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Synthesis and thermal behavior study of complexes of the type [Pd(μ-X)(4-eb-p-phen)]2 (X = Cl, Br, I, N3, NCO, SCN) and 4-eb-p-phen [bis(4-ethylbenzyl)p-phenylenediimine]

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Abstract

The Schiff base bis(4-ethylbenzyl) p-phenylenediimine, 4-eb-p-phen (1), and six new dimeric Pd(II) complexes of the type [Pd(μ-X)(4-eb-p-phen)]2 {X = Cl (2), Br (3), I (4), N3 (5), NCO (6), SCN (7)} have been synthesized and characterized by elemental analysis, IR spectroscopy, and 1H and 13C{1H}-NMR experiments. The thermal behavior of the complexes 2–7 has been investigated by means of thermogravimetry and differential thermal analysis. From the final decomposition temperatures, the thermal stability of the complexes can be ordered in the following sequence: 3 > 4 > 7 > 2 ≈ 5 > 6. The final products of the thermal decompositions were characterized as metallic palladium by X-ray powder diffraction (XRD).

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Acknowledgements

We thank CAPES, CNPq, FINEP, and FAPEMIG for financial support and scholarship: Bozza GF (CAPES), Sarto LE (FAPEMIG).

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Authors and Affiliations

  1. UNIFAL - MG - Univ Federal de Alfenas, Instituto de Química, CEP, Alfenas, MG, 37130-000, Brazil

    Gabriela Francini Bozza, Luis Eduardo Sarto, Claudia Torres & Eduardo Tonon de Almeida

  2. UNESP - Univ Estadual Paulista, Instituto de Química, CEP, Araraquara, SP, 14801-970, Brazil

    Adelino Vieira de Godoy Netto

Authors
  1. Gabriela Francini Bozza
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  2. Luis Eduardo Sarto
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  3. Claudia Torres
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  4. Adelino Vieira de Godoy Netto
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  5. Eduardo Tonon de Almeida
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Correspondence to Eduardo Tonon de Almeida.

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Bozza, G.F., Sarto, L.E., Torres, C. et al. Synthesis and thermal behavior study of complexes of the type [Pd(μ-X)(4-eb-p-phen)]2 (X = Cl, Br, I, N3, NCO, SCN) and 4-eb-p-phen [bis(4-ethylbenzyl)p-phenylenediimine]. J Therm Anal Calorim 118, 67–74 (2014). https://doi.org/10.1007/s10973-014-4015-9

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  • DOI: https://doi.org/10.1007/s10973-014-4015-9

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