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Syntheses, Crystal Structures and Properties of Organic–Inorganic Hybrid Compounds of 4,4′-Bipyridine–Decorated Ni/Cu-Substituted Molybdophosphates

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Abstract

Organic–inorganic hybrid compounds of transition metal mono-substituted molybdophosphates, (H2bipy)2[PNi(Hbipy)Mo11O39]·4H2O (1), (H2bipy)1.5[HPCu(Hbipy)Mo11O39]·4H2O (2) (bipy = 4,4′-bipyridine), were synthesized hydrothermally and characterized by elemental analysis, IR spectroscopy, TGA, fluorescent spectroscopy, powder and single crystal X-ray diffraction methods. In 1 and 2 the transition metal atom (Ni and Cu) occupies one site of twelve molybdenum atoms of Keggin anion and combines a monoprotonated bipyridine molecular cation, Hbipy+, forming a 4,4′-bipyridine–decorated M-substituted molybdophosphate anion (M = Ni and Cu). In 1 two anions form a dimer through hydrogen bonds, in 2 the anions form a chain through hydrogen bonds. The dimers or the chains, H2bipy2+ cations and lattice water molecules are connected by hydrogen bonds, giving supramolecular compounds. The two kinds of bipy molecules, coordinated and uncoordinated, in 1 and 2 give two emission peaks in their photoluminescent spectra.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Xiao-Min Li, Tian Shi & Ya-Guang Chen

  2. Department of Chemistry, Yili Normal University, Yining, 835000, Xingjiang, People’s Republic of China

    Xiao-Min Li

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  1. Xiao-Min Li
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  2. Tian Shi
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Correspondence to Ya-Guang Chen.

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Li, XM., Shi, T. & Chen, YG. Syntheses, Crystal Structures and Properties of Organic–Inorganic Hybrid Compounds of 4,4′-Bipyridine–Decorated Ni/Cu-Substituted Molybdophosphates. J Clust Sci 27, 457–468 (2016). https://doi.org/10.1007/s10876-015-0940-4

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