performed by any of the authors.

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Editorial responsibility: Maryam Shabani.

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Pietrantonio, M., Pucciarmati, S., Sebastianelli, L. et al. Materials recovery from end-of-life wind turbine magnets. Int. J. Environ. Sci. Technol. 19, 8019–8026 (2022). https://doi.org/10.1007/s13762-021-03546-1

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  • DOI: https://doi.org/10.1007/s13762-021-03546-1

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