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Hydrogenation of biphenyl and isomeric terphenyls over a Pt-containing catalyst

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Abstract

Catalytic hydrogenation of benzene, biphenyl, and ortho-, metha-, and para-isomers of terphenyl over a 3 wt.% Pt/C at 180 °C and 70 atm was studied. The directions of hydrogenation of each substrate were revealed. Relationships between structures of the substrate and hydrogen consumption rates were found. It was shown that hydrogenation rate decreases on going from benzene to terphenyl and with increasing degree of the substrate hydrogenation. Hydrogenation rate of terphenyl isomers decreases in the following order: p-terphenyl > > m-terphenyl > o-terphenyl.

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Authors and Affiliations

  1. Department of Chemistry, M. V. Lomonosov Moscow State University, 3 Build., 1 Leninskie Gory, 119992, Moscow, Russian Federation

    A. N. Kalenchuk, V. I. Bogdan & L. M. Kustov

  2. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

    A. N. Kalenchuk, A. E. Koklin, V. I. Bogdan & L. M. Kustov

Authors
  1. A. N. Kalenchuk
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  2. A. E. Koklin
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  3. V. I. Bogdan
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  4. L. M. Kustov
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Correspondence to A. N. Kalenchuk.

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Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 7, pp. 1208—1212, July, 2017.

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Kalenchuk, A.N., Koklin, A.E., Bogdan, V.I. et al. Hydrogenation of biphenyl and isomeric terphenyls over a Pt-containing catalyst. Russ Chem Bull 66, 1208–1212 (2017). https://doi.org/10.1007/s11172-017-1874-9

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  • DOI: https://doi.org/10.1007/s11172-017-1874-9

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