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Solid Phase Luminescence and Thermal Transformations of Palladium(II) Complexes with 3-(2-Pyridyl)-1,2,4-Triazoles

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Theoretical and Experimental Chemistry Aims and scope

The thermal behavior and luminescent properties of palladium(II) Pd(LR)2 complexes with 3-(2-pyridyl)-5-R-1,2,4-triazoles (LR , where R = H, Ph, Me) in cristalline state were studied. Analysis of the stationary and time-resolved Pd(LMe)2 photoluminescence spectra showed that the introduction of electron–donor methyl substituent into a coordinated ligand is accompanied by emission in the green range of the spectrum (fluorescence, λmax = 442 nm). Molecule aggregation in Pd(LH)2 and Pd(LPh)2 complexes leads to a bathochromic shift of emission (phosphorescence, 𝜆max = 712 and 691 nm).

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Authors and Affiliations

  1. Taras Shevchenko Kyiv National University, Kyiv, Ukraine

    B. V. Zakharchenko, D. M. Khomenko, R. O. Doroshchuk, I. V. Raspertova, I. V. Fesych, V. S. Starova & R. D. Lampeka

  2. A. V. Bogatsky Physico-Chemical Institute, NAS of Ukraine, Odesa, Ukraine

    N. V. Rusakova & S. S. Smola

  3. “Petru Poni” Institute of Macromolecular Chemistry, Iasi, Romania

    S. Shova

Authors
  1. B. V. Zakharchenko
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  2. D. M. Khomenko
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  3. R. O. Doroshchuk
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  4. I. V. Raspertova
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  5. I. V. Fesych
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  6. V. S. Starova
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  7. N. V. Rusakova
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  8. S. S. Smola
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  9. S. Shova
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  10. R. D. Lampeka
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Corresponding author

Correspondence to B. V. Zakharchenko.

Additional information

Translated from Teoretychna ta Eksperymentalna Khimiya, Vol. 57, No. 5, pp. 307-313, September-October, 2021.

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Zakharchenko, B.V., Khomenko, D.M., Doroshchuk, R.O. et al. Solid Phase Luminescence and Thermal Transformations of Palladium(II) Complexes with 3-(2-Pyridyl)-1,2,4-Triazoles. Theor Exp Chem 57, 358–365 (2021). https://doi.org/10.1007/s11237-021-09705-2

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  • DOI: https://doi.org/10.1007/s11237-021-09705-2

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