Skip to main content
Log in

Microstructural and electrical characterizations of transparent Er-doped ZnO nano thin films prepared by sol–gel process

  • Published:
Journal of Materials Science: Materials in Electronics Aims and scope Submit manuscript

Abstract

In this study, rare earth element (Er) doped ZnO nano thin films which have dual structure of (Zn1−xErx)O (x = 0.0, 0.01, 0.02, 0.03, 0.04 and 0.05) are prepared by using sol–gel method. The microstructure and electrical properties of prepared nano thin films are investigated. Nano thin films are coated on the glass substrate by using the dip coating method. The films are annealed at 600 °C for 30 min. The X-ray diffractometer (XRD), scanning electron microscopy and atomic force microscopy are used to determine the structural properties such as crystal structures, grain sizes, surface morphology; Hall effect measurements system is used to investigate the electrical properties of materials. XRD results showed that all Er doped nano thin films have a hexagonal structure and (002) orientation. Surface morphologies of ZnErO thin films are denser and more uniform than the undoped ZnO thin film. According to the Hall effect measurements, the resistivity of the films decreased with increasing Er concentration from \(0\) to \(4\%\) and then slightly increased at \(5\% Er\).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Z.K. Heiba, L. Arda, Structural properties of Zn1−xMgxO nanomaterials prepared by sol–gel method. Cryst. Res. Technol. 44, 845–850 (2009)

    Article  Google Scholar 

  2. S. Zhao, P. Li, Y. Wei, Effects of Ni doping on the luminescent and magnetic behaviors of ZnO nanocrystals. Powder Technol. 224, 390–394 (2012)

    Article  Google Scholar 

  3. C.C. Vidyasagar, Y.A. Naik, T.G. Venkatesh, R. Viswanatha, Solid-state synthesis and effect of temperature on optical properties of Cu–ZnO, Cu–CdO and CuO nanoparticles. Powder Technol. 214, 337–343 (2011)

    Article  Google Scholar 

  4. S. Muthukumaran, R. Gopalakrishnan, Structural, optical and photoluminescence studies of heavily Mn-doped ZnO nanoparticles annealed under Ar atmosphere. J. Mater. Sci. 23, 1393–1401 (2012)

    Google Scholar 

  5. Z.K. Heiba, L. Arda, M.B. Mohamed, N.Y. Mostafa, N. Dogan, Effect of annealing temperature on structural and magnetic properties of Zn0.94Co0.05Cu0.01O. J. Supercond. Nov. Magn. 26, 3487–3493 (2013)

    Article  Google Scholar 

  6. X.J. Liu, X.Y. Zhu, J.T. Luo, F. Zeng, F. Pan, Grain boundary defects-mediated room temperature ferromagnetism in Co-doped ZnO film. J. Alloys Compd. 482, 224–228 (2009)

    Article  Google Scholar 

  7. G. Pei, C. Xia, F. Wu, J. Xu, Absence of room-temperature ferromagnetism in Al-codoped Zn0.95Co0.05O nanoparticles. J. Alloys Compd. 467, 539–542 (2009)

    Article  Google Scholar 

  8. R. Vettumperumal, S. Kalyanaraman, R. Thangavel, Optical constants and near infrared emission of Er doped ZnO sol–gel nano thin films. J. Lumin. 158, 493–500 (2015)

    Article  Google Scholar 

  9. W. DeYi, Z. Jian, L. GuiZhen, Effect of Li-doped concentration on the structure, optical and electrical properties of p-type ZnO thin films prepared by sol–gel method. J. Alloys Compd. 481, 802–805 (2009)

    Article  Google Scholar 

  10. D.K. Takci, E.S. Tuzemen, K. Kara, S. Yilmaz, R. Esen, O. Baglayan, Influence of Al concentration on structural and optical properties of Al-doped ZnO nano thin films. J. Mater. Sci. 25, 2078–2085 (2014)

    Google Scholar 

  11. M. Caglar, Y. Caglar, S. Aksoy, S. Ilican, Temperature dependence of the optical band gap and electrical conductivity of sol-gel derived undoped and Li-doped ZnO films. Appl. Surface Sci. 256, 4966–4971 (2010)

    Article  Google Scholar 

  12. Z. Fan, J.G. Lu, Zinc oxide nanostructures: synthesis and properties. J. Nanosci. Nanotechnol. 5, 1561–1573 (2005)

    Article  Google Scholar 

  13. N. Kılınç, L. Arda, S. Öztürk, Z.Z. Öztürk, Structure and electrical properties of Mg-doped ZnO nanoparticles. Cryst. Res. Technol. 4, 529–538 (2010)

    Google Scholar 

  14. M. Girtan, M. Socol, B. Pattier, M. Sylla, A. Stanculescu, On the structural, morphological, optical and electrical properties of sol–gel deposited ZnO: in films. Thin Solid Films 519, 573–577 (2010)

    Article  Google Scholar 

  15. M. Tosun, S. Ataoglu, L. Arda, O. Ozturk, E. Asikuzun, D. Akcan, O. Cakiroglu, Structural and mechanical properties of ZnMgO nanoparticles. Mater. Sci. Eng. A 590, 416–422 (2014)

    Article  Google Scholar 

  16. L. Arda, O. Ozturk, E. Asikuzun, S. Ataoglu, Structural and mechanical properties of transition metals doped ZnMgO nanoparticles. Powder Technol. 235, 479–484 (2013)

    Article  Google Scholar 

  17. E.J. Luna-Arredondo, A. Maldonado, R. Asomoza, D.R. Acosta, M.A. Mele´ndez-Lira, M. de la, L. Olvera, Indium-doped ZnO thin films deposited by the sol–gel technique. Thin Solid Films 490, 132–136 (2005)

    Article  Google Scholar 

  18. J.G. Lu, Z.Z. Ye, Y.J. Zeng, L.P. Zhu, L. Wang, J. Yuan, Q.L. Liang, Structural, optical, and electrical properties of (Zn, Al) O films over a wide range of compositions. J. Appl. Phys. 100, 073714 (2006)

    Article  Google Scholar 

  19. S.D. Senol, O. Ozturk, C. Terzioğlu, Effect of boron doping on the structural, optical and electrical properties of ZnO nanoparticles produced by the hydrothermal method. Ceram. Int. 41, 11194–11201 (2015)

    Article  Google Scholar 

  20. K. Necmettin, O. Sadullah, A. Lutfi, A. Ahmet, Z.O. Zafer, Structural, electrical, transport and NO2 sensing properties of Y-doped ZnO nano thin films. J. Alloys Compd. 536, 138–144 (2012)

    Article  Google Scholar 

  21. E. Asikuzun, A. Donmez, L. Arda, O. Cakiroglu, O. Ozturk, D. Akcan, C. Terzioglu, Structural and mechanical properties of (Co/Mg) co-doped nano ZnO. Ceram. Int. 41, 6326–6334 (2015)

    Article  Google Scholar 

  22. E. Asikuzun, O. Ozturk, L. Arda, A.T. Tasci, F. Kartal, C. Terzioglu, High-quality c-axis oriented non-vacuum Er doped ZnO thin films, Ceram. Int. 2, 8085–8091 (2016)

    Article  Google Scholar 

  23. C.Y. Tsay, K.S. Fan, Y.W. Wang, C.J. Chang, Y.K. Tseng, C.K. Lin, Transparent semiconductor zinc oxide nano thin films deposited on glass substrates by sol–gel process. Ceram. Int. 36, 1791–1795 (2010)

    Article  Google Scholar 

  24. S.D. Senol, A. Senol, O. Ozturk, M. Erdem, Effect of annealing time on the structural, optical and electrical characteristics of DC sputtered ITO nano thin films, J. Mater. Sci. 25, 4992–4999 (2014)

    Google Scholar 

  25. C.Y. Tsay, W.T. Hsu, Sol–gel derived undoped and boron-doped ZnO semiconductor thin films: preparation and characterization. Ceram. Int. 39, 7425–7432 (2013)

    Article  Google Scholar 

  26. L.J. Van der Pauw, A method of measuring the resistivity and Hall coefficient on lamellae of arbitrary shape. Philips Tech. Rev. 20, 220–224 (1958)

    Google Scholar 

  27. I. Winer, G.E. Shter, M. Mann-Lahav, G.S. Grader, Effect of solvents and stabilizers on sol–gel deposition of Ga-doped zinc oxide TCO films. J. Mater. Res. 26, 1309–1315 (2011)

    Article  Google Scholar 

Download references

Acknowledgements

The authors would like to thank the Kastamonu University Scientific Research Projects Coordination Department under the Grant No. KUBAP-03/2013-41, Grant No. KUBAP-05/2015-12 and the Scientific and Technological Research Council of Turkey (TUBITAK) Project No. 114F259 for the supports.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. Asikuzun.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Asikuzun, E., Ozturk, O., Arda, L. et al. Microstructural and electrical characterizations of transparent Er-doped ZnO nano thin films prepared by sol–gel process. J Mater Sci: Mater Electron 28, 14314–14322 (2017). https://doi.org/10.1007/s10854-017-7291-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10854-017-7291-x

Navigation