Skip to main content
SpringerLink
Log in

Synthesis, Structure and Properties of an Organically Templated Molybdate Zn2(bpe)Mo2O8 (bpe = 1,2-Bis(4-pyridyl)ethane)

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A new organically templated molybdenum oxides compound Zn2(bpe)Mo2O8 (bpe = 1,2-bis(4-pyridyl)ethane) has been hydrothermal synthesized and characterized by single X-ray analysis, element analysis, IR spectroscopy, TG analysis, diffuse reflectance UV–Vis spectra. Compound 1 shows a three-dimensional net-like structure, where the bimetallic oxide layers {ZnMoO4} were knitted together with the bpe ligands. The optical band gap for 1 was 2.5 eV, which is comparable to that of TiO2. Moreover, the photoluminescent properties of 1 have been investigated at room temperature.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. M. Vougo-Zanda, X. Q. Wang, and A. J. Jacobson (2007). Inorg. Chem. 46, 8819.

    Article  CAS  Google Scholar 

  2. A. J. Cheetham (1994). Science 264, 794.

    Article  CAS  Google Scholar 

  3. R. K. Grasselli (1999). Catal. Today 49, 141.

    Article  CAS  Google Scholar 

  4. C. Coue, R. Dessapt, M. Bujoli-Doeuff, M. Evain, and S. Jobic (2007). Inorg. Chem. 46, 2824.

    Article  CAS  Google Scholar 

  5. R. S. Rarig, and J. Zubieta (2001). J. Chem. Dalton Trans. 23, 3446.

    Article  Google Scholar 

  6. J. Q. Xu, R. Z. Wang, G. Y. Yang, Y. H. Xing, D. M. Li, W. M. Bu, L. Ye, Y. G. Fan, G. D. Yang, Y. Xing, Y. H. Lin and H. Q. Jia (1999). Chem. Commun. 11, 983.

    Article  Google Scholar 

  7. G. D. Santis, L. Fabbrizzi, M. Licchelli, A. Poggi, and A. Taglietti (1996). Angew. Chem. Int. Ed. 35, 202.

    Article  Google Scholar 

  8. J. E. McGarrah, Y. J. Kim, M. Hissler, and R. Eisenberg (2001). Inorg. Chem. 40, 4510.

    Article  CAS  Google Scholar 

  9. Q. Wu, M. Esteghamatian, N. X. Hu, Z. Popovic, G. Enright, Y. Tao, M. D’Iorio, and S. Wang (2000). Chem. Mater. 12, 79.

    Article  CAS  Google Scholar 

  10. G. M. Sheldrick SHELXS 97, Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  11. J. I. Pankove Optical Processes in Semiconductors (Prentice-Hall, Englewood Cliffs, 1971), p. 34.

    Google Scholar 

  12. Y. Xu and M. A. A. Schoonen (2000). Am. Mineral. 85, 543.

    Article  CAS  Google Scholar 

  13. Y. Yang, P. Du, J. F. Ma, W. Q. Kan, B. Liu, and J. Yang (2011). Cryst. Growth Des. 11, 5540.

    Article  CAS  Google Scholar 

  14. L. P. Zhang, J. F. Ma, J. Yang, Y. Y. Pang, and J. C. Ma (2010). Inorg. Chem. 49, 1535.

    Article  CAS  Google Scholar 

  15. L. Wen, Z. Lu, J. Lin, Z. Tian, H. Zhu, and Q. Meng (2007). Cryst. Growth Des. 7, 93.

    Article  CAS  Google Scholar 

  16. H. Y. Liu, H. Wu, J. F. Ma, Y. Y. Liu, B. Liu, and J. Yang (2010). Cryst. Growth Des. 10, 4795.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This project is financially supported by the National Natural Science Foundation of China (Grant No. 21361027 and 21571029), Jilin Provincial Science and Technology Development Foundation (Grant No. 20140101120JC).

Author information

Authors and Affiliations

  1. Department of Chemistry, Baicheng Teacher’s College, Baicheng, 137000, Jilin, People’s Republic of China

    Wen-Ju Wang, Zhe-Yu Zhang & Ze-Min Mei

  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People’s Republic of China

    Feng-Yan Li

Authors
  1. Wen-Ju Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zhe-Yu Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Ze-Min Mei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Feng-Yan Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Wen-Ju Wang or Feng-Yan Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, WJ., Zhang, ZY., Mei, ZM. et al. Synthesis, Structure and Properties of an Organically Templated Molybdate Zn2(bpe)Mo2O8 (bpe = 1,2-Bis(4-pyridyl)ethane). J Clust Sci 27, 617–624 (2016). https://doi.org/10.1007/s10876-015-0943-1

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-015-0943-1

Keywords

Search

Navigation